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Ultrafast dynamics of excitons and charge carriers in Van der Waals WS2 nanotubes
Materials Today Chemistry. 2024. No. 36. Article 101886.
Paukov M. I., Starchenko V. V., Melnikov A., Komandin G. A., Goldt A. E., Yakubovsky D. I., Syuy A. V., Mishra P., Zaytsev K. I., Garnov S. V., Nasibulin A. G., Arsenin A. V., Volkov V., Burdanova M. G.
An P. P., V. V. Kovalyuk, Y. G. Gladush et al., Applied Physics Letters 2024 Vol. 125 No. 20 Article 201101
The rapid development of photonic integrated circuits (PICs) and their applications in various fields of science and technology requires the creation of easy-to-manufacture high-speed integrated detectors. In this work, we fabricated and studied planar waveguide-integrated bolometers based on a thin film of single-walled carbon nanotubes (SWCNTs) on the silicon nitride platform. This bolometer showed good ...
Added: November 11, 2024
Jiang X., Tan J., Liu D. et al., The Journal of Physical Chemistry Letters 2024 Vol. 15 No. 10 P. 2867–2875
The rapid recombination of photogenerated carriers heavily restrict the photocatalytic efficiency. Here, we propose a new strategy to improve catalytic efficiency based on ferroelectric van der Waals heterostructure (CuBiP2Se6/C2N). Combining density functional theory and nonadiabatic molecular dynamics (NAMD) method, we have systematically analyzed the ground state properties and carrier dynamics images in CuBiP2Se6/C2N heterostructure. Our ...
Added: March 5, 2024
Duleba A., Pugachev M., Mark Blumenau et al., Micromachines 2024 Vol. 15 No. 1 Article 94
Most 2D materials are unstable under ambient conditions. Assembly of van der Waals heterostructures in the inert atmosphere of the glove box with ex situ lithography partially solves the problem of device fabrication out of unstable materials. In our paper, we demonstrate an approach to the next-generation inert-atmosphere (nitrogen, <20 ppm oxygen content) fabrication setup, ...
Added: February 15, 2024
Kirill Shein, Zharkova E., Kashchenko M. et al., Nano Letters 2024 Vol. 24 No. 7 P. 2282–2288
The rapid development of infrared spectroscopy, observational astronomy, and scanning near-field microscopy has been enabled by the emergence of sensitive mid- and far-infrared photodetectors. Superconducting hot-electron bolometers (HEBs), known for their exceptional signal-to-noise ratio and fast photoresponse, play a crucial role in these applications. While superconducting HEBs are traditionally crafted from sputtered thin films such ...
Added: February 13, 2024
Zhukov A., Bessonov I. V., Bobrova E. et al., Нанотехнологии в строительстве: научный интернет-журнал 2021 Vol. 13 No. 3 P. 144–149
ABSTRACT: Introduction. The use of gypsum in construction systems exposed to atmospheric influences involves the introduction of modifying additives of various types: polymer compositions, mineral fine and nanodisperse components, which can also be products of other industries. Methods and materials. To increase the weather resistance of gypsum stone, its strength characteristics and water resistance, the research ...
Added: March 20, 2023
Mukhangali S., Neplokh V., Kochetkov F. et al., Applied Physics Letters 2022 No. 121 Article 243504
This paper demonstrates an elastic (i.e., both flexible and stretchable) pixel matrix based on the patterned films of single-walled carbon nanotubes, which were obtained using optical lithography and plasma etching. The proposed elastic electrodes maintain their initial resistivity at 10% stretching. We also demonstrate an application of the elastic pixel matrix to an array of ...
Added: December 14, 2022
Pugachev M., Duleba A., Arslan A. Galiullin et al., Micromachines 2021 Vol. 12 No. 8 Article 850
The fast and precise fabrication of micro-devices based on single flakes of novel 2D materials and stacked heterostructures is vital for exploration of novel functionalities. In this paper, we demonstrate a fast high-resolution contact mask lithography through a simple upgrade of metallographic optical microscope. Suggested kit for the micromask lithography is compact and easily compatible ...
Added: November 14, 2022
Klokov A., Frolov N., Sharkov A. et al., Nano Letters 2022 Vol. 22 No. 5 P. 2070–2076
The mechanical properties of the layered crystals in the few layer limit are largely unexplored. We employ a picosecond ultrasonic technique to access the corresponding mechanical parameters. Temporal variation of the reflection coefficient of the Al film that covers hBN/WSe2/hBN (where hBN is hexagonal boron nitride) heterostructures on a sapphire substrate after the femtosecond laser ...
Added: June 17, 2022
Glebov E., Bakulina O. D., Shushakov A. A. et al., Mendeleev Communications 2020 Vol. 30 No. 3 P. 322–324
The photophysical and photochemial properties of dipyrido[3,2-a:2′,3′-c]phenazine (dppz) in acetonitrile have been investigated by laser flash photolysis and ultrafast pump-probe spectroscopy. The excitation of dppz to the first singlet excited state was followed by vibrational cooling with solvent relaxation for ∼3 ps and then intersystem crossing for ∼50 ps. Spectral and kinetic characteristics of the triplet excited ...
Added: January 18, 2021
Glebov E., Pozdnyakov I., Semionova V. V. et al., Mendeleev Communications 2020 Vol. 30 No. 1 P. 61–63
Early processes in photochemistry of 2,3-bis(2,5-dimethylthiophen-3-yl)cyclopent-2-enone were explored using the ultrafast pump-probe spectroscopy. The photocyclization occurs from the antiparallel conformation of an open form on a time scale of 7 ps, while the parallel conformation exhibits an intersystem crossing within 130 ps. The mechanism and timescales were revealed as typical of other thiophene-containing diarylethenes. ...
Added: January 18, 2021
Melnikov A., Pozdnyakov I., Chekalin S. et al., Mendeleev Communications 2020 Vol. 30 No. 4 P. 509–511
The time of ultrafast intersystem crossing for the PtIVBr62– complex in aqueous solution was measured by a fluorescence up-conversion technique. The corresponding time constant (140 ± 40 fs) is in agreement with that estimated from previous ultrafast transient absorption measurements and with the reported results of theoretical calculations. ...
Added: January 18, 2021
Shushakov A. A., Matveeva S. G., Pozdnyakov I. et al., Photochemical and Photobiological Sciences 2020 Vol. 19 P. 1222–1229
It is known that trans,cis,cis-[RuCl2(DMSO)2(H2O)2] (1a) complexes, which are formed upon dissolution of trans-[RuCl2(DMSO)4] in water, demonstrate light-induced cytotoxicity. The mechanistic study of 1a photochemistry has been performed using ultrafast pump–probe spectroscopy, laser flash photolysis and stationary photolysis. The first stage of 1a photochemistry is the photoexchange of a DMSO ligand to a water molecule; its quantum yield is wavelength-dependent (estimating ...
Added: January 18, 2021
Glebov E., Matveeva S. G., Pozdnyakov I. et al., Photochemical and Photobiological Sciences 2020 Vol. 19 P. 1569–1579
The photochemistry of the OsIVCl62− complex in ethanol was studied by means of stationary photolysis, nanosecond laser flash photolysis, ultrafast pump–probe spectroscopy and quantum chemistry. The direction of the photochemical process was found to be wavelength-dependent. Irradiation in the region of the d–d and LMCT bands results in the photosolvation (with the wavelength-dependent quantum yield) and ...
Added: January 18, 2021
Glebov E., Pozdnyakov I., Vasilchenko D. et al., , in: Journal of Photochemistry and Photobiology A: Chemistry. Special Issue: Molecular Photonics.: Elsevier, 2018. P. 78–85.
Diiodido Pt(IV) complexes (earlier tested as prodrugs in photodynamic therapy) could be considered as model mixed-ligand platinum complexes. In this work, photochemistry of cis,trans-[Pt-IV(en)(I)(2)(OH)(2)] complex (1) in aqueous solutions was examined in time interval from hundreds of femtoseconds to hours. UV and NMR spectroscopy, nanosecond laser flash photolysis and ultrafast spectroscopy were applied to study ...
Added: February 15, 2019