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Evidence for zero-field slow magnetic relaxation in a Co(II) complex with a pseudo-tetrahedral N2I2 environment
Dalton Transactions. 2022. Vol. 51. P. 11916–11921.
Yureva E. A., Korchagin D. V., Anichkin A. A., Shilov G. V., Babeshkin K. A., Efimov N. N., Palii A. V., Алдошин С. М.
Herein, we report on the synthesis, structure and magnetic properties of a four-coordinate mononuclear Co(II) diiodide complex with the 3,5-dimethylpyrazole ligand. A distorted tetrahedral local coordination environment around the central cobalt ion is formed by the two nitrogen atoms of two monodentate pyrazole ligands and by iodide ions. Direct current (dc) magnetic measurements in combination with ab initio SA-CASSCF/NEVPT2 quantum-chemical calculations revealed a strong easy-axis-type magnetic anisotropy with a record value Dexp = −30.58(3) cm−1 of the axial zero field splitting parameter for pseudo-tetrahedral Co(II)-based CoL2Hal2 complexes. Moreover, it is the only complex in this series demonstrating the slow relaxation of magnetization at zero dc field. The Orbach process is shown to be the dominant mechanism of magnetic relaxations in the high temperature range, while the quantum tunneling of magnetization produces the leading contribution to the overall relaxation at temperatures below 4 K.
Kobtsev Danil, Albert J., Nitzan M. et al., Applied Sciences (Switzerland) 2026 Vol. 16 No. 17 Article 8577
AIVBVI semiconductors, particularly lead chalcogenides, remain key materials for mid-wave infrared (MWIR) photodetection due to their narrow bandgap and exceptional carrier transport properties. However, the realization of high-quality p-type PbTe thin films, suitable for p–n junction devices, remains a technological challenge. In this work, we report the fabrication of high-mobility p-type PbTe thin films grown on ...
Added: August 30, 2026
Воронеж: Издательский дом ВГУ, 2026.
В сборник вошли материалы XXXII Международной научно-технической конференции «Радиолокация, навигация, связь» (RLNC*2026), прошедшие ре цензирование членами программного комитета конференции. Основной целью конференции является организация взаимодействия научных и научно технических коллективов для обмена опытом и новыми творческими успехами. Достижение этой цели также способствует внедрению перспективных разрабо ток, имеющих практическое значение для дальнейшего развития промышленно сти, экономики ...
Added: August 29, 2026
Melnikov I., Pelinovsky E., Nonlinear Dynamics 2026 No. 114 Article 934
Pyramidal solitons (solitons with more than two inflection points) of the generalized Korteweg–de Vries (KdV) equation are investigated. Necessary and sufficient conditions for the existence of such structures are presented. Within the framework of the generalized Gardner equation — the simplest model that admits pyramidal solitons as solutions — it is shown that these solutions ...
Added: August 27, 2026
Zhukov A., Kryzhanovskaya N., Moiseev E. et al., Nature 2026 Vol. 656 P. 80–85
Reaching lasing in electrically pumped microdevices based on solution-processed
semiconductors poses a substantial scientific and technological challenge. Halide
perovskites offer a promising platform for electrical injection1, as their optically
excited single-crystal cavities2–4 and predesigned5,6 or postprocessed microstructures7,8
have exhibited low lasing threshold. Indirect electrical pumping of a dual-cavity
perovskite laser was recently obtained9, using a well-established technological
concept of embedding a ...
Added: August 27, 2026
Belousov Y., Кискин М. А., Sidoruk A. et al., Australian Journal of Chemistry 2022 Vol. 75 No. 9 P. 572–580
Four new complexes [Ln(pfaa)3(H2O)2]n (Ln = Eu (1), Tb (2)) and [Ln2Cd2(pfaa)10 (phen)2(EtOH)2]·2MeCN (Ln = Eu (3), Tb (4), phen = 1,10-phenanthroline) based on pentaphorphenylacetic acid (Hpfaa) have been prepared and completely investigated. The structures of compounds 1 and 3 were studied by single crystal X-ray diffraction analysis: the isostructural complexes 1 and 2 represent ...
Added: August 26, 2026
Mazur D., Brandyshev P., Doronin S. V. et al., Electrochimica Acta 2026 Vol. 577 Article 149729
The electric double layer (EDL) at a single-crystal metal surface is controlled not only by the electrolyte composition and the electrode potential, but also by the atomic structure of the surface itself. This makes the Ag(hkl)/NaF interface a stringent test for continuum theories of the EDL. In the third part of our series, we examine ...
Added: August 20, 2026
Аничкин А. А., Yureva E. A., Korchagin, D. V. et al., Dalton Transactions 2022 Vol. 51 No. 311 P. 11916–11921
Herein, we report on the synthesis, structure and magnetic properties of a four-coordinate mononuclear Co(ii) diiodide complex with the 3,5-dimethylpyrazole ligand. A distorted tetrahedral local coordination environment around the central cobalt ion is formed by the two nitrogen atoms of two monodentate pyrazole ligands and by iodide ions. Direct current (dc) magnetic measurements in combination ...
Added: August 19, 2026
Gimaev R., Karpenkov A., Shelkovyi F. et al., Journal of Alloys and Compounds 2026 No. 1080 Article 190307
The magnetothermal properties of the quaternary Fe49Rh46.1Pd3.1Ir1.8 alloy are investigated by a combination of first-principles calculations, structural characterization, magnetometry, calorimetry, and direct measurements of the adiabatic temperature change. An exceptional magnetocaloric response is obtained, with ΔTad reaching −11.9 K in a field of 1.85 T under the discontinuous protocol and −8.6 K under the continuous ...
Added: August 18, 2026
Beck M. E., Seidov S., Mukhin S., Physical Review A: Atomic, Molecular, and Optical physics 2026
Quantum dissipation is studied in the superradiant phase of the extended Dicke model. It is demonstrated analytically by quantum mechanical derivation of the Lindblad equation for the Dicke model in the superradiant state coupled to Caldeira-Leggett thermal bath that the effective viscosity appearing in the semiclassical equations of motion of polaritonic condensate survives in the zero-temperature limit ...
Added: August 13, 2026
S. S. Seidov, N. G. Pugach, Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 114 No. 7 Article 074504
In this manuscript we consider a superconducting film in the vicinity of the critical temperature and presence of the proximity effect. We analytically solve the corresponding linearized Usadel equation and the self-consistency equation, defining the critical temperature. This is a system of coupled differential and integral equations for the anomalous Green's function and the order parameter of ...
Added: August 13, 2026
Ievlev E., Marshakov A., Sumbatian G. et al., Physical Review D - Particles, Fields, Gravitation and Cosmology 2026 Vol. 114 Article 046006
We continue the study of non-Abelian vortex string in 4D N =2 supersymmetric QCD (SQCD) as
critical superstring, and extend this analysis to UðNÞ gauge theory with arbitrary even N and Nf = 2N
number of quarks. We introduce a special mass deformation and show that the SQCD hadron spectrum is
still given by the string spectrum on the ...
Added: August 13, 2026
Ratnikov F., Bocharnikov V., Journal of High Energy Physics 2026 Vol. 2026 P. 1–21
The BM@N experiment (Baryonic Matter at the Nuclotron) is the first fixed-target experiment at the JINR NICA accelerator complex. In this work, data on the interactions of a carbon-ion beam with kinetic energies of 4.0A GeV and 4.5A GeV with C, Al, Cu, and Pb targets are used to measure transverse momentum spectra and rapidity ...
Added: August 12, 2026
Budkov Y., Kalikin N., Journal of Chemical Physics 2026 Vol. 165 Article 064506
A self-consistent statistical-mechanical theory of the Hall effect in electrolyte solutions is developed by extending the self-consistent Debye–Hückel–Onsager (SCDHO) framework to crossed electric and magnetic fields. The theory incorporates non-local ionic charge distributions via Slater-type form factors, regularizing the Coulomb interaction at short range, and accounts for dielectric friction through ion-specific coefficients, employing experimental values ...
Added: August 12, 2026
Novikov A., New Journal of Chemistry 2026 Vol. 50 P. 13931–13957
The rational design of coinage metal nanocarriers requires a mechanistic understanding of metal-drug binding and predictive descriptors that translate molecular interactions into design rules. Using DFT (B3LYP-D3BJ/def2-TZVP, SMD water), we systematically investigated the binding of 5-fluorouracil (5-FU) and levodopa (l-DOPA) to neutral and cationic homo- and heteronuclear dimers of Au, Ag, and Cu (Au2, Ag2, ...
Added: August 12, 2026
Ali S., Bocharnikov V., Ratnikov F. et al., Sensors 2026 Vol. 26 No. 16 Article 5024
Large distributed sensor arrays require repeated recalibration as radiation damage, material aging, gain variation, and readout drift alter channel responses. We studied a high-granularity calorimeter as a large sensor array and addressed unsupervised recalibration from two unpaired datasets: a nominal reference response and an aged response with attenuated cell-wise signals. Aging was modeled by a ...
Added: August 11, 2026
Ponomarev A., Aleksandrov N., Journal of Physics D: Applied Physics 2026 Vol. 59 No. 31 Article 315205
Electron attachment and detachment in H2O:O2 and H2O:air mixtures are theoretically studied at moderate (40–100 Td) reduced electric fields. It is shown that there are two synergistic mechanisms of ultra-rapid electron detachment from negative ions in these mixtures, whereas these detachment channels are absent in pure gases. Effective attachment coefficient calculated with consideration for fast ion–molecule ...
Added: August 6, 2026
Khrapai V., Tikhonov E., Nature Physics 2026 P. 1198–1199
Feng et al.1 presented transport measurements of three-terminal normal–superconductor–normal devices based on topological insulator nanowires. They measured the full differential conductance matrix, defined as Gij = ∂Ii /∂Vj , beyond the linear response regime as a function of various control parameters. Here i, j∈ [1, 2] denote normal terminals biased by the voltages V1 and ...
Added: August 5, 2026
G. G. Bondarenko, Kristya V. I., Savichkin D. O. et al., Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques 2026 Vol. 20 No. 2 P. 417–423
A model of a glow gas discharge in a mixture of argon and mercury vapor is formulated in the presence
of a thin insulating film on the cathode surface. Dependences of the discharge characteristics on the
mixture temperature are calculated in the range of its variation, in which a noticeable contribution to ionization
of the working gas is ...
Added: August 1, 2026
Махаева Г. Ф., Ковалева Н. В., Рудакова Е. В. et al., Molecules 2024 Vol. 29 No. 2 Article 321
Effective therapeutics for Alzheimer’s disease (AD) are in great demand worldwide. In our previous work, we responded to this need by synthesizing novel drug candidates consisting of 4-amino-2,3-polymethylenequinolines conjugated with butylated hydroxytoluene via fixed-length alkylimine or alkylamine linkers (spacers) and studying their bioactivities pertaining to AD treatment. Here, we report significant extensions of these studies, ...
Added: September 14, 2025
Rumyantseva V. D., Ageeva T. A., Voropai D. et al., Russian Journal of General Chemistry 2023 Vol. 93 No. 1 P. S293–S303
Rhenium complexes of 5,10,15,20-tetraphenylporphine, 5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin, 5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrin, and 2,3,7,8,12,13,17,18-octabromo-5,10,15,20-tetraphenylporphyrin were synthesized and characterized by mass spectrometry, electron and 1H NMR spectroscopy, and HPLC. The X-ray photoelectron spectra of the complexes showed that rhenium is present predominantly in the pentavalent state. The optimized geometries, dipole moments, and charge and spin density distributions of the synthesized complexes were ...
Added: December 20, 2023