• A
  • A
  • A
  • АБВ
  • АБВ
  • АБВ
  • A
  • A
  • A
  • A
  • A
Обычная версия сайта
  • RU
  • EN
  • HSE University
  • Publications
  • Articles
  • Luminescent lanthanide-based sensor for H2O detection in aprotic solvents and D2O
  • RU
  • EN
Расширенный поиск
Высшая школа экономики
Национальный исследовательский университет
Priority areas
  • business informatics
  • economics
  • engineering science
  • humanitarian
  • IT and mathematics
  • law
  • management
  • mathematics
  • sociology
  • state and public administration
by year
  • 2027
  • 2026
  • 2025
  • 2024
  • 2023
  • 2022
  • 2021
  • 2020
  • 2019
  • 2018
  • 2017
  • 2016
  • 2015
  • 2014
  • 2013
  • 2012
  • 2011
  • 2010
  • 2009
  • 2008
  • 2007
  • 2006
  • 2005
  • 2004
  • 2003
  • 2002
  • 2001
  • 2000
  • 1999
  • 1998
  • 1997
  • 1996
  • 1995
  • 1994
  • 1993
  • 1992
  • 1991
  • 1990
  • 1989
  • 1988
  • 1987
  • 1986
  • 1985
  • 1984
  • 1983
  • 1982
  • 1981
  • 1980
  • 1979
  • 1978
  • 1977
  • 1976
  • 1975
  • 1974
  • 1973
  • 1972
  • 1971
  • 1970
  • 1969
  • 1968
  • 1967
  • 1966
  • 1965
  • 1964
  • 1963
  • 1958
  • More
Subject
News
June 25, 2026
HSE Researchers Make Aldehydes Perform Dual Function
Chemists from HSE University have discovered a way to carry out a reductive addition reaction without using an external reducing agent. Instead, the required 'resource' is supplied by the aldehyde itself, one of the reaction participants. This approach helps prevent unwanted side reactions, reduces toxicity, and simplifies the production and synthesis of organic molecules, including those used in the manufacture of medicines. The study has been published in Journal of Catalysis.
June 25, 2026
HSE Scientists Explain Why Findings in Autism Research Differ
Researchers from the Cognitive Health and Intelligence Centre at HSE University conducted the first-ever systematic review of studies on the specifics of emotion-from-motion perception in autism. The review showed that differences found between autistic and non-autistic individuals are largely associated with the experimental design and the types of tasks given to study participants. The review findings have been published in Research in Autism.
June 22, 2026
‘In Science, You Are Your Own Boss
Polina Nasledskova is interested in identifying gaps in linguistics and topics that have been overlooked by other researchers. In an interview for the  Young Scientists of HSE University project, she spoke about rare ordinal numerals in Nakh-Daghestanian languages, the benefits of knitting for concentration, and the beauty of the Patriarshy Bridge.

 

Have you spotted a typo?
Highlight it, click Ctrl+Enter and send us a message. Thank you for your help!

Publications
  • Books
  • Articles
  • Chapters of books
  • Working papers
  • Report a publication
  • Research at HSE

?

Luminescent lanthanide-based sensor for H2O detection in aprotic solvents and D2O

IEEE Sensors Journal. 2019. Vol. 19. No. 17. P. 7365–7372.
Gontcharenko V., Lunev A. M., Taydakov I., Korshunov V., Drozdov A., Belousov Y.

Applied methods for detecting water impurities in organic solvents, such as Fischer titration, include wayward equipment and toxic reagents. This method is inapplicable for detecting H2O in D2O, but suitable techniques like NMR-, IR-, and mass-spectrometry are costly. We report a low-cost, novel luminescent sensor material based on terbium-europium 3D MOF compound developed for facile, portable, and disposable monitoring of water quantities. Our sensor is able to determine water traces in D2O and aprotic organic solvents. Treating the material to solvent leads to the change in intensities ratio of terbium and europium bands in emission spectra depending of water content and nature of solvent. For D2O calibrating plot IEu/ITb – %H2O is linear whereas for dioxane and acetonitrile the dependence becomes linear in the coordinates IEu/ITb - ln(%H2O). The results reveal the potential application of developed sensor for ratiometric quantitation of H2O admixtures in D2O, organic solvents, transformer oil, etc.

Research target: Physics Chemistry
Language: English
Full text
DOI
Text on another site
Keywords: sensorlanthanideMOF
Similar publications
Incorporating Scientific Knowledge into Neural Network Density Functionals
Medvedev M., Journal of Chemical Theory and Computation 2026 Vol. 22 No. 9
Density functional theory (DFT) is the workhorse of modern reactions and materials modeling. While the exact functional remains unknown, many approximations to it have been constructed either by hand-crafting functional forms to satisfy exact constraints or by machine learning. In this work, we show how both of these approaches can be fused to build both ...
Added: June 26, 2026
High-temperature properties of mixed conductors LaxSr0.85−xCe0.15FeO3−δ
Никонов В. Д., Никитин С. С., Патракеев М. В., Ionics 2025 Vol. 31 No. 1 P. 675–687
Modification of perovskite-type oxides is an effective way to develop functional materials with advanced properties. The effects of cerium introduction into the A sublattice of La0.5Sr0.5FeO3−δ and variation of La:Sr ratio on the defect structure and charge transfer characteristics were studied in this work. The LaxSr0.85−xCe0.15FeO3−δ oxides were found to be single-phase with cubic (x = 0.1) and orthorhombic ...
Added: June 26, 2026
Optical conductivity of a dirty current-carrying superconductor
Polkin A., Skvortsov M., Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 113 Article 174516
We develop a full microscopic theory for the optical conductivity 𝜎⁡(𝜔) of a dirty current-carrying superconductor. Within the Keldysh sigma model formalism, we obtain the general analytical expression for 𝜎⁡(𝜔), applicable for arbitrary frequency 𝜔, temperature 𝑇, and dc supercurrent 𝐼. In addition to altering the usual Mattis-Bardeen conductivity 𝜎1⁡(𝜔), a finite supercurrent introduces two new contributions: 𝜎qp2⁡(𝜔) from quasiparticle redistribution and 𝜎SH2⁡(𝜔) from the amplitude ...
Added: June 25, 2026
Thermal phase slips in superconducting films
Skvortsov M., Artem Polkin, Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 113 No. 10 Article 100502
A dissipationless supercurrent state in superconductors can be destroyed by thermal fluctuations. Thermally activated phase slips provide a finite resistance of the sample and are responsible for dark counts in superconducting single-photon detectors. The activation barrier for a phase slip is determined by a space-dependent saddle-point (instanton) configuration of the order parameter. In the one-dimensional ...
Added: June 25, 2026
Electrodeposition and electrochromic properties of hydrated mixed oxides MoxW1-xO3·2H2O films
Laurinavichyute V., Levin E. E., Mironkova A. A. et al., Surfaces and Interfaces 2026 Vol. 81 P. 108389
In this work we characterize mixed Mo-W acidic deposition solutions with Mo content ranging from 0 to 100 mol.% by Raman and UV–Vis spectroscopy. The obtained distribution diagram of mixed isopolyanions allows one to explain the observed change in film deposition rate with increase in Mo content. It was found that the initial decrease in ...
Added: June 24, 2026
Динамика спинорных экситон-поляритонных конденсатов в двойных потенциальных ловушках в GaAs/AlAs микрорезонаторе при резонансном пикосекундном возбуждении
Деменев А. А., Терешко С. Н., Гиппиус Н А et al., Известия РАН. Серия физическая Россия 2025 Т. 89 № 2 С. 265–273
The authors study the temporal evolution of polarized spectra of emissions from spinor exciton‒ polariton condensates in double tunnel-coupled potential traps inside a high-Q GaAs/AlAs microcavity at 2 K upon resonance laser pumping with picosecond pulses at times of up to 1.5 ns. The period of the condensates’ spin relaxation in a double trap is estimated as τs ...
Added: June 23, 2026
Предвестники солнечных вспышек по наблюдениям на RSTN
Абрамов-Максимов В. Е., И.А. Бакунина, Геомагнетизм и аэрономия 2026 Т. 66 № 3 С. 515–529
Проанализировано 8 вспышечных событий по данным многочастотных наблюдений сети радиотелескопов Radio Solar Telescope Network. Целью анализа было выявление предвестников солнечных вспышек. В семи рассмотренных случаях выявлены предвспышечные квазипериодические флуктуации радиоизлучения. Сделанная по вейвлет-спектрам оценка квазипериодов дает в большинстве случаев значения 40–50 сек. В одном событии с большой вспышкой класса M8.0 квазипериодические флуктуации не проявились. В ...
Added: June 22, 2026
Взаимное расположение магнитных жгутов и источников микроволнового излучения в эруптивных вспышках
И.А. Бакунина, В.Ф. М., А.В. Ш. et al., Геомагнетизм и аэрономия 2025 Т. 65 № 9 С. 1363–1373
Рассмотрена связь особенностей положения и ориентации магнитных жгутов в активной области (АО) с источниками микроволнового (17 ГГц) излучения и излучения в крайнем ультрафиолетовом диапазоне (EUV) при возникновении эруптивных вспышек, сопровождающихся корональными выбросами массы, и вспышек с "запертой" эрупцией. Приведены примеры эруптивных событий, демонстрирующие пространственное совпадение микроволновых источников с расположением магнитных жгутов в АО, восстановленных при ...
Added: June 22, 2026
Моделирование влияния температуры на взаимодействие катода с тонкой диэлектрической пленкой и плазмы тлеющего газового разряда в смеси аргона и паров ртути
Г. Г. Бондаренко, Кристя В. И., Савичкин Д. О. et al., Поверхность. Рентгеновские, синхротронные и нейтронные исследования 2026 № 4 С. 29–36
Сформулирована модель тлеющего газового разряда в смеси аргона и паров ртути при наличии на поверхности катода тонкой диэлектрической пленки. Рассчитаны зависимости характеристик разряда от температуры в интервале ее изменения, в котором заметный вклад в ионизацию рабочей газовой смеси дает ионизация атомов ртути метастабильными возбужденными атомами аргона (реакция Пеннинга). Показано, что в случае катода без диэлектрической пленки при повышении температуры до ...
Added: June 20, 2026
Supervised Learning in Critical Phenomena—Statistical and Systematic Accuracy
Chertenkov V. I., Shchur L., Lobachevskii Journal of Mathematics 2026 Vol. 47 No. 2 P. 720–727
Supervised machine learning is successfully applied to the study of critical phenomena and allows us to obtain a numerical estimate of the phase transition temperature and the correlation length exponent. We discuss the influence of possible systematic errors, as well as statistical errors, on the accuracy of such numerical estimates. Errors in the training and ...
Added: June 16, 2026
ВНИИОФИ в период 2016–2025 годов: основные результаты научной деятельности
Батурин А. С., Гаврилов В. Р., Иванов А. В. et al., Измерительная техника 2026 Т. 75 № 2 С. 14–28
28 декабря 2025 года Всероссийскому научно-исследовательскому институту оптико-физических измерений (ВНИИОФИ) исполнилось 60 лет. За прошедшие десятилетия институт  выполнил значительное количество научных исследований, разработал и поставил потребителям тысячи высокоточных средств оптико-физических измерений (включая эталонное оборудование). В статье представлены наиболее значимые для метрологического обеспечения оптико-физических измерений результаты научно-исследовательских работ, выполненных ВНИИОФИ за период 2016–2025 гг. ...
Added: June 15, 2026
Государственный первичный эталон единиц оптической силы и коэффициента передачи модуляции очковой оптики и объективов ГЭТ 205-2025
Вишняков Г. Н., Левина Э. Ю., Minaev V., Измерительная техника 2025 Т. 74 № 2 С. 20–27
Качество формируемого оптической системой изображения определяется её частотно-контрастной характеристикой или коэффициентами передачи модуляции на различных пространственных частотах. Для обеспечения единства измерений коэффициентов передачи модуляции и создания эталонной базы по воспроизведению, хранению и передаче единицы коэффициента передачи модуляции усовершенствован Государственный первичный эталон единиц оптической силы очковой оптики ГЭТ 205-2013 в части воспроизведения единицы коэффициентов передачи модуляции ...
Added: June 15, 2026
Impact of heat treatment on microstructure and mechanical properties of additively manufactured aluminum bronze
Filippova A. V., Yurchenko N. Y., Smirnov S. A. et al., Journal of Alloys and Compounds 2026 No. 1074 Article 189162
This study investigates the effects of post-processing heat treatment at 300–500 °C on the microstructure, hardness, and tensile properties of laser powder bed fusion (PBF-LB) processed Al-bronze processed with energy densities (ED) in the range of 125–938 J/mm3. In the as-printed state, sharp needle-like α + β′ laths form at lower ED whereas with increasing ED, the β′ ...
Added: June 12, 2026
Спонтанное образование скин-слоя в воде с деформацией ОН-полосы КР вкладом компоненты льда 3200 см-1
Першин С. М., Степанов Е. В., Артемова Д. Г. et al., Письма в Журнал экспериментальной и теоретической физики 2026 Т. 123 № 6 С. 383–390
Открыто спонтанное образование в течение 4 ч скин-слоя дистиллированной воды толщиной до 3 мм при комнатной температуре с новыми свойствами. Обнаружены деформация ОН-полосы комбинационного рассеяния вкладом компоненты льда ( 3200 см-1), снижение коэффициента упругого рассеяния и его флуктуаций, а также увеличение на 20 капиллярах. Восстановление слоя после обогащения воздухом в результате перемешивания указывает на стабильность ...
Added: June 8, 2026
Innovations in Information and Decision Sciences. Proceedings of the 13th International Conference on Frontiers in Intelligent Computing: Theory and Applications (FICTA 2025), Volume 4
Springer, 2026.
The book presents the proceedings of the 13th International Conference on Frontiers of Intelligent Computing: Theory and Applications (FICTA 2024), held at Intelligent Systems Research Group (ISRG), London Metropolitan University, London, United Kingdom, during June 6–7, 2025. Researchers, scientists, engineers and practitioners exchange new ideas and experiences in the domain of intelligent computing theories with ...
Added: June 8, 2026
Relativistic effects in the interaction of electrons with a slow extraordinary wave
N.S. Artekha, D.R. Shklyar, Physics of Plasmas 2026 Vol. 33 No. 6 Article 062105
The peculiarities of resonant interaction between slow extraordinary (SE) waves and relativistic electrons have been studied. General equations of motion of relativistic electrons in the field of SE wave and a uniform ambient magnetic field are derived. Conditions of applicability of the isolated resonance approximation are elucidated. In this approximation, the equations of motion are reduced to one-dimensional set of ...
Added: June 6, 2026
Structural and broadband radio-frequency properties of InGaZnO4 nanoparticles synthesized by gel decomposition method
Zirnik G., Ostovari Moghaddam A., Zhukov S. et al., Journal of Materials Science: Materials in Electronics 2026 Vol. 37 Article 738
In regards to the advances in InGaZnO for flexible transistors applications, herein for the first time we measure the broadband radio-frequency range (10 Hz to 1 MHz) dielectric permittivity ε′ and electrical conductivity σ of InGaZnO4 nanoparticle layers at different temperatures ranging from 10 to 300 K. The InGaZnO4 nanoparticles prepared by metal–nitrate–glycol gel decomposition method exhibited ...
Added: June 6, 2026
Column chromatography separation of lanthanide(III) bisphthalocyaninate and phthalocyanine ligand
Botnar A. A., Tikhomirova T. V., Vashurin A., Mendeleev Communications 2023 Vol. 33 No. 5 P. 729–731
During the synthesis of double-decker f-metal phthalocyanine complexes Ln(Pc)2 free phthalocyanine ligands can be also formed, however, routine column chromatography is not effective for their separation. The preliminary reduction of the complexes with hydrazine hydrate affords the low mobile forms, which can be re-oxidized in the chromatography columns after the free ligand is eluted. ...
Added: September 16, 2025
Efficiency of the energy transfer through 5d state of the Ln3+ ion in complexes with diarylcyclopentadienyl ligands
Puntus L., Varaksina E., Bardonov D. et al., Optical Materials 2025 Vol. 160 Article 116734
Lanthanide tris complexes with unsubstituted and diarylcyclopentadienyl ligands have been synthesized and studied by single crystal X-ray diffraction analysis and optical spectroscopy. It is shown that the ligand field formed by three Cp ligands can be an effective tool to decrease the energy of 4f5d configuration and as a result for Ce complexes the luminescence in red region ...
Added: July 4, 2025
Методы детектирования взрывоопасных концентраций водорода: сравнительный анализ и преимущества оптических сенсоров
Кузьминых И. О., Kuzin A., Флоря И. Н. et al., Нано- и микросистемная техника 2025 Т. 27 № 4 С. 184–194
В работе рассмотрены основные варианты детектирования водорода, а также приведены требования, которые предъявляются к сенсорам водорода. Проанализированы преимущества и недостатки существующих решений по детектированию водорода и проведен сравнительный анализ основных метрик коммерчески доступных сенсоров водорода. Было установлено, что оптические сенсоры преодолевают основную проблему существующих сенсоров – использование электрического тока в чувствительной зоне сенсоров. Данная обзорная ...
Added: April 30, 2025
Алгоритм поиска оптимального расположения сенсоров для решения задачи мониторинга пространства
Кочкаров А. А., Яцкин Д. В., Программные продукты и системы 2016 № 3 С. 60–66
This paper is devoted to the task of space monitoring, algorithm and software package for solving it. From this problem the authors go on to the problem of detection, and then – to the problem of geometrical sensors location. It is proposed to use a decentralized robotic network to solve this problem. Limitations and assumptions ...
Added: March 7, 2025
Особенности решения задачи геометрического расположения сенсоров при мониторинге пространства.
Яцкин Д. В., Кочкаров А. А., Наукоемкие технологии 2016 Т. 17 № 9 С. 20–29
This paper provides the interpretation of space monitoring problem as a target detection problem within a certain area. There are considered a few subproblems, and its comprehensive solution ensures the solution of the original problem. The task of searching the sensors geometrical location  is formulated. The task is given into a discrete form, its solution ...
Added: March 7, 2025
An unexpected imidazole-induced porphyrinylphosphonate-based MOF-to-HOF structural transformation leading to the enhancement of proton conductivity
Zhigileva E., Enakieva Y., Chernyshev V. et al., Dalton Transactions 2024 Vol. 53 No. 39 P. 16345–16354
Post-synthetic modification of proton-conducting metal–organic frameworks (MOFs) by loading small molecules capable of generating protons into pores is an efficient approach for developing a new type of material with improved ionic conductivity. Herein, the synthesis, characterization and proton conductivity of a novel electroneutral MOF based on palladium(II) meso-tetrakis(4-(phosphonatophenyl))porphyrinate, IPCE-1Pd, are reported. The exposure of the obtained framework to imidazole ...
Added: January 21, 2025
Application of a Sensor Based on a Deceleration System for Measuring Movements
Maksim S. Akatov, Aleksandr L. Tuv, Sultan A. Lenvu et al., , in: 2022 International Conference on Quality Management, Transport and Information Security, Information Technologies (IT&QM&IS).: St. Petersburg: IEEE, 2022. Ch. 6 P. 207–212.
This paper presents the results of a research on the possibility of using a sensor based on deceleration systems to measure the distance to a flat metal surface with a sensing element in the form of a deceleration system consisting of two connected flat spiral inductance coils with opposite winding direction. In the course of the work the properties of ...
Added: October 2, 2023
  • About
  • About
  • Key Figures & Facts
  • Sustainability at HSE University
  • Faculties & Departments
  • International Partnerships
  • Faculty & Staff
  • HSE Buildings
  • HSE University for Persons with Disabilities
  • Public Enquiries
  • Studies
  • Admissions
  • Programme Catalogue
  • Undergraduate
  • Graduate
  • Exchange Programmes
  • Summer University
  • Summer Schools
  • Semester in Moscow
  • Business Internship
  • Research
  • International Laboratories
  • Research Centres
  • Research Projects
  • Monitoring Studies
  • Conferences & Seminars
  • Academic Jobs
  • Yasin (April) International Academic Conference on Economic and Social Development
  • Media & Resources
  • Publications by staff
  • HSE Journals
  • Publishing House
  • iq.hse.ru: commentary by HSE experts
  • Library
  • Economic & Social Data Archive
  • Video
  • HSE Repository of Socio-Economic Information
  • HSE1993–2026
  • Contacts
  • Copyright
  • Privacy Policy
  • Site Map
Edit