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Regular version of the site

Article

Charge redistribution in the SpnF-catalyzed Diels–Alder reaction

Mendeleev Communications. 2017. Vol. 27. No. 5. P. 500-502.
Medvedev M., Novikov F., Bushmarinov I., Zeifman A., Polkovnichenko M., Stroganov O., Chilov G., Lyssenko K., Svitanko I.

Investigation of charge delocalization (redistribution) in a SpnF-catalyzed reaction that proceeds through overlapping Diels–Alder and bis-pericyclic mechanisms has shown that it is better represented as a nonpolar cycloaddition rather than a cationic rearrangement.