### Article

## Highly sensitive spectroscopy based on a surface plasmon polariton quantum generator

A novel method is proposed for highly sensitive surface spectroscopy based on hole burning in the surface plasmon polariton (SPP) quantum generator spectrum due to absorption by analyzed molecules or clusters located *inside* the SPP cavity. The SPP quantum generator spectrum is calculated with an account of inhomogeneous broadening due to variations of the active medium transition frequency. The influence of an analyzed sample on the generation spectrum is demonstrated. The realization of the SPP generator spectroscopy based on a 2D cavity is proposed. It is shown that a SPP quantum generator with a sufficiently large cavity is qualitatively different from the usual laser. In particular, the SPP generation mode is not identical to the passive cavity mode and it appears only due to the active medium. Thus, such kinds of SPP generation cannot be described by the usual single-mode approach and one needs to solve the corresponding spatial problem. The sensitivity of the proposed plasmonic generator intracavity spectroscopy method is calculated.

We propose a method for high-sensitivity subwavelength spectromicroscopy based on the usage of a spaser (plasmonic nanolaser) in the form of a scanning probe microscope tip. The high spatial resolution is defined by plasmon localization at the tip, as is the case for apertureless scanning near-field optical microscopy. In contrast to the latter method, we suggest using radiationless plasmon pumping with quantum dots instead of irradiation with an external laser beam. Due to absorption at the transition frequencies of neighboring nano-objects (molecules or clusters), dips appear in the plasmon generation spectrum. The highest sensitivity is achieved near the generation threshold.

The detection of ultra-low concentration at the level of single molecules has practical importance with regard to the detection of clinically relevant biomarkers in blood serum. The early detection of several diseases, including coronary artery disease, demands detection of corresponding biomolecules at a single-molecule-level.

A novel type of spaser with the net amplification of surface plasmons (SPs) in a doped graphene nanoribbon is proposed. The plasmons in the THz region can be generated in a doped graphene nanoribbon due to nonradiative excitation by emitters like two level quantum dots located along a graphene nanoribbon. The minimal population inversion per unit area, needed for the net amplification of SPs in a doped graphene nanoribbon, is obtained. The dependence of the minimal population inversion on the surface plasmon wave vector, graphene nanoribbon width, doping, and damping parameters necessary for the amplification of surface plasmons in the armchair graphene nanoribbon is studied.

The dynamics of a two-component Davydov-Scott (DS) soliton with a small mismatch of the initial location or velocity of the high-frequency (HF) component was investigated within the framework of the Zakharov-type system of two coupled equations for the HF and low-frequency (LF) fields. In this system, the HF field is described by the linear Schrödinger equation with the potential generated by the LF component varying in time and space. The LF component in this system is described by the Korteweg-de Vries equation with a term of quadratic influence of the HF field on the LF field. The frequency of the DS soliton`s component oscillation was found analytically using the balance equation. The perturbed DS soliton was shown to be stable. The analytical results were confirmed by numerical simulations.

Radiation conditions are described for various space regions, radiation-induced effects in spacecraft materials and equipment components are considered and information on theoretical, computational, and experimental methods for studying radiation effects are presented. The peculiarities of radiation effects on nanostructures and some problems related to modeling and radiation testing of such structures are considered.

Let k be a field of characteristic zero, let G be a connected reductive algebraic group over k and let g be its Lie algebra. Let k(G), respectively, k(g), be the field of k- rational functions on G, respectively, g. The conjugation action of G on itself induces the adjoint action of G on g. We investigate the question whether or not the field extensions k(G)/k(G)^G and k(g)/k(g)^G are purely transcendental. We show that the answer is the same for k(G)/k(G)^G and k(g)/k(g)^G, and reduce the problem to the case where G is simple. For simple groups we show that the answer is positive if G is split of type A_n or C_n, and negative for groups of other types, except possibly G_2. A key ingredient in the proof of the negative result is a recent formula for the unramified Brauer group of a homogeneous space with connected stabilizers. As a byproduct of our investigation we give an affirmative answer to a question of Grothendieck about the existence of a rational section of the categorical quotient morphism for the conjugating action of G on itself.

Let G be a connected semisimple algebraic group over an algebraically closed field k. In 1965 Steinberg proved that if G is simply connected, then in G there exists a closed irreducible cross-section of the set of closures of regular conjugacy classes. We prove that in arbitrary G such a cross-section exists if and only if the universal covering isogeny Ĝ → G is bijective; this answers Grothendieck's question cited in the epigraph. In particular, for char k = 0, the converse to Steinberg's theorem holds. The existence of a cross-section in G implies, at least for char k = 0, that the algebra k[G]G of class functions on G is generated by rk G elements. We describe, for arbitrary G, a minimal generating set of k[G]G and that of the representation ring of G and answer two Grothendieck's questions on constructing generating sets of k[G]G. We prove the existence of a rational (i.e., local) section of the quotient morphism for arbitrary G and the existence of a rational cross-section in G (for char k = 0, this has been proved earlier); this answers the other question cited in the epigraph. We also prove that the existence of a rational section is equivalent to the existence of a rational W-equivariant map T- - - >G/T where T is a maximal torus of G and W the Weyl group.