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New {RuNO} Polyoxometalate [PW11O39RuII(NO)]4-: Synthesis and Reactivity
Inorganic Chemistry. 2013. Vol. 52. No. 16. P. 9675–9682.
Майничев Д. А., Sokolov M. N., Adonin S. A., Sinkevich P. L., Vicent C., Kompankov N. B., Gushchin A. L., Nadolinny V. A., Fedin V. P.
New Ru-substituted Keggin-type polyoxometalate complex containing nitroso ligand, [PW11O39Ru(NO)]4-, has been prepared. It is converted by hydrazin or hydroxylamine into aqua complex [PW11O39RuIII(H2O)]4- in quantitative yield. Intermediate complex of dinitrogen has been detected. Sn2+ converts [PW11O39Ru(NO)]4- into [PW11O39Ru(NH3)]4-.
Язык:
английский