Organometallic derivatives of Rh- and Ir-substituted polyoxotungstates with Keggin structure: reactivity screening by electrospray ionization mass-spectrometry

Dalton Transactions. 2012. Vol. 41. No. 33. P. 9889–9892.

Майничев Д. А., Sokolov M. N., Adonin S. A., Sinkevich P. L., Vicent C., Fedin V. P.

ESI-MS based methodology for the rapid reactivity screening of [PW11O39RhCl]5− and [PW11O39Ir(H2O)]4− toward various metalation-intended substrates (reagents with an activated C–H bond, boronic acids and organotin compounds) is presented. Formation of a series of new organometallic POM derivatives with Rh–R (R = malonate, phenylacetate, CH3, Ph, ferrocenyl) and Ir–R (R = CH3) bonds is reported.

Ключевые слова: математическое и компьютерное моделирование, mathematical and computer modeling, nuclear magnetic resonance, ядерный магнитный резонанс