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(Cyclopentadienyl)neodymium borohydrides with auxiliary N3-heterocyclic ligands
Mendeleev Communications. 2023. Vol. 33. No. 3. P. 357–359.
Guzelia I. Sadrtdinova, Daniil A. Bardonov, Konstantin A. Lyssenko, Minyaev M., Ilya E. Nifant'ev, Dmitrii M. Roitershtein
Mononuclear [CpNd(BH4)2L] borohydrides comprising
L = 1,3,5-trimethyl-1,3,5-triazacyclohexane (Me3tach) and
L = 1,4,7-trimethyl-1,4,7-triazacyclononane (Me3tacn) were
obtained and structurally characterized. Their catalytic
activity in coordination–insertion ring-opening polymerization
of e-caprolactone was studied.
Keywords: crystal structureLanthanide complexesPolymerizationcyclopentadienylциклопентадиенилКомплексы лантанидовborohydridesneodymium complexes
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