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Carbamazepine solubility in supercritical CO2: a comprehensive study
Journal of Molecular Liquids. 2020. Vol. 311. Article 113104.
Kalikin N., Kurskaya M. V., Ivlev D. V., Krestyaninov M. A., Oparin R. D., Kolesnikov A. L., Budkov Y., Idrissi A., Kiselev M. G.
In this paper we present our study of carbamazepine solubility in supercritical carbon dioxide. We have calculated the solubility values along two isochores corresponding to the CO2 densities ρ = 1.1ρcr(CO2) and ρ = 1.3ρcr(CO2), where ρcr(CO2) is the critical density of CO2, in the temperature range from 313 to 383 K, as well as along three isotherms at T = 318, 328 and 348 K by an approach based on the classical density functional theory. The solubility values were also obtained using in situ IR spectroscopy and molecular dynamics simulations along the mentioned isochores and isotherms, respectively. Because the density functional theory only takes into account the Lennard-Jones interactions, it can be expected to underestimate the solubility values when compared to the experimental ones. However, we have shown that the data calculated within the classical density functional theory qualitatively reproduce the solubility trends obtained by IR spectroscopy and molecular dynamics simulation. Moreover, the obtained position of the upper crossover pressure is in good agreement with the experimental literature results
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Beck M. E., Seidov S., Mukhin S., Physical Review A: Atomic, Molecular, and Optical physics 2026
Quantum dissipation is studied in the superradiant phase of the extended Dicke model. It is demonstrated analytically by quantum mechanical derivation of the Lindblad equation for the Dicke model in the superradiant state coupled to Caldeira-Leggett thermal bath that the effective viscosity appearing in the semiclassical equations of motion of polaritonic condensate survives in the zero-temperature limit ...
Added: August 13, 2026
Seidov S., Pugach N., Physical Review B: Condensed Matter and Materials Physics 2026
In this manuscript we consider a superconducting film in the vicinity of the critical temperature and presence of the proximity effect. We analytically solve the corresponding linearized Usadel equation and the self-consistency equation, defining the critical temperature. This is a system of coupled differential and integral equations for the anomalous Green's function and the order parameter of ...
Added: August 13, 2026
Yu Z., Wang J., Wang Z. et al., Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences 2026 Vol. 384 P. 1–16
The integration of data-driven and knowledge-driven approaches in generative geospatial modelling (GGM) is often hindered by their mathematical incompatibilities. Here, we propose a geometric algebra (GA)-based framework that employs a unified multi-vector representation to fuse heterogeneous data and diverse knowledge. The framework facilitates structured reasoning and hypothesis generation through a task-adaptable, five-stage cycle: representation, reasoning, ...
Added: August 13, 2026
Marshakov A., Yung A, Ievlev E. et al., Physical Review D - Particles, Fields, Gravitation and Cosmology 2026 Vol. 114 Article 046006
We continue the study of non-Abelian vortex string in 4D N =2 supersymmetric QCD (SQCD) as
critical superstring, and extend this analysis to UðNÞ gauge theory with arbitrary even N and Nf = 2N
number of quarks. We introduce a special mass deformation and show that the SQCD hadron spectrum is
still given by the string spectrum on the ...
Added: August 13, 2026
Ratnikov F., Bocharnikov V., Journal of High Energy Physics 2026 Vol. 2026 P. 1–21
The BM@N experiment (Baryonic Matter at the Nuclotron) is the first fixed-target experiment at the JINR NICA accelerator complex. In this work, data on the interactions of a carbon-ion beam with kinetic energies of 4.0A GeV and 4.5A GeV with C, Al, Cu, and Pb targets are used to measure transverse momentum spectra and rapidity ...
Added: August 12, 2026
Budkov Y., Kalikin N., Journal of Chemical Physics 2026 Vol. 165 Article 064506
A self-consistent statistical-mechanical theory of the Hall effect in electrolyte solutions is developed by extending the self-consistent Debye–Hückel–Onsager (SCDHO) framework to crossed electric and magnetic fields. The theory incorporates non-local ionic charge distributions via Slater-type form factors, regularizing the Coulomb interaction at short range, and accounts for dielectric friction through ion-specific coefficients, employing experimental values ...
Added: August 12, 2026
Speranski S. O., Математические заметки 2026 Т. 120 № 3 С. 470–483
We show that, in terms of closure ordinals, many infinitary calculi for ‘first-order’ logics of probability (i.e., for languages similar to those in [Abadi & Halpern 1994]) are as hard as possible: the corresponding closure ordinals coincide with the least non-constructive ordinal, denoted by $\omega_1^{\mathrm{CK}}$. ...
Added: August 12, 2026
Ali S., Bocharnikov V., Ratnikov F. et al., Sensors 2026 Vol. 26 No. 16 Article 5024
Large distributed sensor arrays require repeated recalibration as radiation damage, material aging, gain variation, and readout drift alter channel responses. We studied a high-granularity calorimeter as a large sensor array and addressed unsupervised recalibration from two unpaired datasets: a nominal reference response and an aged response with attenuated cell-wise signals. Aging was modeled by a ...
Added: August 11, 2026
Kulev Y., Maksaev A., Promyslov V., Linear Algebra and its Applications 2026 Vol. 730 P. 51–72
The notion of λ-th upper scrambling index was introduced by Huang and Liu in 2010, as a generalization of a notion considered by Akelbek and Kirkland in 2009. For a primitive digraph D, it is defined as the smallest positive integer k such that for every λ vertices of D there exist directed paths of lengths k from these vertices to a common vertex. This ...
Added: August 7, 2026
Kanunnikov A., Promyslov V., Vassilieva E., Electronic Journal of Combinatorics 2024 Vol. 31 No. 3 Article P3.6
Introduced by Goulden and Jackson in their 1996 paper, the matchings-Jack conjecture and the hypermap-Jack conjecture (also known as the b-conjecture) are two major open questions relating Jack symmetric functions, the representation theory of the symmetric groups and combinatorial maps. They show that the coefficients in the power sum expansion of some Cauchy sum for ...
Added: August 7, 2026
Ponomarev A., Aleksandrov N., Journal of Physics D: Applied Physics 2026 Vol. 59 Article 315205
Electron attachment and detachment in H2O:O2 and H2O:air mixtures are theoretically studied at moderate (40–100 Td) reduced electric fields. It is shown that there are two synergistic mechanisms of ultra-rapid electron detachment from negative ions in these mixtures, whereas these detachment channels are absent in pure gases. Effective attachment coefficient calculated with consideration for fast ion–molecule ...
Added: August 6, 2026
Khrapai V., Tikhonov E., Nature Physics 2026 P. 1–2
Feng et al.1 presented transport measurements of three-terminal normal–superconductor–normal devices based on topological insulator nanowires. They measured the full differential conductance matrix, defined as Gij = ∂Ii /∂Vj , beyond the linear response regime as a function of various control parameters. Here i, j∈ [1, 2] denote normal terminals biased by the voltages V1 and ...
Added: August 5, 2026
Spiridonov V. P., Belousov N. M., Sarkissian G. A., Analysis and Mathematical Physics 2026 Vol. 16 Article 96
Hyperbolic hypergeometric integrals are defined as Barnes-type integrals of products of hyperbolic gamma functions. Their reduction to ordinary hypergeometric functions is well known. We study in detail their degeneration to complex hypergeometric functions. Namely, using uniform bounds on the integrands, we prove that the univariate hyperbolic beta integral and the conical function degenerate to two-dimensional ...
Added: August 4, 2026
Gayfullin S., Kikteva V., Results in Mathematics 2026 Vol. 81 No. 5 Article 146
In this paper we obtain a criterion of flexibility for an affine complexity-zero horospherical variety. This result generalizes previously known results on flexibility of normal horospherical varieties, horospherical varieties with an action of a semisimple group, and non-normal toric varieties. ...
Added: August 3, 2026
Lunts V., Функциональный анализ и его приложения 2026 Т. 60 № 3 С. 127–129
Доказано, что канонические полуортогональные разложения производной категории диаграммной схемы индуцируют аналогичные разложения подкатегории совершенных комплексов. ...
Added: August 3, 2026
Belomestny D., Gasnikov A., Gladin E. et al., Russian Mathematical Surveys 2026 Vol. 81 No. 4(490) P. 3–90
Reinforcement learning (RL) is increasingly grounded in tools from probability, optimization, and operator theory. This survey organizes the mathematical structures that underpin the design and analysis of modern algorithms in RL. We begin from Markov decision processes (MDPs) and the Bellman operators, emphasizing contraction mappings, monotonicity, and fixed-point theory that yield convergence guarantees and rates ...
Added: August 3, 2026
G. G. Bondarenko, Kristya V. I., Savichkin D. O. et al., Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques 2026 Vol. 20 No. 2 P. 417–423
A model of a glow gas discharge in a mixture of argon and mercury vapor is formulated in the presence
of a thin insulating film on the cathode surface. Dependences of the discharge characteristics on the
mixture temperature are calculated in the range of its variation, in which a noticeable contribution to ionization
of the working gas is ...
Added: August 1, 2026
Касимов Р. Х., Аржанов А. И., Седых К. О. et al., Оптический журнал 2026 Т. 93 № 1 С. 80–86
Предмет исследования. Использование метода капельного нанесения для изготовления источника одиночных фотонов. Цель работы. Разработка технологического процесса изготовления источника одиночных фотонов на коллоидных квантовых точках для использования их в фотон- ных интегральных схемах. Метод. На первом этапе в программе ANSYS Lumerical рассчитыва- ются период и фактор заполнения фокусирующих элементов связи на длинах волн 545 и 600 ...
Added: July 31, 2026
Loubenets E. R., / Series arxiv.org "quant-ph". 2026. No. 2607.18050.
In many quantum applications it is important to know whether or not a Bell nonlocal two-qudit state exhibits its nonlocality under correlation scenarios with some given numbers S1,S2≥1 of generalized quantum measurements at two sites. In the present article, we find analytically a new general locality condition sufficient for a nonseparable Werner state with a ...
Added: July 21, 2026
Bolbachan V., / Series math "arxiv.org". 2024.
Chow polylogarithms are some special functions arising in explicit description of the Beilinson regulator map. The most interesting functional equation for this function reflects its vanishing on the boundary in the Bloch's cycle complex. We show that this functional equation formally follows from more simple ones, namely skew-symmetry, functoriality and multiplicativity.
To prove this, we study ...
Added: July 16, 2026
Bolbachan V., / Series math "arxiv.org". 2024.
Let K be a field of characteristic zero. We prove that its motivic cohomology in degree m−1 and weight m is rationally isomorphic to the cohomology of the polylogarithmic complex. This gives a partial extension of A. Suslin theorem describing the indecomposable K3 of a field. ...
Added: July 16, 2026
Panov V., Ryabchenko A., / Series arXiv "stat.ME". 2026. No. 2607.05048.
This paper investigates the problem of statistical inference for a mixture distribution consisting of a discrete and a continuous component, with a particular focus on the class of rational-infinitely divisible distributions. We consider non-parametric estimation of both components of the mixture as well as the quasi-L{é}vy measure, assuming that the mixture belongs to the class ...
Added: July 9, 2026
Konakov V., Kucher D., Mammen E., / Series arXiv "math". 2026. No. 2606.11142v1.
In this paper, we construct strong approximations for discrete-time Markov chains weakly converging to continuous diffusion processes, as well as for their perturbed counterparts. Under the assumption of bounded coefficients, we construct closely coupled versions of these processes on a shared probability space. In particular, for both non-degenerate and degenerate cases, we maximize the probability ...
Added: June 11, 2026
Malikov D., Krasnov L., Kiseleva M. et al., Scientific data 2026 Vol. 13 Article 727
Solubility is a crucial property of organic compounds, impacting their potential applications in synthetic chemistry, materials science and drug design. Moreover, in technological processes mixtures of solvents are often utilized, making the solubility assessment more complicated. Predicting solubility values in mixtures of solvents from a molecular structure can help to address this issue, although a ...
Added: May 19, 2026