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  • Измерение параметров монослоев Ленгмюра на поверхности жидкости методом поверхностной дифракции при помощи синхротронного излучения
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News
July 15, 2026
Economists Propose More Effective Approach to Reducing Smoking
Economists at HSE University have examined how smokers respond to changes in cigarette prices. When tobacco prices increase, cigarette consumption does not always decline. In fact, spending on tobacco may even rise: according to the researchers, a 1% decrease in cigarette affordability leads to a 0.28% increase in per capita tobacco expenditure. The findings suggest that to reduce smoking rates, tobacco prices must rise faster than household incomes. The study has been published in Voprosy Statistiki.
July 15, 2026
HSE MIEM Students to Develop Two Satellites from Scratch for Orbital Experiments
The devices, created by student teams, will conduct space research on the properties of promising solar cells, on-board energy storage systems, and serial electronics for student satellites.
July 13, 2026
Biologists Discover Unique Properties of MiR-93-5p MicroRNA in Prostate Cancer
Researchers at the International Laboratory of Microphysiological Systems of the HSE Faculty of Biology and Biotechnology investigated how different isoforms of the same microRNA influence gene function in prostate adenocarcinoma. The study found that in some cases, microRNAs can reinforce each other’s effects by targeting and suppressing the same genes. This finding offers a fresh perspective on the molecular mechanisms underlying tumour development and on the search for disease biomarkers. The results have been published in PeerJ.

 

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Измерение параметров монослоев Ленгмюра на поверхности жидкости методом поверхностной дифракции при помощи синхротронного излучения

С. 248–249.
Prutskov G. V.
Language: Russian
Full text
Keywords: Langmuir-Blodgett filmsX-ray scatteringпленки Ленгмюра-Блоджеттx-ray diffractionсинхротронное излучениеLangmuir monolayersgrazing incidence diffractionsynchrotron radiationрассеяние рентгеновских лучейрентгеновская дифракция в скользящей геометрииамфифильные молекулы

In book

Научно-техническая конференция студентов, аспирантов и молодых специалистов НИУ ВШЭ. Материалы конференции
Научно-техническая конференция студентов, аспирантов и молодых специалистов НИУ ВШЭ. Материалы конференции
М.: МИЭМ НИУ ВШЭ, 2014.
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A new bis(cyclopentadienyl) terbium(III) complex with 1,2,4-triphenylcyclopentadienyl and 4,4,4-trifluoro-1-phenylbutane-1,3-dionate ligands was synthesized. Single-crystal X-ray analysis revealed a mononuclear bis(cyclopentadienyl) complex with a diketonate ligand in the bisector plane. The compound under study exhibits a ligand ligand charge transfer state (LLCT), according to optical spectroscopy and crystallographic data. ...
Added: February 19, 2026
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Added: February 10, 2026
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in the presence of 1,3,5-trimethyl-1,3,5-triazacyclohexane (Me3tach) gives complexes of the type [Cp'Y(Me3tach)Cl2] (Cp' = Ph2C5H3 (CpPh2) (I), Ph3C5H2 (CpPh3) (II), Ph4C5H (CpPh4) (III). The molecular structure of complexes I–III was established by X-ray diffraction (CCDC nos. 2406644 (I), 2406645 (II), 2406646 (III)). The main structural parameters of all of the obtained monocyclopentadienyl complexes were similar, irrespective of the number ...
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Quantum theory of synchrotron radiation from charged massless fermions
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This work is the first, to the best of our knowledge, to study synchrotron radiation (SR) from a massless charged electron based on the quantum theory of radiation using exact solutions of the Dirac equation in a constant magnetic field. The cases of (2 + 1)-dimensional and (3 + 1)-dimensional quantum electrodynamics are considered separately, and the ...
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1,2,4-ТРИФЕНИЛЦИКЛОПЕНТАДИЕНИЛЬНЫЕ КОМПЛЕКСЫ ПРАЗЕОДИМА И ЭРБИЯ
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reaction of triphenylcyclopentadienyl potassium with praseodymium and erbium chloride tetrahydrofuranates gives, depending on the reactant ratio, tetranuclear ate complexes, [{(Ph3C5H2)Pr(THF)}2(μ2-Cl)2(μ3-Cl)3K]2(C7H8)4 (I) and [{(Ph3C5H2)Er(THF)}2(μ2-Cl)2(μ3-Cl)3K(THF)]2 (III), or binuclear ate complexes [(Ph3C5H2)2LnCl(KCl)]2 Ln = Pr (II), Er (IV) (CCDC no. 2224244 (I), 2224243 (II), 2224245 (III), 2224242 (IV)). The structurally similar complexes I and III are based on the {[Ln2(μ-Cl)3]2(μ-Cl)2K2} core, and ...
Added: January 28, 2024
Lanthanide Tris-2-(quinolyl-8-iminomethyl)phenolates: Synthesis and Structures
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The reactions of sodium 2-(quinolyl-8-iminomethyl)phenolate with rare-earth element chlorides afford homoleptic mononuclear complexes [Ln{2-(8-quinolyl)N=CH–C6H4O}3] (Ln = La (I), Nd (II), Eu (III), and Tb (IV)) with the nonacoordinated rare-earth element ion. All synthesized complexes are similar in structure, and complexes II, III, and IV are isostructural (CIF files CCDC nos. 2124365 (I), 2124364 (II), 2124366 ...
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Crystallization of Niobium Alkali-Silicate Glasses Under Thermal Poling
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Crystallization of a Na 2 O-K 2 O-Nb 2 O 5 -SiO 2 glass under thermal poling and subsequent annealing was studied by Raman spectroscopy and X-ray diffractometry. It was found that the poling and subsequent thermal treatment lead to partial crystallization of the poled region of the glass, which should be related with watering ...
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This paper is a brief summary of the results of long-term experimental studies of C60Hx hydrofullerites with a hydrogen content of up to x ~ 60 or more, obtained by loading C60 fullerites with hydrogen at pressures up to 9 GPa and temperatures up to 500°C. Basically, this is an overview of already published data. Some results for ...
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Added: October 29, 2021
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A new inhibitor of phosphodiesterase (PDE), i.e., nitric oxide (NO) donor, a water soluble DNIC Na[Fe(C7H5N4S)2(NO)2]⋅2.5H2O (1), has been synthesized. The structure of the new complex, its physical-chemical properties in the solid state and in solutions have been studied experimentally (X-ray analysis, IR, UV-Vis, Mossbauer spectroscopy, mass-spectrometry, and amperometry) and theoretically (quantum-chemical modeling by DFT ...
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Удивительный пример сохранения необычной куполообразной структуры 3,5-ди-(трет-бутил)-2-оксиазобензола PDII в кристалле и газовой фазе
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New cobalt‐iron chalcogenide clusters C5HMe4Co(CO)E2Fe2(CO)6 (E = Se, Te) were prepared and characterized by IR and NMR spectroscopy; their structures were determined by single‐crystal XRD. Catalysts consisting of nanoparticles of bimetallic chalcogenides of cobalt and iron deposited on highly dispersed carbon black Vulcan XC‐72 were made from the synthesized clusters. Structural characteristics of these catalysts were ...
Added: March 10, 2021
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The reactions of lanthanum and neodymium triphenylacetates with polydentate 6- and 18-membered N- and O-heterocyclic ligands give various types of mononuclear triphenylacetate complexes containing a polydentate auxiliary ligand (neutral or cationic and anionic): [Nd(Ph3CCOO)(3)(Me(3)TACH)] center dot CHCl3 (II), [La(Ph3CCOO)(4)(Me(3)TACH)](-)[NH4Me](+) (III), [La(Ph3CCOO)(3)(18-crown-6)] (IV), and [Nd(Ph3CCOO)(2)(18-crown-6)](+)[Nd(Ph3CCOO)(4)](-) (V) and binuclear complex [La-2(Ph3CCOO)(3)-(Me(3)TACH)] center dot 2C(6)H(5)CH(3) (I) (CIF files ...
Added: September 3, 2020
Meet the Cerium(IV) Phosphate Sisters: CeIV(OH)PO4 and CeIV2O(PO4)2
Shekunova T. O., Mironov A. V., Istomin S. et al., Chemistry - A European Journal 2020 Vol. 26 P. 12188–12193
Two novel cerium(IV) phosphates were obtained: cerium(IV) hydroxidophosphate, Ce(OH)PO4, and cerium(IV) oxidophosphate, Cе2O(PO4)2, which were shown to complement the classes of isostructural compounds M(OH)PO4 and R2O(PO4)2, where M = Th, U and R = Th, U, Np, Zr. Cе2O(PO4)2 oxidophosphate is formed by elimination of H2O from the crystal structure of Ce(OH)PO4 during its thermal ...
Added: July 2, 2020
Рентгеновская топография: вчера, сегодня и перспективы
Суворов Э. В., Поверхность. Рентгеновские, синхротронные и нейтронные исследования 2018 № 9 С. 3–22
X-ray topography is a complex of X-ray diffraction methods allowing one to detect the images of defects, to determine their type, the arrangement in a crystal structure volume or on its surface, to measure their basic characteristics. The possibilities, limitations and prospects of X-ray topography methods are discussed in the given work. ...
Added: November 21, 2019
The first example of group 13 elements triacetate with an infinite chain crystal structure
Churakov A. V., Vinokurov A. A., Znamekov K. O. et al., Polyhedron 2019 Vol. 160 P. 42–45
Single crystals of In(CH3COO)3 have been prepared by dissolution of basic indium carbonate In(OH)CO3 in a mixture of anhydrous acetic acid and acetic anhydride. The crystal structure of In(CH3COO)3 has been solved and refined for the first time using single crystal X-ray diffraction data [space group P21, a=8.0770(10) Å, b=7.6481(10) Å, c=8.0859(10) Å, β = ...
Added: May 29, 2019
Synthesis and characterization of an Fe(I) cage complex with high stability towards strong H-acids
Roitershtein D., Voloshin Y., Novikov V. et al., Chemical Communications 2018 No. 28 P. 3436–3439
The first synthesized and X-ray structurally characterized ‘‘classical’’ iron(I) dioximate showed an unrivaled stability towards strong acids, thus calling for a reassessment of the origins of the electrocatalytic activity of similar low-valent cobalt and iron cage complexes with electron-withdrawing ribbed substituents, shown previously to be effective electrocatalysts of the HER ...
Added: October 19, 2018
Polyphenylcyclopentadienyl ligands as an effective light-harvestig π-bonded antenna for lanthanide +3 ions
Roitershtein D., Puntus L., Nifant'ev I. et al., Inorganic Chemistry 2018 Vol. 57 No. 16 P. 10199–10213
A new approach to design “antenna-ligands” to enhance the photoluminescence of lanthanide coordination compounds based on π-type ligand - polyphenylsubstituted cyclopentadienyl has been developed. The complexes of di-, tri- and tetraphenyl cyclopentadienyl ligands with Tb and Gd has been synthesized and all the possible structural types from mononuclear to di- and tetranuclear as well as ...
Added: October 18, 2018
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