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  • Удивительный пример сохранения необычной куполообразной структуры 3,5-ди-(трет-бутил)-2-оксиазобензола PDII в кристалле и газовой фазе
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Subject
News
September 15, 2026
Immunity to Chaos: How Personal Resources Help Us Cope with the Challenges of a Turbulent World
International conflicts, crises and digital overload—the modern world puts our minds to the test every day. Traditional psychology often focuses on the consequences: anxiety, depression, and psychosomatic disorders. But what if we looked at the problem differently—through the lens of the resources that prevent us from breaking down? Psychological immunity is precisely this set of resources. Alena Zolotareva and her group, Psychological Immunity as a Resource for Positive Functioning, are developing an integrative model of this phenomenon, adapting diagnostic tools and preparing for large-scale empirical research. Why do psychologists need to collaborate with medical professionals, and how could their research transform preventive care in clinics and corporations?
September 11, 2026
How to Assess Students Knowledge in the Age of AI
A researcher at HSE University has proposed a flowchart to help lecturers decide how to assess students who use artificial intelligence. It shows where the use of AI should be restricted and where it can be incorporated into the learning process. The article has been published in IT Professional.
September 9, 2026
‘Balkan Hospitality Opens Doors: Studying Dialects on the Verge of Extinction
You cannot study spoken dialects from books. Instead, you need to go to a village, seek out its elders, and earn the trust of local residents before you can record hours of spontaneous stories. This is how Natalia Muravleva, Associate Professor at the Faculty of Humanities, conducts her research. Her internship in Serbia continued her long-standing study of dialects spoken by Macedonian settlers. In this interview, she discusses how diaspora cultural centres help researchers reach informants, why native speakers need to be interviewed only in their own language (otherwise, as she puts it, they may 'break'), and how a single field season helped her finalise her monograph. She also shares warm memories of autumn in Belgrade and of colleagues with whom grammar can be discussed in three languages at once.

 

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Удивительный пример сохранения необычной куполообразной структуры 3,5-ди-(трет-бутил)-2-оксиазобензола PDII в кристалле и газовой фазе

Известия РАН. Серия химическая. 2021. Т. 70. № 5. С. 847–856.
Tkachev V., Bozhenko K., Utenyshev A., Алдошин С. М., Gutsev L.

The structure of the newly synthesized palladium(ii) 3,5-di(tert-butyl)-2-oxyazobenzene, PdL2, was determined by X-ray diffraction. The metal chelate was found to adopt an unusual domed conformation, with the trans-planar coordination unit at the top. This is the first complex of this class, the domed structure of which was confirmed by X-ray diffraction and in which the planes of the ligands are cis with respect to the coordination unit. Quantum chemical calculations were performed to examine the possibility of the existence in the gas phase of the compound PdL2 with this unusual structure and of related Pd- and Ni-based model complexes.

Research target: Chemistry
Priority areas: engineering science
Language: Russian
Full text
DOI
Keywords: структураx-ray diffractionstructurepalladium quantum chemical calculationsквантово-химические расчетыmetal chelatesazo compoundsisomerismДифракция рентгеновских лучейхелаты металловизомерия
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Stress tensor of inhomogeneous flexible polymer chain solutions beyond the ground-state dominance approximation
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“-Ethylene” vs “-ethane”: How minor cation variations drive the self-assembly of structurally different supramolecular diiodine-halometalate hybrid complexes
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From Small Data to High Capacity: Symbolic Learning of Sodium-Ion Cathode Materials
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Monometallic Ln3+ and heterometallic Ln3+–Cd2+ complexes based on pentafluorophenylacetic acid: efficient control of dimension and luminescent properties
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Added: August 26, 2026
Understanding the electric double layer at electrode–electrolyte interfaces, Part III: crystallographic-face dependence of silver capacitance in aqueous NaF solutions
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Added: February 12, 2026
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