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## Advances in Chemistry Research

We single out the main features of the mathematical theory of noble gases. It is proved that the points of degeneracy of the Bose gas fractal dimension in momentum space coincide with the critical points of noble gases, while the jumps of the critical indices and the Maxwell rule are related to tunnel quantization in thermodynamics. We consider semiclassical methods for tunnel quantization in thermodynamics as well as those for second and ultrasecond quantization (the creation and annihilation operators for pairs of particles). Each noble gas is associated with a new critical point of the limit negative pressure. The negative pressure is equivalent to covering the (P,Z) diagram by the second sheet.

We single out the main features of the mathematical theory of noble gases. It is proved that the points of degeneracy of the Bose gas fractal dimension in momentum space coincide with the critical points of noble gases, while the jumps of the critical indices and the Maxwell rule are related to tunnel quantization in thermodynamics. We consider semiclassical methods for tunnel quantization in thermodynamics as well as those for second and ultrasecond quantization (the creation and annihilation operators for pairs of particles). Each noble gas is associated with a new critical point of the limit negative pressure. The negative pressure is equivalent to covering the (P,Z)- diagram by the second sheet.

We single out the main features of the mathematical theory of noble gases. It is proved that the points of degeneracy of the Bose gas fractal dimension in momentum space coincide with the critical points of noble gases, while the jumps of the critical indices and the Maxwell rule are related to tunnel quantization in thermodynamics. We consider semiclassical methods for tunnel quantization in thermodynamics as well as those for second and ultrasecond quantization (the creation and annihilation operators for pairs of particles). Each noble gas is associated with a new critical point of the limit negative pressure. The negative pressure is equivalent to covering the (P,Z)- diagram by the second sheet.

We study the case where the values of random variables increase without bound.

A model for organizing cargo transportation between two node stations connected by a railway line which contains a certain number of intermediate stations is considered. The movement of cargo is in one direction. Such a situation may occur, for example, if one of the node stations is located in a region which produce raw material for manufacturing industry located in another region, and there is another node station. The organization of freight traﬃc is performed by means of a number of technologies. These technologies determine the rules for taking on cargo at the initial node station, the rules of interaction between neighboring stations, as well as the rule of distribution of cargo to the ﬁnal node stations. The process of cargo transportation is followed by the set rule of control. For such a model, one must determine possible modes of cargo transportation and describe their properties. This model is described by a ﬁnite-dimensional system of diﬀerential equations with nonlocal linear restrictions. The class of the solution satisfying nonlocal linear restrictions is extremely narrow. It results in the need for the “correct” extension of solutions of a system of diﬀerential equations to a class of quasi-solutions having the distinctive feature of gaps in a countable number of points. It was possible numerically using the Runge–Kutta method of the fourth order to build these quasi-solutions and determine their rate of growth. Let us note that in the technical plan the main complexity consisted in obtaining quasi-solutions satisfying the nonlocal linear restrictions. Furthermore, we investigated the dependence of quasi-solutions and, in particular, sizes of gaps (jumps) of solutions on a number of parameters of the model characterizing a rule of control, technologies for transportation of cargo and intensity of giving of cargo on a node station.

For a class of optimal control problems and Hamiltonian systems generated by these problems in the space *l *2, we prove the existence of extremals with a countable number of switchings on a finite time interval. The optimal synthesis that we construct in the space *l *2 forms a fiber bundle with piecewise smooth two-dimensional fibers consisting of extremals with a countable number of switchings over an infinite-dimensional basis of singular extremals.

The problem of minimizing the root mean square deviation of a uniform string with clamped ends from an equilibrium position is investigated. It is assumed that the initial conditions are specified and the ends of the string are clamped. The Fourier method is used, which enables the control problem with a partial differential equation to be reduced to a control problem with a denumerable system of ordinary differential equations. For the optimal control problem in the l2 space obtained, it is proved that the optimal synthesis contains singular trajectories and chattering trajectories. For the initial problem of the optimal control of the vibrations of a string it is also proved that there is a unique solution for which the optimal control has a denumerable number of switchings in a finite time interval.

This proceedings publication is a compilation of selected contributions from the “Third International Conference on the Dynamics of Information Systems” which took place at the University of Florida, Gainesville, February 16–18, 2011. The purpose of this conference was to bring together scientists and engineers from industry, government, and academia in order to exchange new discoveries and results in a broad range of topics relevant to the theory and practice of dynamics of information systems. Dynamics of Information Systems: Mathematical Foundation presents state-of-the art research and is intended for graduate students and researchers interested in some of the most recent discoveries in information theory and dynamical systems. Scientists in other disciplines may also benefit from the applications of new developments to their own area of study.

In this paper, we construct a new distribution corresponding to a real noble gas as well as the equation of state for it.