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NaFe0.5Mn0.5PO4–Ge electrochemical system for sodium-ion batteries
Mendeleev Communications. 2023. Vol. 33. No. 3. P. 318–319.
Kudryashova Y., Gavrilin I., Tatiana L. Kulova, Svetlana A. Novikova, Skundin A.
A new electrochemical system for sodium-ion batteries, sodium iron-manganese phosphate–germanium nanowires,
has been developed and tested. The laboratory batteries possessed an average discharge voltage of ~2.0 V and an
energy density based on the weight of active materials to 210 Wh kg–1.
Language:
English
Makarov D. M., Kalikin N., Fashchevsky K. A. et al., Electrochimica Acta 2026 Vol. 579 Article 150159
Machine learning (ML) has become a powerful tool for accelerating the development of carbon-based supercapacitors;
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porous carbons and hybrid carbon electrodes. Here, we test this assumption using a comprehensive
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Shi R., Yu Y., Chibisov A., International Journal of Hydrogen Energy 2025 Vol. 107 P. 52–62
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Zhukov A., Chen F., Zeng Y. et al., Nanoscale 2026 Vol. 18 No. 36 P. 19223–19253
Colloidal semiconductor nanocrystals have emerged as promising materials for next-generation light-emitting diodes (LEDs) owing to their solution processability, tunable emission wavelengths, narrow emission linewidths, and high photoluminescence quantum yields. Among them, anisotropic nanocrystals, including one-dimensional nanorods (NRs) and two-dimensional nanoplatelets (NPLs), offer additional opportunities for controlling transition dipole moment orientation and light out-coupling efficiency. These ...
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Мальцева В. Е., Ananyev I., Milevskii N. et al., Molecular Systems Design and Engineering 2026 Vol. 11 No. 7 P. 691–704
The use of hydrophobic deep eutectic solvents (DESs) as extractants for metal ion separation is largely due to the ease of their preparation and the possibility of modifying them depending on the composition of the metal mixture to be separated. However, the most common approach to DES modification involves the replacement of the extractant, while ...
Added: October 2, 2026
Мальцева В. Е., Ananyev I., Golubev A. V. et al., Russian Journal of Inorganic Chemistry 2026 Vol. 71 P. 724–736
Two voluminous polymer silver(I) salts of perchlorinated dodecoborate clusters, {[(Me2CO)Ag(μ-Me2CO)2Ag(Me2CO)][μ-B12Cl12]}n (1) and {[DMFAg(μ-DMF)2AgDMF][μ-B12Cl12]}n (2) were synthesized. The 35Cl nuclear quadrupole resonance (NQR) spectroscopy supplemented with the X-ray diffraction data was applied for identifying and analyzing noncovalent interactions Cl···X in these salts. Whereas in X-ray diffraction, noncovalent interactions are associated with the presence of the shortened ...
Added: October 2, 2026
Мальцева В. Е., Rozhkov A., Ananyev I. et al., Inorganic Chemistry 2026 Vol. 65 No. 22 P. 12484–12496
Despite the well-established importance of chalcogen bonding in crystal engineering and supramolecular chemistry, experimental charge density data for TeII-centered chalcogen bonds have remained entirely absent, leaving the electronic nature of these interactions uncharacterized at the level of directly measured electron density. Here, we report the first high-resolution X-ray diffraction (HRXRD) study of TeII-centered chalcogen bonds, ...
Added: October 2, 2026
Sharov V., Pavlov A., Eliseyev I. et al., Advanced Optical Materials 2025 Vol. 13 No. 30 Article e01821
Strain engineering is a powerful tool for the development of nanostructured semiconductor devices. In this work, the effect of high external elastic strain is investigated on the photoluminescence of GaN nanowires (NWs). Individual horizontal NWs are strained to bending strains up to 2.2% using an atomic force microscope (AFM) probe. Novel nanomanipulation techniques for mechanical ...
Added: November 12, 2025
E. V. Shpagina, E. S. Tikhonov, Ruhstorfer D. et al., Physical Review B: Condensed Matter and Materials Physics 2025 Vol. 112 No. 14 Article L140503
We investigate a nonequilibrium aspect of the current-driven superconducting-normal phase transition in floating Al islands of epitaxial full-shell Al/InAs nanowires. Within a transition region discontinuous voltage jumps and hysteretic behavior of the I-V characteristics are observed, associated with the destruction and recovery of the superconducting order parameter in the island. The strength of the two ...
Added: November 9, 2025
Novikova S., Kabanov D. A., Kovtushenko E. et al., Ionics 2024 Vol. 30 P. 6151–6161
The cathode material of Na2/3Ni1/3Mn2/3O2 composition (NNMO) was obtained by the carbonate coprecipitation followed by solid-phase reaction and characterized by XRD analysis, ICP-MS, electron and impedance spectroscopy. NNMO crystallizes in a P2-type layered hexagonal structure (sp. gr. P63/mmc), consists of spherical agglomerates of ~1 - 3 microns in size, formed from the plate-like primary grains. ...
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Dubrovskii V., Cirlin G., Kirilenko D. et al., Nanoscale Horizons 2024 Vol. 9 No. 12 P. 2360–2367
Increasing the InN content in the InxGa1xN compound is paramount for optoelectronic applications. It has been demonstrated in homogeneous nanowires or deliberately grown nanowire heterostructures. Here, we present spontaneous core–shell InxGa1xN nanowires grown by molecular beam epitaxy on Si substrates at 625 C. These heterostructures have a high InN fraction in the cores around 0.4 ...
Added: November 23, 2024
Gridchin V. O., Dragunova A., Kotlyar K. P. et al., Journal of Physics: Conference Series 2021 Vol. 2086 Article 012013
The influence of the growth time on the structural properties of InGaN nanowires grown on Si substrate by plasma-assisted molecular beam epitaxy are studied. Under appropriate other growth conditions, the growth for 2h leads to the formation of separated nanowires, whereas the growth for 2h 30min and 3h leads to the formation of nanostructures such ...
Added: May 31, 2024
Седов В. С., Мартьянов А. К., Тяжелов И. А. et al., Diamond and Related Materials 2024 P. 111169
The annealing treatment plays a crucial role in tailoring the properties of synthetic diamond materials, especially those doped with various elements in order to form specific color centers like nitrogen-vacancy (NV), silicon-vacancy (Si-V), germanium-vacancy (Ge-V), etc. This study delves into the annealing of 175 μm-thick Ge-doped polycrystalline diamond (PCD) films grown by microwave plasma-assisted chemical vapor ...
Added: May 16, 2024
Жуков А. А., И. E. Батов, Журнал экспериментальной и теоретической физики 2024 Т. 165 № 3 С. 424–437
We report on the low temperature measurements of the magnetotransport in Si-doped InAs quantum wire in the presence of a charged tip of an atomic force microscope serving as a mobile gate, i.e. scanning gate microscopy (SGM). By altering the carrier concentration with back gate voltage, we transfer the wire through several transport regimes: from ...
Added: April 14, 2024
E. V. Shpagina, Tikhonov E., Ruhstorfer D. et al., Physical Review B: Condensed Matter and Materials Physics 2024 Vol. 109 No. 14 Article L140501
We investigate the impact of transport current on the superconducting order parameter in superconducting islands in full-shell epitaxial Al-InAs nanowires. Depending on the device layout, the suppression of superconductivity occurs in three fundamentally different ways-by a critical current in the case of superconducting reservoirs and by a critical voltage or by a critical Joule power ...
Added: April 2, 2024
Mankaev B., Serova V., Syroeshkin M. et al., European Journal of Inorganic Chemistry 2023 Vol. 26 No. 11 Article e202200690
A series of novel tetrylenes based on three 2,6-bis(2-hydroxyphenyl)pyridines has been obtained by the reaction of Lappert’s tetrylenes E[N(SiMe3)2]2 (E=Ge, Sn) with corresponding tridentate pyridine-linked phenol-based ligands. It was found that the structure of the ligand and the size of the atom of the group 14 element drastically affect the structure of the reaction product. ...
Added: February 14, 2024
Gavrilov S., Gavrilin I., Martynova I. et al., Batteries 2023 Vol. 9 No. 9 Article 445
Germanium–cobalt–indium nanostructures were synthesized via cathodic electrodeposition
from aqueous complex solutions of Ge (IV) and Co (II) with drop-like indium crystallization centers.
This approach features simplicity, avoids heating and allows using cheaper GeO2 instead of pure
Ge as starting material. Further, in this case, target nanostructures grow directly upon the substrate.
Various analytical methods (scanning electron microscopy, transmission electron ...
Added: January 25, 2024
Shugabaev T., Gridchin V. O., Sergey D. Komarov et al., Nanomaterials 2023 Vol. 13 No. 6 Article 1069
Hybrid nanostructures based on InGaN nanowires with decorated plasmonic silver nanoparticles are investigated in the present study. It is shown that plasmonic nanoparticles induce the redistribution of room temperature photoluminescence between short-wavelength and long-wavelength peaks of InGaN nanowires. It is defined that short-wavelength maxima decreased by 20%, whereas the long-wavelength maxima increased by 19%. We ...
Added: July 3, 2023
Reznik R. R., Gridchin V. O., Kotlyar K. P. et al., St. Petersburg Polytechnical University Journal: Physics and Mathematics 2023 Vol. 16 No. 1.1 P. 153–157
AlGaAs nanowires with InAs quantum dots on the silicon surface were synthesized by molecular-beam epitaxy. Morphological and optical properties of grown nanostructures were studied. It is important to note, that emission from quantum dots is observed in the wavelength range from 780 to 970 nm. Assumptions about the nature of short-wave radiation from quantum dots ...
Added: July 3, 2023
S. D. Komarov, Gridchin V. O., Lendyashova V. V. et al., St. Petersburg Polytechnical University Journal: Physics and Mathematics 2023 Vol. 16 No. 1.2 P. 114–120
In this work, the photoluminescence of single InGaN NWs with a core-shell structure is investigated along their entire length at RT and 77 K. Multicolor emission, covering the spectral range from 380 to 650 nm, was obtained and described in details. Using the modified Vegard’s law, the photoluminescence lines were correlated with the InGaN composition. ...
Added: July 3, 2023
Tatiana L. Kulova, Skundin A., Gavrilin I. et al., Batteries 2022 Vol. 8 No. 8 Article 98
Nanostructure composites Ge-Co-P with brutto-composition CoGe2P0.1, or CoGe2@GePwere manufactured via electrolysis of aqueous electrolyte. Such composites are able to reversibleinsertion of lithium and sodium with specific capacities up to 855 and 425 mAh/g, respectively. Themain advantage of the composites consists in their excellent cycleability. ...
Added: January 21, 2023
Воропаева Д. Ю., Novikova S., Yaroslavtsev A. B., Успехи химии 2020 Т. 89 № 10 С. 1132–1155
Рассмотрены полимерные электролиты для литий- и натрий-ионных аккумуляторов. Прогресс исследований в этой области обусловлен потребностью создания твердотельных аккумуляторов, характеризующихся безопасностью и стабильностью. Результатом работ является синтез ряда электролитов с проводимостью не менее 10-4 См∙см-1 при 25°С. Описаны основные типы полимерных электролитов: типа полимер/соль, с добавкой неорганических частиц и анионных акцепторов, а также полимерные электролиты на ...
Added: November 25, 2022
Tatiana L. Kulova, Skundin A., Gavrilin I. M. et al., Batteries 2022 Vol. 8 No. 8 Article 98
Nanostructure composites Ge-Co-P with brutto-composition CoGe2P0.1, or CoGe2@GeP were manufactured via electrolysis of aqueous electrolyte. Such composites are able to reversible insertion of lithium and sodium with specific capacities up to 855 and 425 mAh/g, respectively. The main advantage of the composites consists in their excellent cycleability. ...
Added: November 25, 2022