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Meet the cerium(IV) phosphate sisters: CeIV(OH)PO4 and CeIV2O(PO4)2

Chemistry - A European Journal. 2020. Vol. 26. No. 53. P. 12188–12193.
Ivanov V.
Language: English
DOI
Keywords: cerium phosphatecerium
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Synergistic Effect of Poly(ethylenephosphoric Acid) and Cerium in Bone Substitute Composites on Tissue Response and Bone Remodeling
Besprozvannyh V., Ryndyk M., Nifantiev I. et al., International Journal of Molecular Sciences 2025 Vol. 26 No. 22 Article 11113
To reduce the time of postoperative recovery and to prevent post-surgical complications, biocompatible synthetic materials with osteoconductive and osteoinductive properties are used as bone substitutes in large bone defect management. A simplified biomimetic approach to similar materials is based on the use of an inorganic filler, a polymer matrix, and a compatibilizer, mimicking the composition ...
Added: March 1, 2026
Effect of sodium and cerium co-doping on microstructure and luminescent properties of hydroxyapatite ceramics
Petrakova N., Demina A., Zobkova Y. et al., Journal of Alloys and Compounds 2025 Vol. 1037 Article 181865
The hydroxyapatite powders with co-doping of Ca2+ with Na+ and Ce3+ were obtained by aqueous precipitation. Co-doping was considered as a method of charge compensation in the cationic sublattice of the HA structure by means of the 2Ca2+→Ce3+ + Me+ in order to maintain the stability of phase composition, improve the optical and microstructural properties of the HA ...
Added: November 5, 2025
Sodium Cerium Phosphate, (Na,Ce)2Ce(PO4)2 · xH2O, with Mixed Cerium Oxidation States
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A previously unknown double ceric sodium phosphate hydrate Na1.97Ce1.03(PO4)2 · xH2O containing both ceric and cerous cations was obtained by the hydrothermal treatment of amorphous ceric phosphate mixed with a sodium hydroxide aqueous solution. The presence of Ce3+ in the structure was proved by HERFD-XANES and ESR spectroscopy. Iterative transformation factor analysis of HERFD-XANES data allowed estimating the content of Ce3+ as ...
Added: June 4, 2024
Composite Anion Exchange Membranes Based on Quaternary Ammonium-Functionalized Polystyrene and Cerium(IV) Phosphate with Improved Monovalent-Ion Selectivity and Antifouling Properties
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The possibility of targeted change of the properties of ion exchange membranes by incorporation of various nanoparticles into the membranes is attracting the attention of many research groups. Here we studied for the first time the influence of cerium phosphate nanoparticles on the physicochemical and transport properties of commercial anion exchange membranes based on quaternary ammonium-functionalized polystyrenes, such as ...
Added: July 26, 2023
The way to increase the monovalent ion selectivity of FujiFilm® anion-exchange membranes by cerium phosphate modification for electrodialysis desalination
Golubenko D. V., Manin A., Yaroslavtsev A. B., Desalination 2022
Recently, the selectivity of ion-exchange membranes and its control have been the subject of numerous fundamental and applied studies. This paper reports an enhanced monovalent anion selectivity of hybrid membrane based on the FujiFilm® Type I anion-exchange membrane and in situ synthesized cerium phosphate (CeP) with a gradient distribution over the membrane thickness. The Cl/SO4-selectivity ...
Added: December 7, 2022
Improvement of Li/Mg monovalent ion selectivity of cation-exchange membranes by incorporation of cerium or zirconium phosphate particles
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To improve the selectivity of cation-exchange membranes to the transfer of lithium with respect to magnesium during the electrodialysis desalination of lithium and magnesium sulfates solutions, the surface of a commercial cation-exchange membrane based on sulfated polystyrene was modified with cerium(III, IV) and zirconium phosphates. Upon incorporation of phosphate particles, the Li/Mg selectivity coefficients of ...
Added: December 7, 2022
Crystallization pathways of cerium(IV) phosphates under hydrothermal conditions: A search for new phases with a tunnel structure
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Added: October 4, 2021
1D ceric hydrogen phosphate aerogels: noncarbonaceous ultra-flyweight monolithic aerogels
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Added: October 4, 2021
Meet the Cerium(IV) Phosphate Sisters: CeIV(OH)PO4 and CeIV2O(PO4)2
Shekunova T. O., Mironov A. V., Istomin S. et al., Chemistry - A European Journal 2020 Vol. 26 P. 12188–12193
Two novel cerium(IV) phosphates were obtained: cerium(IV) hydroxidophosphate, Ce(OH)PO4, and cerium(IV) oxidophosphate, Cе2O(PO4)2, which were shown to complement the classes of isostructural compounds M(OH)PO4 and R2O(PO4)2, where M = Th, U and R = Th, U, Np, Zr. Cе2O(PO4)2 oxidophosphate is formed by elimination of H2O from the crystal structure of Ce(OH)PO4 during its thermal ...
Added: July 2, 2020
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