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Перенос энергии от Ce3+ к Tb3+ в ортоборатах иттрия и гадолиния, полученных гидротермальным синтезом.

Физика твердого тела. 2019. Т. 61. № 1. С. 123–136.
Шмурак С. З., Кедров В. В., Киселев А. П., Фурсова Т. Н., Rybchenko O.

We studied the structure, IR absorption spectra, the spectral characteristics of photoluminescence and morphology of cerium- and terbium-doped orthoborates of gadolinium and yttrium obtained by hydrothermal synthesis at 200°C, as well as solid solutions of orthoborates on the basis of yttrium, gadolinium, and lutetium with composition RECe0.01Tb0.1BO3 (RE = Lu0.5Gd0.39, Lu0.5Y0.39, and Y0.5Gd0.39). The X-ray diffraction spectrum of yttrium orthoborate Y1 – x – yCexTbyBO3 is described by a hexagonal lattice with space group P63/m, which, after annealing at 970°C, transforms into a monoclinic lattice with space group C2/c. High-temperature annealing of the studied orthoborates leads to a multiple, more than two orders of magnitude, increase in the luminescence intensity of Tb3+ ions when the samples are excited in the absorption band of cerium ions. This effect is the result of a significant increase in the concentration of Ce3+ ions in the orthoborates at high temperatures. It is shown that the luminescence of terbium ions is due to energy transfer from Ce3+ to Tb3+, which proceeds with high efficiency (∼85%) by the mechanism of dipole-dipole interaction between cerium and terbium.

Research target: Materials Technologies Physics
Language: Russian
Full text
DOI
Keywords: структура crystal structureлюминесценцияортоборат orthoborates
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