First-Principle Study of Phosphine Adsorption on Si(001)-2x1-Cl
This paper presents a density functional theory study for phosphine adsorption on a Si(001)-2 × 1 surface covered by a chlorine monolayer, including adsorption on local defects, i.e., mono- and bivacancies in the adsorbate layer (Cl, Cl2), and combined vacancies with removed silicon atoms (SiCl, SiCl2). Activation barriers were found for the adsorbing PH3 to dissociate into PH2 + H and PH + H2 fragments; it was also established that phosphine dissociation on combined vacancies is possible at room temperature. If there is a silicon vacancy on the surface, phosphorus settles in the Si(001) lattice as PH (if the vacancy is SiCl) or as PH2 (if the vacancy is SiCl2). This paper suggests a method to plant a separate phosphorus atom into the silicon surface layer with atomic precision, using phosphine adsorption on defects specially created on a Si(001)-2 × 1–Cl surface with a scanning tunneling microscope tip.
This edition presents abstracts of the reports of the Meeting and Youth Conference on Neutron Scattering and Synchrotron Radiationin Condensed Matte (NSSR-CM-2014)r
Diffusion transport of material sputtered from the surface of the powered electrode in the asymmetric alternating current discharge is theoretically studied. It is shown that amplitudes of the non-stationary component of the sputtered atom (SA) flow densities at the electrodes depend on the discharge frequency and two dimensionless parameters, which are functions of the SA mass, its mean free path length in the background gas and the distance between the electrodes. It is found that diffusion damping of the time-varying component of the SA number density takes place in the discharge volume under certain conditions and their flows at the electrodes can be considered as time-independent.
In his reasoning concerning the relationship between surface or visible superficies (understood as the boundary or the limit of a body) and color (De sensu 439a19–b17), Aristotle asserts that the Pythagoreans called the surface (ἐπιφάνεια) color (χροιά), i.e. that they made no terminological difference between the former and the latter. In the scholarship on early Pythagoreans, this passage has been usually used as an indirect proof for the inaccuracy of attribution to the early Pythagoreans (1) of the abstract notion of surface (as found in Plato and Euclid), and thereby (2) of various forms of “derivation theory”. We argue that the colour-surface-limit doctrine has great significance for the understanding of the early Pythagorean concept of a number, since they articulated it, in various ways, precisely through the notion of a limit.
The book is an introduction to the qualitative theory of dynamical systems on manifolds of low dimension (on the circle and on surfaces). Along with classical results, it reflects the most significant achevements in this area obtained in recent times. The reader of this book need to be familiar only with basic courses in differential equations and smooth manifolds.
This chapter presents a review of the experimental and theoretical investigations of halogen interaction with metal surfaces. The emphasis is on the recent measurements performed with scanning tunneling microscopy in combination with density functional theory calculations. The surface structures formed on metal surface after halogen action are classified into three groups: chemisorbed monolayer, surface halide, bulk-like halide. Formation of monolayer structures is described in terms of surface phase transitions. Surface halide phases are considered as intermediates between chemisorbed halogen and bulk halide. The general conclusion is that, for a number of systems, the picture of halogen/metal interaction is still far from complete.
Main regularities of the influence of the air adsorbate on the interpretation of images of thin metal films were experimentally determined in the scanning tunneling microscopy (STM). Modification of the surface relief of a thin film of Pt was made in air.Effect of formation of surface structures of 50-100 nm, a cluster of polarized adsorbate molecules by a strong electric field in the electrode gap, was defined. Tunnel voltage and current threshold values of irreversible relief changes was obtained. Technique of local adsorbate removal from the test surface area was developed by pulse contactless interaction of STM electrodes.
The dynamics of a two-component Davydov-Scott (DS) soliton with a small mismatch of the initial location or velocity of the high-frequency (HF) component was investigated within the framework of the Zakharov-type system of two coupled equations for the HF and low-frequency (LF) fields. In this system, the HF field is described by the linear Schrödinger equation with the potential generated by the LF component varying in time and space. The LF component in this system is described by the Korteweg-de Vries equation with a term of quadratic influence of the HF field on the LF field. The frequency of the DS soliton`s component oscillation was found analytically using the balance equation. The perturbed DS soliton was shown to be stable. The analytical results were confirmed by numerical simulations.
By using superconducting quantum interference device (SQUID) magnetometry, we investigated anisotropic high-field (H less than or similar to 7T) low-temperature (10 K) magnetization response of inhomogeneous nanoisland FeNi films grown by rf sputtering deposition on Sitall (TiO2) glass substrates. In the grown FeNi films, the FeNi layer nominal thickness varied from 0.6 to 2.5 nm, across the percolation transition at the d(c) similar or equal to 1.8 nm. We discovered that, beyond conventional spin-magnetism of Fe21Ni79 permalloy, the extracted out-of-plane magnetization response of the nanoisland FeNi films is not saturated in the range of investigated magnetic fields and exhibits paramagnetic-like behavior. We found that the anomalous out-of-plane magnetization response exhibits an escalating slope with increase in the nominal film thickness from 0.6 to 1.1 nm, however, it decreases with further increase in the film thickness, and then practically vanishes on approaching the FeNi film percolation threshold. At the same time, the in-plane response demonstrates saturation behavior above 1.5-2T, competing with anomalously large diamagnetic-like response, which becomes pronounced at high magnetic fields. It is possible that the supported-metal interaction leads to the creation of a thin charge-transfer (CT) layer and a Schottky barrier at the FeNi film/Sitall (TiO2) interface. Then, in the system with nanoscale circular domains, the observed anomalous paramagnetic-like magnetization response can be associated with a large orbital moment of the localized electrons. In addition, the inhomogeneous nanoisland FeNi films can possess spontaneous ordering of toroidal moments, which can be either of orbital or spin origin. The system with toroidal inhomogeneity can lead to anomalously strong diamagnetic-like response. The observed magnetization response is determined by the interplay between the paramagnetic-and diamagnetic-like contributions.
Radiation conditions are described for various space regions, radiation-induced effects in spacecraft materials and equipment components are considered and information on theoretical, computational, and experimental methods for studying radiation effects are presented. The peculiarities of radiation effects on nanostructures and some problems related to modeling and radiation testing of such structures are considered.