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Regular version of the site

Article

Diphenylacetylene hydrogenation on a PdAg/Al2O3 single-atom catalyst: an experimental and DFT study

Mendeleev Communications. 2017. Vol. 27. No. 6. P. 615-617.
Svitanko I., Стахеев А. Ю., Рассолов А. В., Медведев М. Г., Машковский И. С., Криворученко Д. С.

The hydrogenation of diphenylacetylene (DPA) on palladium–silver catalysts with a single-atom structure was investigated. It has been shown experimentally that the reaction rate of alkene to alkane hydrogenation is substantially lower than the rate of DPA semi-hydrogenation. The kinetic barriers of all stages of hydrogenation were calculated by the DFT method.