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Regular version of the site

Article

Simulation of inhomogeneous pores filling in template electrodeposition of ordered metal nanowire arrays

Electrochimica Acta. 2013. Vol. 112. P. 279-286.
Translator: V. Volgin, A. Davydov.

A model of inhomogeneous pores filling during electrodeposition of ordered metal nanowire arrays isdeveloped. The model takes into consideration the ionic transfer both in the varying diffusion layer in thepores and in the diffusion layer above the template, which is determined by the external hydrodynamicconditions. The model takes into account the kinetics of electrochemical reaction (the Tafel equation)and the diffusion transfer of metal cations both in the pores and in the outer diffusion layer. In the quasi-steady-state approximation, two problems were considered. The problem for the case that the initiallength of one pore differs from that of all other pores is solved analytically. The problem for the case thatthe initial lengths of all pores are different is solved numerically. The time dependences of unfilled porelength are obtained for various overpotentials and various initial distributions of pore length. It is foundthat the pores filling inhomogeneity increases with increasing overpotential.