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Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and 183W NMR studies
Chemical Communications. 2012. Vol. 48. No. 53. P. 6666–6668.
Майничев Д. А., Sokolov M. N., Adonin S. A., Abramov P. A., Zakharchuk N. F., Fedin V. P.
A sandwich-type rhodium polyoxotungstate with unprecedented tetrarhodium-oxo core Na12[(Rh4(μ3–O)2(H2O)2)(H2W9O33)2]·38H2O (1) was obtained by hydrothermal reaction of rhodium(II) acetate and sodium tungstate; crystal structure was determined by X-ray diffractometry and was confirmed by 183W NMR data is active in electrocatalytic water oxidation.
Язык:
английский