Base-Ionizable Anionic NHC Ligands in Pd-catalyzed Reactions of Aryl Chlorides

Two new supramolecular halometalate hybrid complexes, (H2bpen){[MCl5](I2)} (M = Sb(III) (1) and Bi(III) (2); bpen – 1,2-Bis(4-pyridyl)ethylene, have been prepared. Despite very close similarity of the nature of cations, they reveal significant structural difference from the (H2bpe){[MCl5](I2)} (bpe – 1,2-bis(4-pyridil)ethane) reported earlier. We discuss these features, along with thermal stability, optical properties as well as Raman spectra ...

Добавлено: 2 сентября 2026 г.

From Small Data to High Capacity: Symbolic Learning of Sodium-Ion Cathode Materials

Meng K., Васенко А. С., Чулков Е. В. и др., The Journal of Physical Chemistry Letters 2026 Vol. 17 No. 36 P. 10546–10554

Добавлено: 29 августа 2026 г.

Monometallic Ln3+ and heterometallic Ln3+–Cd2+ complexes based on pentafluorophenylacetic acid: efficient control of dimension and luminescent properties

Белоусов Ю. А., Кискин М. А., Сидорук А. В. и др., Australian Journal of Chemistry 2022 Vol. 75 No. 9 P. 572–580

Добавлено: 26 августа 2026 г.

Understanding the electric double layer at electrode–electrolyte interfaces, Part III: crystallographic-face dependence of silver capacitance in aqueous NaF solutions

Мазур Д. А., Petr E. Brandyshev, Doronin S. и др., Electrochimica Acta 2026 Vol. 577 Article 149729

Добавлено: 20 августа 2026 г.

Hall effect in electrolyte solutions: Self-consistent Debye–Hückel–Onsager theory

Будков Ю. А., Каликин Н. Н., Journal of Chemical Physics 2026 Vol. 165 Article 064506

Добавлено: 12 августа 2026 г.

Charge-controlled binding, alloy synergy, and the copper anomaly in Au–Ag–Cu dimers to clusters: DFT-derived design rules for targeted drug delivery

Obijiofor O., Alexander S. Novikov, New Journal of Chemistry 2026 Vol. 50 No. 33 P. 13931–13957

Добавлено: 12 августа 2026 г.

Surface-sulfonated Al₂O₃, CeO₂, and TiO₂ as functional fillers for Nafion-type gel polymer electrolytes for lithium metal batteries

Voropaeva D., S. Novikova, I. Stenina и др., Solid State Ionics 2026 Vol. 445 Article 117288

Добавлено: 30 июля 2026 г.

Long-range machine-learning potentials with environment-dependent charges enable predicting LO-TO splitting and dielectric constants

Korogod D., Shapeev A., Ivan S. Novikov, Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 114 No. 2 Article 024104

Добавлено: 22 июля 2026 г.

A Way to Create Mn-Containing GdFe3(BO3)4 and the Dopant Effect on Its Magnetic Properties

Moshkina E., Molokeev M., Zolotov A. и др., Journal of Alloys and Compounds 2026 Vol. 1077 Article 189412

Добавлено: 29 июня 2026 г.

Incorporating Scientific Knowledge into Neural Network Density Functionals

Schneider M., Zaripov D., Dokin R. и др., Journal of Chemical Theory and Computation 2026 Vol. 22 No. 9 P. 4405–4414

Добавлено: 26 июня 2026 г.

Electrodeposition and electrochromic properties of hydrated mixed oxides MoxW1-xO3·2H2O films

Лауринавичюте В. К., Levin E. E., Mironkova A. A. и др., Surfaces and Interfaces 2026 Vol. 81 Article 108389

Добавлено: 24 июня 2026 г.

Impact of heat treatment on microstructure and mechanical properties of additively manufactured aluminum bronze

Filippova A. V., Yurchenko N. Y., Smirnov S. A. и др., Journal of Alloys and Compounds 2026 No. 1074 Article 189162

Добавлено: 12 июня 2026 г.

Phosphorescent Cyclometalated Palladium(II) and Platinum(II) Complexes Derived from Diaminocarbene Precursors

Kashina M., Luzyanin K., Dar'in D. и др., Inorganic Chemistry 2024 Vol. 63 No. 12 P. 5315–5319

Добавлено: 16 сентября 2024 г.

Boosting the generality of catalytic systems by the synergetic ligand effect in Pd-catalyzed C-N cross-coupling

Grebennikov N., Boiko D., Prima D. и др., Journal of Catalysis 2024 Vol. 429 Article 115240

Добавлено: 14 февраля 2024 г.

New class of RSO2-NHC ligands and Pd/RSO2-NHC complexes with tailored electronic properties and high performance in catalytic C–C and C–N bonds formation

Pasyukov D., Shevchenko M., Astakhov A. и др., Dalton Transactions 2023 Vol. 52 No. 34 P. 12067–12086

Добавлено: 14 февраля 2024 г.

The Role of Ligands in Oxidative Addition Chemistry of Low-Valent Main Group Derivatives: Not Only Stabilization but Also Activation

Shangin P., Akyeva A., Vakhrusheva D. и др., Organometallics 2023 Vol. 42 No. 18 P. 2541–2548

Добавлено: 14 февраля 2024 г.

Noble Metal versus Abundant Metal Catalysts in Fine Organic Synthesis: Cost Comparison of C–H Activation Methods

Komarova A., Dmitry S. Perekalin, Organometallics 2023 Vol. 42 No. 13 P. 1433–1438

Добавлено: 11 августа 2023 г.

Palladium Nanoparticles Entrapped In a Hydrogen Bonded Crystalline Organic Salt Matrix as a Selective Heterogeneous Reduction Catalyst

Kuznetsova S., Yunusov S., Gak A. и др., ChemistrySelect 2022 Vol. 7 No. 41 Article e202203011

Добавлено: 31 января 2023 г.

Mechanistic Studies for Pd(II)(O2) Reduction Generating Pd(0) and H2O: Formation of Pd(OH)2 as a Key Intermediate

Cha J., Lee E., Dmitry V. Yandulov, Inorganic Chemistry 2022 Vol. 61 No. 37 P. 14544–14552

Добавлено: 24 октября 2022 г.

On the Mechanism of the Oxidative Cleavage of N-Heterocyclic-Carbene–Palladium Bonds with Iodine

Lee E., Lee J., Yandulov D. V., European Journal of Inorganic Chemistry 2017 Vol. 2017 P. 2058–2067

Добавлено: 24 октября 2022 г.