• A
  • A
  • A
  • АБВ
  • АБВ
  • АБВ
  • A
  • A
  • A
  • A
  • A
Обычная версия сайта
  • RU
  • EN
  • HSE University
  • Publications
  • Articles
  • Solid Electrolytes Based on NASICON-Structured Phosphates for Lithium Metal Batteries
  • RU
  • EN
Расширенный поиск
Высшая школа экономики
Национальный исследовательский университет
Priority areas
  • business informatics
  • economics
  • engineering science
  • humanitarian
  • IT and mathematics
  • law
  • management
  • mathematics
  • sociology
  • state and public administration
by year
  • 2027
  • 2026
  • 2025
  • 2024
  • 2023
  • 2022
  • 2021
  • 2020
  • 2019
  • 2018
  • 2017
  • 2016
  • 2015
  • 2014
  • 2013
  • 2012
  • 2011
  • 2010
  • 2009
  • 2008
  • 2007
  • 2006
  • 2005
  • 2004
  • 2003
  • 2002
  • 2001
  • 2000
  • 1999
  • 1998
  • 1997
  • 1996
  • 1995
  • 1994
  • 1993
  • 1992
  • 1991
  • 1990
  • 1989
  • 1988
  • 1987
  • 1986
  • 1985
  • 1984
  • 1983
  • 1982
  • 1981
  • 1980
  • 1979
  • 1978
  • 1977
  • 1976
  • 1975
  • 1974
  • 1973
  • 1972
  • 1971
  • 1970
  • 1969
  • 1968
  • 1967
  • 1966
  • 1965
  • 1964
  • 1963
  • 1958
  • More
Subject
News
April 30, 2026
HSE Researchers Compile Scientific Database for Studying Childrens Eating Habits
The database created at HSE University can serve as a foundation for studying children’s eating habits. This is outlined in the study ‘The Influence of Age, Gender, and Social-Role Factors on Children’s Compliance with Age-Based Nutritional Norms: An Experimental Study Using the Dish-I-Wish Web Application.’ The work has been carried out as part of the HSE Basic Research Programme and was presented at the XXVI April International Academic Conference named after Evgeny Yasin.
April 30, 2026
New Foresight Centre Study Identifies the Most Destructive Global Trends for Humankind
A team of researchers from the HSE International Research and Educational Foresight Centre has examined how global trends affect the quality of human life—from life expectancy to professional fulfilment. The findings of the study titled ‘Human Capital Transformation under the Influence of Global Trends’ were published in Foresight.
April 28, 2026
Scientists Develop Algorithm for Accurate Financial Time Series Forecasting
Researchers at the HSE Faculty of Computer Science benchmarked more than 200,000 model configurations for predicting financial asset prices and realised volatility, showing that performance can be improved by filtering out noise at specific frequencies in advance. This technique increased accuracy in 65% of cases. The authors also developed their own algorithm, which achieves accuracy comparable to that of the best models while requiring less computational power. The study has been published in Applied Soft Computing.

 

Have you spotted a typo?
Highlight it, click Ctrl+Enter and send us a message. Thank you for your help!

Publications
  • Books
  • Articles
  • Chapters of books
  • Working papers
  • Report a publication
  • Research at HSE

?

Solid Electrolytes Based on NASICON-Structured Phosphates for Lithium Metal Batteries

Batteries. 2023. Vol. 9. No. 8. Article 407.
Stenina I., Novikova S., Voropaeva D., Andrey Yaroslavtsev

All-solid-state lithium batteries are a promising alternative to commercially available
lithium-ion batteries due to their ability to achieve high energy density, safety, and compactness. Electrolytes
are key components of all-solid-state batteries, as they are crucial in determining the batteries’
efficiency. Herein, the structure of LiM2(PO4)3 (M = Ti, Ge, Zr) and lithium-ion migration mechanisms
are introduced as well as different synthetic routes and doping (co-doping), and their influence on
conductivity is discussed. The effective methods of reducing electrolyte/electrode interface resistance
and improving ion-conducting properties are summarized. In addition, different polymer/NASICON
composites are considered. The challenges and prospects of practical applications of NASICON-type
lithium phosphates as electrolytes for all-solid-state batteries are discussed.

Research target: Chemistry
Language: English
Full text
DOI
Text on another site
Keywords: Ионная проводимостьNasiconIonic conductivityLithium metal batterysolid electrolytecomposite electrolyteLAGPLATPall-solid-state batteryтвердый электролитНасиконкомпозиционный электролитLAGPLATPполностью твердотельный аккумулятор
Similar publications
Machine Learning Approach to Anticancer Activity Prediction of Transition-Metal Complexes Based on a Large-Scale Experimental Database
Krasnov L., Malikov D., Kiseleva M. et al., Journal of Medicinal Chemistry 2026 Vol. 69 No. 8 P. 8838–8851
In this work, we developed a straightforward data-driven approach to predict the cytotoxicity of metal complexes based entirely on their (metal + ligands) composition. To this end, we have manually curated MetalCytoToxDB─a comprehensive experimental database comprising 26,500 IC50 values for 7050 metal complexes against 754 cell lines from 1921 articles. Based on these, machine learning ...
Added: April 23, 2026
Cu(I) acetylide clusters decorated with pyridylphosphine ligands: structural diversity, cuprophilic interactions and phosphorescence properties
Novikov A., Inorganic Chemistry Communications 2026 Article 116670
The reaction of copper(I) phenylacetylide [PhC ≡ CCu]n with the 2-pyridylphosphines (tBu2PyP and Ph2PyP) offers a straightforward route to structurally diverse clusters. With tBu2PyP, a trinuclear cluster [Cu3(C ≡ CPh)3(tBu2PyP)3] featuring a Cu3 triangular was isolated. Surprisingly, the reaction of [PhC ≡ CCu]n with Ph2PyP yields two isomeric clusters [Cu4(C ≡ CPh)4(Ph2PyP)4] with tetrahedral or zigzag-arranged Cu4 cores. Upon prolonged storage in acetonitrile, the tetrahedral Cu4 cluster converts to ...
Added: April 22, 2026
Rapid synthesis of redox-responsive trithiocyanuric acid-based nanocarriers: in vitro multidrug resistance reversal and In vivo safety assessment
Kopoleva E., Sergey A. Tsymbal, Kuchur O. et al., Drug Delivery and Translational Research 2026 P. 1–16
Multidrug resistance (MDR) remains one of the principal challenges in cancer chemotherapy, necessitating new strategies to restore drug efficacy. In this study we developed and characterize a redox-responsive nanoplatform based on trithiocyanuric acid and polyethylene glycol (TTCA-PEG NPs) as a potential tool to overcome MDR and provide a biocompatible delivery system for conventional antitumor drugs. ...
Added: April 20, 2026
Dipolar [3+2] Cycloaddition of Nitrones to 3-Aroylpyrrolo[2,1-c][1,4]benzothiazine-1,2,4-triones
Novikov A., Russian Journal of Organic Chemistry 2026 Vol. 62 Article 12
The dipolar [3+2]-cycloaddition reactions of 3-aroylpyrrolo[2,1-c][1,4]benzothiazine-1,2,4-triones with diarylnitrones lead to the formation of benzo[b]isoxazolo[5',4':2,3]pyrrolo[1,2-d][1,4]thiazines. The reac- tion proceeds stereoselectively to form exclusively the (2aS*,3R*,5aS*) diastereomers. Density functional theory computations for the model reaction showed that the (2aS*,3R*,5aS*) diastereomers are both kinetically and thermodynamically preferred over the alternative (2aS*,3S*,5aS*) diastereomers. At room temperature in solution, the ...
Added: April 19, 2026
Modeling cosolvent effects on solubility in supercritical CO2 using data-driven approaches
Makarov D. M., Kalikin N., Gurikov P. et al., Journal of Supercritical Fluids 2026 Vol. 235 Article 106979
Supercritical CO2 (scCO2 ) is an environmentally friendly solvent, but its low polarity limits the solubility of polar compounds. Cosolvents are commonly used to enhance solvation capability, yet comprehensive datadriven studies are scarce. We compiled the largest dataset to date — 4401 experimental solubility records with 22 cosolvents for 93 nonionic solutes, plus 4855 records ...
Added: April 19, 2026
Theory of capillary-induced self-coacervation in zwitterionic polymer solutions
Kalikin N., Брандышев П. Е., Budkov Y., Journal of Chemical Physics 2026 Vol. 164 Article 154904
This study presents a mean-field theory for zwitterionic polymer solutions confined within attractive slit-like nanopores. Building upon our prior model for self-coacervation [Budkov et al., Soft Matter 19, 3281–3289 (2023)], we demonstrate that strong electrostatic dipole–dipole correlations between monomeric units, coupled with attraction to pore walls, can induce capillary-driven liquid–liquid phase separation inside the pore—a ...
Added: April 18, 2026
Exploring the luminescent and thermometric potentials of samarium(iii) diketonate complexes with extended fluoroalkyl chains
Metlina D., Metlin M., Korshunov V. et al., Dalton Transactions 2025 Vol. 54 No. 9 P. 3812–3826
We synthesized and investigated a new series of Sm3+ 1,3-diketonate complexes with CnF2n+1-homologous thiophene-containing ligands. A clear correlation was found between the number of fluorine atoms in the 1,3-diketone's carbon chain and the luminescent properties of the samarium(III) complexes. The ligand modification method employed facilitates targeted and significant enhancements in the photoluminescence quantum yield (PLQY). ...
Added: March 24, 2026
Combining materials design and deep learning: AI-enhanced luminescence thermometry with a novel Eu3+/Tb3+polymeric coordination compound
Polikovskiy T., Gontcharenko V., Korshunov V. et al., Materials Chemistry Frontiers 2025 Vol. 9 No. 23 P. 3443–3459
Conventional thermal sensors often face limitations due to their reliance on direct contact and restricted measurement ranges, leading to the emergence of novel techniques like luminescence thermometry. However, sensitivity of luminescent thermometers is limited by the only used Boltzmann-based Mott–Seitz model, which is imperfect. To overcome this, we complemented Mott–Seitz model applying machine learning algorithms, ...
Added: March 24, 2026
Harvesting Magneto-Acoustic Waves Using Magnetic 2D Chromium Telluride (CrTe3)
Chowde Gowda C., Alexey Kartsev, Tiwari N. et al., Small 2024 Vol. 20 No. 47 Article 2405197
A vast majority of electrical devices have integrated magnetic units, which generate constant magnetic fields with noticeable vibrations. The majority of existing nanogenerators acquire energy through friction/mechanical forces and most of these instances overlook acoustic vibrations and magnetic fields. Magnetic two-dimensional (2D) tellurides present a wide range of possibilities for devising a potential flexible energy ...
Added: March 16, 2026
Non-thermal magnetic deicing using two-dimensional chromium telluride
Chowde Gowda C., Alexey Kartsev, Tiwari N. et al., Journal of Materials Chemistry C 2024 Vol. 12 No. 46 P. 18691–18703
Two-dimensional (2D) chromium telluride Cr2Te3 exhibits strong ferromagnetic ordering with high coercivity at low temperatures and paramagnetic behavior when approaching room temperature. The spin states of monolayer Cr2Te3 show ferromagnetic ordering in the ground state. In situ Raman analysis reveals a reversible structure transformation and hence proves ferromagnetic to paramagnetic transition during low-temperature heating cycles (0–25 °C). The magnetic ...
Added: March 16, 2026
Simultaneous enhancement of thermoelectric performance and mechanical properties in lead-free cubic GeTe-based composite materials
Xu Z., Guo Z., Zhang P. et al., Journal of Materials Chemistry A 2025 Vol. 13 No. 41 P. 35284–35291
GeTe is a promising mid-temperature thermoelectric material that exhibits excellent thermoelectric performance. However, the rhombohedral-to-cubic phase transition occurring near 700 K causes a change in the coefficient of thermal expansion, leading to internal stresses in the device and affecting its working efficiency. In this work, we reported the alloying of Ge0.81Mn0.15Bi0.04Te with AgSbTe2 to further reduce ...
Added: March 16, 2026
Электронные и магнитные свойства двухкомпонентных твердых растворов Cr(ClxF1-x)3
Лебедев И. С., Кудрявцев А. В., Карцев А. И. et al., Журнал радиоэлектроники 2025 № 11 Статья 30
n this paper, the effect of doping on the electronic and magnetic properties of a monolayer compound Cr(ClxF1-x)3 is studied based on a first-principles calculation. The densities of electronic states, the values of the band gap, the constants of the crystal lattice and the difference in total energies for ferromagnetic and antiferromagnetic configurations at different mutual ...
Added: March 16, 2026
Effect of doping on structure and functional properties of SrFe12-xInxO19 hexaferrite nanoparticles for biomedical applications
Shchetinin I., Nikolenko P., Nizamov T. et al., Ceramics International 2026 Vol. 52 No. 3 P. 3500–3511
In this work, we comprehensively investigated the influence of Indium doping on the structure, magnetic and functional properties of strontium M-type hexaferrites SrFe12-xInxO19 nanoparticles (where x = 1.7, 1.8, 2.0). Colloidally stable SrFe12-xInxO19 nanoparticles (∼10 nm) were synthesized using a combination of the citrate method and high-energy ball milling. We demonstrate that doping reduces both the specific saturation magnetization and, ...
Added: March 16, 2026
Formation of a Pt-Ni Catalyst in the Structure of a Silicon Micro-Fuel Cell
Starkov V., Gosteva E., Alexey Kartsev et al., Molecules 2026 Vol. 31 No. 3 Article 499
This paper demonstrates the results of constructive technological research on the development of a catalyst with a Ni/PSi@Pt structure. This catalyst eliminates the use of gold in the structure of μ-FC electrodes. This work uses the main technological solutions for the formation of a gold-containing “core–shell” structure on the inner surface of pores. Comparative data ...
Added: March 16, 2026
Tackling the challenge of ML-assisted antibacterial activity prediction: One step closer to controlled quaternary ammonium compounds design via neural networks model
Ilin E., Frolov N., Seferyan M. et al., Bioorganic Chemistry 2025 Vol. 167 Article 109175
The ongoing rise of resistant bacterial pathogens poses a significant threat to current antibacterials' effectiveness putting millions of people's lives at risk. However, modern machine learning (ML) tools promise to tip the scales in the never-ending development of antimicrobial agents' pipelines. Herein we present a novel approach for quaternary ammonium compounds (QACs) antibacterial activity prediction ...
Added: March 16, 2026
Aqueous solutions of La1−xPrxPO4 nanoparticles: microwave‑assisted hydrothermal synthesis, X‑ray excited UV‑C luminescence, and colloidal properties
Шайдулин А. Т., Orlovskaya E., Popov A. et al., Journal of Nanoparticle Research 2025 Vol. 27 Article 320
Nanoparticles (NPs) exhibiting X-ray excited UV-C luminescence can be used in radia tion therapy to deactivate cancer cells through pho tochemical reactions of DNA with UV-C quanta. Colloidal solutions of monoclinic La1−xPrxPO4 NPs (x = 0.01–0.3), luminescent in the UV-C range (220–280 nm), with different morphologies, from nanofiber (diameter and length not larger than 15 and ...
Added: March 13, 2026
Do chemists control plane packing, i.e. two-dimensional self-assembly, at all scales?
Chinaud-Chaix C., Marchenko N., Fernique Т. C. et al., New Journal of Chemistry 2023 Vol. 47 No. 15 P. 7014–7025
Two-dimensional (2D) self-assembly (SA) is an efficient strategy to organize building blocks in a simple and efficient way. Actually, different communities of chemists or physicists use 2D SA, with different systems at different scales: molecules, nanoobjects, micron-sized colloidal particles, and even millimetric plastic shapes. Although, the cases of study and the perspectives are different, general ...
Added: March 11, 2026
Синтез и физико-химические свойства солей магния с 4Н-пирановыми кислотами
Козин С. В., Кравцов А. А., Киндоп В. Н. et al., Журнал неорганической химии 2025 Т. 70 № 2 С. 191–200
В результате взаимодействия 4-оксо-4H-пиран-2,6-дикарбоновой (хелидоновой) кислоты с ацетатом магния было получено сокристаллическое соединение - хелидонат магния. Изучение процесса термоокислительной деструкции хелидоната магния показало, что его дегидратация осуществляется в два этапа, а термодеструкция органической части сопровождается ярко выраженными тепловыми эффектами. В структуре хелидоната магния вокруг катиона магния имеется как внутренняя, так и внешняя координационная сфера. Во ...
Added: March 10, 2026
Features of fast charging of lithium-ion batteries: electrochemical aspects (mini-review)
Skundin A. M., Kulova T., Journal of Solid State Electrochemistry 2025 Vol. 29 P. 4079–4099
The problem of fast charging of lithium-ion batteries is one of the key problems for the development of electric transport.This problem is multidisciplinary and is connected, on the one hand, with electrochemical current-producing processes andthe features of lithium-ion batteries themselves, and on the other hand, with the charging infrastructure, the design of chargers,charging protocols, thermal ...
Added: March 9, 2026
All-Solid-State Anode-Free Sodium Batteries: Challenges and Prospects
Skundin A., Kulova T., Batteries 2025 Vol. 11 No. 8 Article 292
All-solid-state anode-free sodium batteries present a special and especially important kind of energy storage device. Unfortunately, the industrial production of such batteries has been absent up to now, although the prospects of their development seem to be rather optimistic. The present mini review considers the fundamental advantages of all-solidstate anode-free sodium batteries as well as ...
Added: March 9, 2026
Effect of Composition of Low-Molecular-Weight Plasticizers on the Properties of Gel Polymer Electrolytes for Lithium Metal Batteries Based on Composite Membrane Nafion and Sulfonated Zirconia
Voropaeva D., Trofimenko N. A., S. A. Novikova et al., Membranes and Membrane Technologies 2025 Vol. 7 No. 2 P. 112–124
Modern studies in the field of lithium metal batteries focus on the development of safe and stable electrolytes with high ionic conductivity and electrochemical stability. In this context, promising materials are gel polymer electrolytes based on perfluorosulfonic acid cation-exchange membranes modified with inorganic fillers and solvated with aprotic solvents. This study addresses Nafion® composite membranes ...
Added: February 17, 2026
HYBRID MEMBRANES BASED ON ZIRCONIUM PHOSPHONATES
Karavanova Y.A., Golubenko D.V., Yaroslavtsev A.B., МЕМБРАНЫ И МЕМБРАННЫЕ ТЕХНОЛОГИИ, Российская Федерация 2020 Vol. 2 No. 4 P. 251–255
Phosphonates with the composition Zr(PO3(CH2)nPh)2 with n = 0, 1, and 3 are synthesized. Hybrid membranes based on an MF-4SK membrane and the synthesized phosphonates are made. The influence of the dopant, its concentration, and synthesis method on the ion-conducting properties of the membranes is studied in comparison with hybrid membranes based on α-zirconium hydrogen phosphate. ...
Added: November 5, 2024
Perfluorosulfonic Acid Membranes as Gel-Polymer Electrolytes for Lithium Metal Batteries
Voropaeva D., Safronova E., Novikova S. et al., Journal of Physical Chemistry C 2024 Vol. 128 No. 10 P. 4143–4151
Gel-polymer electrolytes based on perfluorinated cation-exchange membranes are promising electrolytes for lithium metal batteries due to the strength and chemical stability of the fluorinated matrix and high values of ionic conductivity and cation transference numbers, which contribute to the suppression of dendrite formation. The present work compares the main characteristics of polymer electrolytes based on ...
Added: June 20, 2024
Nafion-212 Membrane Solvated by Ethylene and Propylene Carbonates as Electrolyte for Lithium Metal Batteries
Voropaeva D., Novikova S., Stenina I. et al., Polymers 2023 Vol. 15 No. 22 Article 4340
The use of cation-exchange membranes as electrolytes for lithium metal batteries can prevent the formation of lithium dendrites during extended cycling and guarantee safe battery operation. In our study, the Nafion-212 membrane in lithium form solvated by a mixture of ethylene carbonate and propylene carbonate (EC-PC) was used as an electrolyte in a lithium metal ...
Added: January 25, 2024
  • About
  • About
  • Key Figures & Facts
  • Sustainability at HSE University
  • Faculties & Departments
  • International Partnerships
  • Faculty & Staff
  • HSE Buildings
  • HSE University for Persons with Disabilities
  • Public Enquiries
  • Studies
  • Admissions
  • Programme Catalogue
  • Undergraduate
  • Graduate
  • Exchange Programmes
  • Summer University
  • Summer Schools
  • Semester in Moscow
  • Business Internship
  • Research
  • International Laboratories
  • Research Centres
  • Research Projects
  • Monitoring Studies
  • Conferences & Seminars
  • Academic Jobs
  • Yasin (April) International Academic Conference on Economic and Social Development
  • Media & Resources
  • Publications by staff
  • HSE Journals
  • Publishing House
  • iq.hse.ru: commentary by HSE experts
  • Library
  • Economic & Social Data Archive
  • Video
  • HSE Repository of Socio-Economic Information
  • HSE1993–2026
  • Contacts
  • Copyright
  • Privacy Policy
  • Site Map
Edit