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Effect of Composition of Low-Molecular-Weight Plasticizers on the Properties of Gel Polymer Electrolytes for Lithium Metal Batteries Based on Composite Membrane Nafion and Sulfonated Zirconia
Membranes and Membrane Technologies. 2025. Vol. 7. No. 2. P. 112–124.
Modern studies in the field of lithium metal batteries focus on the development of safe and stable electrolytes with high ionic conductivity and electrochemical stability. In this context, promising materials are gel polymer electrolytes based on perfluorosulfonic acid cation-exchange membranes modified with inorganic fillers and solvated with aprotic solvents. This study addresses Nafion® composite membranes containing surface-sulfonated zirconia (sZrO2) and solvated with binary mixtures of ethylene carbonate (EC) with dimethylacetamide (DMAc), dimethylformamide (DMF), and dimethyl sulfoxide (DMSO) at a 1 : 1 ratio by volume. The presented systems demonstrate the dependence of ionic conductivity on the nature of the solvent, following the series: EC–DMAc > EC–DMF > EC–DMSO, with the maximum conductivity (2.2 mS/cm at 25°C) being achieved for the Nafion@sZrO2–EC–DMAc composition. The resulting electrolytes are electrochemically stable up to 4.2 V (vs. to Li+/Li), which makes them compatible with cathode materials such as LiFePO4 (LFP). However, DMSO slowly interacts with lithium metal to form a low-conductivity SEI layer, whereas EC–DMAc and EC–DMF systems provide stable operation of Li|Li cells for >1000 h at a current density of 0.1 mA/cm2. Cyclic tests of Li|LFP cells with Nafion@sZrO2–EC–DMAc and Nafion@sZrO2–EC–DMF electrolytes show an initial discharge capacity of ∼155 mA h/g (0.1C) and high stability—capacity loss after 50 cycles at 0.5C is 4.7 and 2.0%, respectively. The obtained results confirm the potential of using Nafion®-based composite gel polymer electrolytes solvated with amide solvents in new generation lithium metal batteries.
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Budkov Y., Kalikin N., Journal of Chemical Physics 2026 Vol. 165 Article 064506
A self-consistent statistical-mechanical theory of the Hall effect in electrolyte solutions is developed by extending the self-consistent Debye–Hückel–Onsager (SCDHO) framework to crossed electric and magnetic fields. The theory incorporates non-local ionic charge distributions via Slater-type form factors, regularizing the Coulomb interaction at short range, and accounts for dielectric friction through ion-specific coefficients, employing experimental values ...
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G. G. Bondarenko, Kristya V. I., Savichkin D. O. et al., Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques 2026 Vol. 20 No. 2 P. 417–423
A model of a glow gas discharge in a mixture of argon and mercury vapor is formulated in the presence
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Composite gel polymer electrolytes based on a perfluorinated sulfonic acid cation-exchange MF-4SC membrane
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Added: July 30, 2026
Dmitry Vasilyev, Gorev V., Ikhsanov R. et al., Journal of Materials Science 2026 No. 61 P. 25452–25470
The orthorhombic phase of 𝛼-Mo2 C is a key component in electrocatalytic applications, as Mo2C-based catalysts can exhibit catalytic performance comparable to or exceeding that of noble metals. Despite its technological relevance, theoretical understanding of the anisotropy in the thermal expansion and related thermoelastic properties of 𝛼-Mo2 C remains limited. In this work, first-principles calculations ...
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The effect of high-power pulsed laser radiation (LR) generated in the GOS 1001 setup in the
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Korogod D., Shapeev A., Ivan S. Novikov, Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 114 No. 2 Article 024104
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Kilinc N., ALI I., Economies 2026 Vol. 14 No. 7 Article 277
The increasingly rapid process of de-dollarization in the context of growing geopolitical fragmentation has significantly altered the monetary dynamics of the global economy, thereby posing important questions about economic resilience and sustainable development in the emerging world. This research investigates de-dollarization-related macro-financial conditions and their association with economic resilience in the BRICS+ countries during the ...
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Moshkina E., Molokeev M., Zolotov A. et al., Journal of Alloys and Compounds 2026 Vol. 1077 Article 189412
A wide series of substitutions in a subsystem of small radii cations M = Al, Cr, Fe, Ga, Sc is possible in rare-earth borates ReM3(BO3)4 with the huntite structure. However, the existence of these compounds where M = Mn still raises doubts. The study presents a synthetic approach developed in the framework of the flux method allowing for the required ...
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Schneider M., Zaripov D., Dokin R. et al., Journal of Chemical Theory and Computation 2026 Vol. 22 No. 9 P. 4405–4414
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Г. Г. Бондаренко, Кристя В. И., Савичкин Д. О. et al., Поверхность. Рентгеновские, синхротронные и нейтронные исследования 2026 № 4 С. 29–36
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рабочей газовой смеси дает ионизация атомов ртути метастабильными возбужденными атомами
аргона (реакция Пеннинга). Показано, что в случае катода без диэлектрической пленки при
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Added: June 20, 2026
Filippova A. V., Yurchenko N. Y., Smirnov S. A. et al., Journal of Alloys and Compounds 2026 No. 1074 Article 189162
This study investigates the effects of post-processing heat treatment at 300–500 °C on the microstructure, hardness, and tensile properties of laser powder bed fusion (PBF-LB) processed Al-bronze processed with energy densities (ED) in the range of 125–938 J/mm3. In the as-printed state, sharp needle-like α + β′ laths form at lower ED whereas with increasing ED, the β′ ...
Added: June 12, 2026
Zirnik G., Ostovari Moghaddam A., Zhukov S. et al., Journal of Materials Science: Materials in Electronics 2026 Vol. 37 Article 738
In regards to the advances in InGaZnO for flexible transistors applications, herein for the first time we measure the broadband radio-frequency range (10 Hz to 1 MHz) dielectric permittivity ε′ and electrical conductivity σ of InGaZnO4 nanoparticle layers at different temperatures ranging from 10 to 300 K. The InGaZnO4 nanoparticles prepared by metal–nitrate–glycol gel decomposition method exhibited ...
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Rational design of gold-based nanocarriers for neurotherapeutics requires atomic-scale understanding of drug-material interactions. Density functional theory calculations were performed to investigate levodopa (L-DOPA) adsorption on small gold clusters (Au2–Au4) with cationic, neutral, and anionic charges, with additional validation on a larger Au10 cluster using multiple low-energy isomers. Binding free energies (ΔGbind), charge transfer, and electronic descriptors ...
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Developing efficient photoactive materials from bio-derived resources is vital yet challenging for achieving effective water splitting performance. In this work, nano carbon dots (CDs) of zero-dimensional (0D) were synthesized from papaya peel through a simple and eco-friendly process and subsequently anchored onto the two-dimensional (2D) layered structure of graphitic carbon nitride (g-C3N4, GCN) at various ...
Added: June 2, 2026
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Development of heterojunction materials is an efficient approach for enhancing photocatalytic and photoelectrochemical processes. We develop a ZnO/CuO heterojunction via Cu doping into a ZnO matrix. Structural characterization confirmed that Cu was effectively incorporated into ZnO without any structural changes. The improved optical properties and reduced charge carrier recombination of the doped samples were confirmed ...
Added: June 2, 2026
Perfluorosulfonic acid polymer membrane with increased chemical stability for hydrogen-air fuel cell
Safronova E. Y., A. O. Bedarkova, Novikova S. et al., Polymer Degradation and Stability 2025 Vol. 240 Article 111477
One of the key tasks of hydrogen energy development is to obtain chemically stable proton exchange polymer membranes with high proton conductivity. This article presents the results on the investigation of the stabilization of proton-conducting membranes with a Nafion®-type structure using modification by fluorine. The membranes examined in this study exhibited high thermal stability and ...
Added: August 26, 2025
Zhigileva E., Enakieva Y., Chernyshev V. et al., Dalton Transactions 2024 Vol. 53 No. 39 P. 16345–16354
Post-synthetic modification of proton-conducting metal–organic frameworks (MOFs) by loading small molecules
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Added: November 5, 2024
Voropaeva D., Safronova E., Novikova S. et al., Journal of Physical Chemistry C 2024 Vol. 128 No. 10 P. 4143–4151
Gel-polymer electrolytes based on perfluorinated cation-exchange membranes are promising electrolytes for lithium metal batteries due to the strength and chemical stability of the fluorinated matrix and high values of ionic conductivity and cation transference numbers, which contribute to the suppression of dendrite formation. The present work compares the main characteristics of polymer electrolytes based on ...
Added: June 20, 2024
Voropaeva D., Novikova S., Stenina I. et al., Polymers 2023 Vol. 15 No. 22 Article 4340
The use of cation-exchange membranes as electrolytes for lithium metal batteries can prevent the formation of lithium dendrites during extended cycling and guarantee safe battery operation. In our study, the Nafion-212 membrane in lithium form solvated by a mixture of ethylene carbonate and propylene carbonate (EC-PC) was used as an electrolyte in a lithium metal ...
Added: January 25, 2024
Stenina I., Novikova S., Voropaeva D. et al., Batteries 2023 Vol. 9 No. 8 Article 407
All-solid-state lithium batteries are a promising alternative to commercially available
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Added: January 23, 2024
Parshina A., Safronova E., Novikova S. et al., membranes 2023 Vol. 13 No. 8 Article 701
The development of accessible express methods to determine markers of viral diseases in saliva is currently an actual problem. Novel cross-sensitive sensors based on Donnan potential with bio-comparable perfluorosulfonic acid membranes for the determination of salivary viral markers (N-acetyl-L-methionine, L-carnitine, and L-lysine) were proposed. Membranes were formed by casting from dispersions of Nafion or Aquivion in N-methyl-2-pyrollidone or ...
Added: January 23, 2024
Ulyana M. Zavorotnaya, Ponomarev I., Volkova Y. et al., Membranes 2023 Vol. 13 No. 5 Article 485
This paper presents research on the technology development of the hydrogen-air fuel cells with high output power characteristics using fluorine-free co-polynaphtoyleneimide (co-PNIS) membranes. It is found that the optimal operating temperature of a fuel cell based on a co-PNIS membrane with the hydrophilic/hydrophobic blocks = 70/30 composition is in the range of 60-65 °C. The ...
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