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June 25, 2026
HSE Researchers Make Aldehydes Perform Dual Function
Chemists from HSE University have discovered a way to carry out a reductive addition reaction without using an external reducing agent. Instead, the required 'resource' is supplied by the aldehyde itself, one of the reaction participants. This approach helps prevent unwanted side reactions, reduces toxicity, and simplifies the production and synthesis of organic molecules, including those used in the manufacture of medicines. The study has been published in Journal of Catalysis.
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Extremely strong DLAs at high redshift: gas cooling and H2 formation

Monthly Notices of the Royal Astronomical Society. 2022. Vol. 510. No. 4. P. 5974–5983.
Telikova K. N., Balashev S., Notredaeme P., Krogager J. -., Ranjan A.

We present a spectroscopic investigation with the Very Large Telescope/X-shooter of seven candidate extremely strong damped Lyman-α absorption systems [ESDLAs, N(H I) ≥ 5 × 1021 cm-2] observed along quasar sightlines. We confirm the extremely high column densities, albeit slightly (0.1 dex) lower than the original ESDLA definition for four systems. We measured low-ionization metal abundances and dust extinction for all systems. For two systems, we also found strong associated H22 absorption logN(H2)(cm−2)=18.16±0.03log⁡N(H2)(cm−2)=18.16±0.03 and 19.28 ± 0.06 at z = 3.26 and 2.25 towards J2205+1021 and J2359+1354, respectively, while for the remaining five we measured conservative upper limits on the H22 column densities of typically logN(H2)(cm−2)<17.3log⁡N(H2)(cm−2)<17.3. The increased H2 detection rate (10-55 per cent at 68 per cent confidence level) at high H I column density compared with the overall damped Lyman-α population (~5-10 per cent) confirms previous works. We find that these seven ESDLAs have similar observed properties as those previously studied towards quasars and γ-ray burst afterglows, suggesting they probe inner regions of galaxies. We use the abundance of ionized carbon at the excited fine-structure level to calculate the cooling rates through the C II λ158 μm emission, and compare them with the cooling rates from damped Lyman-α systems in the literature. We find that the cooling rate distribution of ESDLAs also presents the same bimodality as previously observed for the general (mostly lower H I column density) damped Lyman-α population.

Research target: Physics
Language: English
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Keywords: absorption spectroscopygalaxiesquasars
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