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Two-component Electrolyte Solutions with Dipolar Cations on a Charged Electrode: Theory and Computer Simulations
Journal of Physical Chemistry C. 2020. Vol. 124. No. 30. P. 16308–16314.
The development of advanced electrochemical devices for energy conversion and storage requires fine tuning of electrode reactions, which can be accomplished by altering the electrode/solution interface structure. Particularly, in case of an alkali-salt electrolyte the electric double layer (EDL) composition can be managed by introducing organic cations (e.g. room temperature ionic liquid cations) that may possess polar fragments. To explore this approach, we develop a theoretical model predicting the efficient replacement of simple (alkali) cations with dipolar (organic) ones within the EDL. For the typical values of the molecular dipole moment ($2-4~D$) the effect manifests itself at the surface charge densities higher than 30 $\mu C/cm^2$. We show that the predicted behavior of the system is in qualitative agreement with the molecular dynamics simulation results.
sobov P., Yakushev I., Shestakov A. et al., Organometallics 2025 Vol. 44 No. 24 P. 2873–2881
Interaction of {Cryptand(K+)}(C60•–) with CpCo(CO)2 yields the air-sensitive crystalline salt {Cryptand(K+)}{CpCo(CO)-η2-C60•–} (1), in which C60•– replaces carbonyl group in CpCo(CO)2. Two Co–C bonds of 2.028(9) and 2.057(8)Å are formed. The magnetic moment of 1 is 1.72 μB, indicating a doublet S = 1/2 spin state of {CpCo(CO)-η2-C60•–} at 300 K. The compound shows a broad ...
Added: September 20, 2026
Medvedev V., Annals of Global Analysis and Geometry 2026 Vol. 70 No. 2 P. 8–23
This paper studies three-dimensional compact static manifolds with boundary and positive scalar curvature. We prove that, under a suitable bound on the Ricci curvature, the orientable quotient of the Nariai static manifold with boundary is the only such manifold with connected boundary, provided that the zero-level set of the potential is connected and does not intersect ...
Added: September 19, 2026
Aleksei Samarin, Alexander Savelev, Aleksei Toropov et al., Pattern Recognition and Image Analysis 2026 Vol. 36 No. 2 P. 323–334
In this paper, an improved approach for automatic wildlife detection in natural environments based on the integration of a neural network architecture with a two-stream attention mechanism and a novel preclassification step based on infrared data has been presented. The proposed method addresses one of the key challenges in environmental monitoring: the need for scalable ...
Added: September 19, 2026
Aleksei Samarin, Nazarenko A., Kotenko E. et al., Proceedings of the ACM on Management of Data, USA 2026 Vol. 4 No. 1 P. 1–28
Modern knowledge and large volumes of data are increasingly encoded within neural networks, making the task of simplifying their structures and reducing the number of parameters especially relevant, both to improve efficiency and to facilitate deployment in resource-constrained environments. This paper presents a novel approach to neural network compression that addresses redundancy at both the ...
Added: September 19, 2026
Aleksei Samarin, Alexander Savelev, Aleksei Toropov et al., Pattern Recognition and Image Analysis 2025 Vol. 35 No. 2 P. 148–158
This paper describes our research on creating classifiers for microbial images (micrococci microscopy images) obtained from pictures of unfixed microscopic scenes. In our work, we propose an AutoML approach based on the automatic generation and analysis of the feature space for constructing the most optimal descriptors of microorganism images for subsequent classification. This makes it ...
Added: September 19, 2026
Aleksei Samarin, Alexander Savelev, Aleksei Toropov et al., Pattern Recognition and Image Analysis 2026 Vol. 36 No. 2 P. 302–312
The lack of annotated microscopic datasets remains a major obstacle to training robust deep learning models for microbial classification. In this paper, a novel data augmentation pipeline that uses visual–linguistic large-scale models to generate synthetic microscopic images of six different bacterial and nonbacterial classes has been proposed. Synthetic samples have gradually been added to the ...
Added: September 19, 2026
Springer, Cham, 2026.
computer vision ...
Added: September 19, 2026
Springer, Cham, 2026.
Added: September 19, 2026
FRUCT Oy, 2024.
Added: September 19, 2026
FRUCT Oy, 2024.
Added: September 19, 2026
FRUCT Oy, 2025.
Added: September 19, 2026
FRUCT Oy, 2026.
Added: September 19, 2026
Aleksei Samarin, Nazarenko A., Kotenko E. et al., Machine Learning and Knowledge Extraction 2026 Vol. 8 No. 8 P. 1–26
This paper presents a novel method for pruning deep neural networks based on the concept of flow, derived from the continuous modeling of signal propagation across layers. We derive flow functions for fully connected, convolutional, and self-attention architectures, and we propose a new iterative pruning algorithm, Iterative Flow-Aware Pruning (IFAP), that leverages these measures to ...
Added: September 19, 2026
Kuzyutin D., Smirnova N., Veselkov A., Bulletin of the South Ural State University, Series: Mathematical Modelling, Programming and Computer Software 2026 Vol. 19 No. 3 P. 40–49
We consider spatial dynamic fishery management problem taking into account the resource migration process between an open-access fishing area and no-take marine protected area. The introduced extension of a standard single-criterion fish war game implies that each player aims to maximize simultaneously two performance criteria which present an economic benefit and an environmental conservation goal ...
Added: September 18, 2026
Копьев А., JETP Letters 2026 Vol. 123 No. 5 P. 310–316
The incompressible three-dimensional Euler equations develop very thin pancake-like regions of exponen tially increasing vorticity. The characteristic thickness of such regions decreases exponentially with time, while the other two dimensions do not change considerably, making the flow near each pancake strongly anisotropic. The pancakes emerge in increasing number with time, which may enhance the anisotropy ...
Added: September 18, 2026
Ероховец Николай Юрьевич, Математический сборник 2026 Т. 217 № 5 С. 45–89
Toric topology assigns to each simple convex n-polytope P with m facets an n-dimensional real moment-angle manifold RZP with a canonical action of Zm2=(Z/2Z)m. We consider (not necessarily free) actions of subgroups H⊂Zm2 on RZP. The orbit space N(P,H)=RZP/H carries an action of Zm2/H. For general n we introduce the notion of Hamiltonian C(n,k)-subcomplex in the boundary of an ...
Added: September 17, 2026
Kuninets A., Malygina E., Cryptography and Communications 2026
In this paper, we determine explicit bases for Riemann–Roch spaces associated with various families of elliptic codes. We establish the feasibility and provide exact algorithms for constructing bases of Riemann–Roch spaces corresponding to arbitrary divisors on elliptic curves, including the non-effective case. These results are subsequently applied to derive bases for quasi-cyclic elliptic codes and ...
Added: September 17, 2026
Захаров А. В., Düven H., Capar M. I., Physics Letters A 2026 No. 576 Article 131388
Molecular dynamics simulations were carried out to study the structural properties of nematic pentyl
cyanobiphenyl (5CB) and pentyloxy cyanobiphenyl (5OCB) liquid crystals (LCs) doped with gold nanoparti
cles (GNPs) of different numbers, shapes and sizes. The spherical GNPs of two different radii and rod-like have
been doped in 5CB and 5OCB cyanobiphenyl liquid crystals. In order to describe ...
Added: September 17, 2026
Kazakov A., Koryakin V., Safonov K. et al., Journal of Differential Equations 2026 Vol. 480 Article 114626
We study a family of one-dimensional maps that models the dynamics of a system of differential equations with a Lorenz attractor near a bifurcation curve where the system has a pair of homoclinic loops with zero separatrix value. Of particular interest is the region of the parameter plane where the map has a robust chaotic ...
Added: September 16, 2026
Budkov Y., Journal of Chemical Physics 2026 Vol. 165 No. 9 Article 094902
We derive the stress tensor of a flexible polymer solution within the Gaussian-chain self-consistent field theory (SCFT) without invoking the ground-state dominance (GSD) approximation. Starting from a covariant formulation of the single-chain partition function in a background metric, we obtain the symmetric stress tensor expressed through the full Edwards propagators. The result contains the local ...
Added: September 2, 2026
Mazur D., Petr E. Brandyshev, Doronin S. et al., Electrochimica Acta 2026 Vol. 577 Article 149729
The electric double layer (EDL) at a single-crystal metal surface is controlled not only by the electrolyte composition and the electrode potential, but also by the atomic structure of the surface itself. This makes the Ag(hkl)/NaF interface a stringent test for continuum theories of the EDL. In the third part of our series, we examine ...
Added: August 20, 2026
Budkov Y., Kalikin N., Journal of Chemical Physics 2026 Vol. 165 Article 064506
A self-consistent statistical-mechanical theory of the Hall effect in electrolyte solutions is developed by extending the self-consistent Debye–Hückel–Onsager (SCDHO) framework to crossed electric and magnetic fields. The theory incorporates non-local ionic charge distributions via Slater-type form factors, regularizing the Coulomb interaction at short range, and accounts for dielectric friction through ion-specific coefficients, employing experimental values ...
Added: August 12, 2026
Doronin S., Yury A. Budkov, Current Opinion in Electrochemistry 2026 Vol. 57 Article 101853
The electric double layer (EDL) governs charge distribution at electrode–electrolyte interfaces, controlling reaction kinetics and energy storage performance. This mini review surveys the evolution of EDL theory—from the classical Gouy-Chapman-Stern framework to modern coupled quantum-continuum schemes that integrate electronic structure with statistical mechanics. We show how modified Poisson–Boltzmann (mPB) formu-lations incorporating finite ion size, dielectric ...
Added: April 19, 2026
Yury A. Budkov, Nikolai N. Kalikin, Physical Chemistry Chemical Physics 2026 Vol. 28 No. 11 P. 6756–6768
This study presents a novel approach to addressing the limitations in understanding the behavior of charged particles in solutions. The approach is based on the development of the Self-Consistent Debye–Hückel–Onsager (SCDHO) theory, which integrates the effects of non-local charge distributions using a Slater-type charge form factor model. This results in a modified Coulomb potential at ...
Added: February 27, 2026