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Синтез полимеров и модификация полимерных материалов в электромагнитных полях
Успехи химии. 2018. Т. 87. № 10. С. 923–949.
Data on the effect of electromagnetic fields on polymerization processes are analyzed and integrated. The results of
investigation of the response of polymeric systems including polymerization mixtures, polymer solutions, melts and gels to external electromagnetic fields are discussed. Mechanisms of changes in the kinetic parameters of cationic polymerization of certain monomers are considered. They are based on ideas of spatial redistribution of growing macroions and counterions depending on the degree of dissociation of the active sites, which can lead to an increase in the polymerization rate, stabilize it or slow down the process. It is shown that these mechanisms are universal for other ionic systems. Almost all types of polymerization processes are discussed to reveal potential fields of their application in additive manufacturing technologies. High demand for further studies of the effect of electromagnetic fields on polymeric objects is pointed out in connection with the need to solve problems in the design of novel materials and functional structures.
Priority areas:
engineering science
Language:
Russian
Томаева М. А., Неверов В. Д., Shanenko A. et al., Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 114 P. 1–6
We report a thermally driven structural crossover of vortex matter in a two-dimensional superconducting Penrose quasicrystal. At low temperatures, vortices are pinned by the quasiperiodic lattice, forming an aperiodic pattern. With increasing temperature, vortex-vortex interactions dominate, leading to a conventional triangular Abrikosov lattice. Our findings reveal a tunable interplay between intrinsic pinning and vortex interactions, ...
Added: September 5, 2026
Budkov Y., Journal of Chemical Physics 2026 Vol. 165 No. 9 Article 094902
We derive the stress tensor of a flexible polymer solution within the Gaussian-chain self-consistent field theory (SCFT) without invoking the ground-state dominance (GSD) approximation. Starting from a covariant formulation of the single-chain partition function in a background metric, we obtain the symmetric stress tensor expressed through the full Edwards propagators. The result contains the local ...
Added: September 2, 2026
Zhukov A., Liang Y., Zhang X. et al., ACS Applied Nano Materials 2026 Vol. 9 No. 32 P. 15224–15232
The development of high-light-yield scintillators based on perovskite quantum dots (PQDs) is hindered by their intrinsic instability and aggregation, which severely limits their long-term operational reliability and integration into polymeric matrices. Silica coating has been demonstrated as an effective strategy to enhance the stability of PQDs. However, achieving fast and uniform silica encapsulation on individual ...
Added: August 27, 2026
Zhukov A., Kryzhanovskaya N., Moiseev E. et al., Nature 2026 Vol. 656 P. 80–85
Reaching lasing in electrically pumped microdevices based on solution-processed
semiconductors poses a substantial scientific and technological challenge. Halide
perovskites offer a promising platform for electrical injection1, as their optically
excited single-crystal cavities2–4 and predesigned5,6 or postprocessed microstructures7,8
have exhibited low lasing threshold. Indirect electrical pumping of a dual-cavity
perovskite laser was recently obtained9, using a well-established technological
concept of embedding a ...
Added: August 27, 2026
Тула: Тульский государственный педагогический университет им. Л.Н. Толстого, 2025.
Сборник содержит материалы, представленные на XXIV Международной конференции «Алгебра, теория чисел, дискретная геометрия и многомасштабное моделирование: современные проблемы, приложения и проблемы истории», посвящённой 110-летию со дня рождения академика Юрия Владимировича Линника и 110-летию со дня рождения профессора Андрея Борисовича Шидловского и 80-летию со дня рождения профессора Геннадия Ивановича Архипова. Материалы конференции будут полезны научным работникам, ...
Added: August 27, 2026
Belousov Y., Кискин М. А., Sidoruk A. et al., Australian Journal of Chemistry 2022 Vol. 75 No. 9 P. 572–580
Four new complexes [Ln(pfaa)3(H2O)2]n (Ln = Eu (1), Tb (2)) and [Ln2Cd2(pfaa)10 (phen)2(EtOH)2]·2MeCN (Ln = Eu (3), Tb (4), phen = 1,10-phenanthroline) based on pentaphorphenylacetic acid (Hpfaa) have been prepared and completely investigated. The structures of compounds 1 and 3 were studied by single crystal X-ray diffraction analysis: the isostructural complexes 1 and 2 represent ...
Added: August 26, 2026
Eduard Sopin, Nazarin A., Begishev V. et al., IEEE Transactions on Vehicular Technology 2026 Vol. 75 No. 6 P. 10995–11007
Aimed at rate-greedy applications having extreme requirements for the data rate at the air interface, 5G New Radio (NR) systems may experience problems when the number of user equipment (UE) in the coverage of the cell increases due to limited capacity of the physical downlink control channel (PDCCH).The aim of this study is to explore ...
Added: August 26, 2026
Mazur D., Petr E. Brandyshev, Doronin S. et al., Electrochimica Acta 2026 Vol. 577 Article 149729
The electric double layer (EDL) at a single-crystal metal surface is controlled not only by the electrolyte composition and the electrode potential, but also by the atomic structure of the surface itself. This makes the Ag(hkl)/NaF interface a stringent test for continuum theories of the EDL. In the third part of our series, we examine ...
Added: August 20, 2026
IEEE, 2025.
Dynamics of Systems, Mechanisms and Machines (Dynamics) ...
Added: August 19, 2026
A. Bogatyrev, Transactions of the Moscow Mathematical Society 2024 Vol. 85 No. 2 P. 323–337
The best uniform rational approximation of the Sign function on two intervals separated by zero was explicitly found by E. I. Zolotarëv in 1877. The natural extension of this problem to three bands was solved by E. Stiefel in 1961. We indicate the solutions overlooked by the prominent geometer and study their properties. ...
Added: August 14, 2026
Budkov Y., Kalikin N., Journal of Chemical Physics 2026 Vol. 165 Article 064506
A self-consistent statistical-mechanical theory of the Hall effect in electrolyte solutions is developed by extending the self-consistent Debye–Hückel–Onsager (SCDHO) framework to crossed electric and magnetic fields. The theory incorporates non-local ionic charge distributions via Slater-type form factors, regularizing the Coulomb interaction at short range, and accounts for dielectric friction through ion-specific coefficients, employing experimental values ...
Added: August 12, 2026
Novikov A., New Journal of Chemistry 2026 Vol. 50 P. 13931–13957
The rational design of coinage metal nanocarriers requires a mechanistic understanding of metal-drug binding and predictive descriptors that translate molecular interactions into design rules. Using DFT (B3LYP-D3BJ/def2-TZVP, SMD water), we systematically investigated the binding of 5-fluorouracil (5-FU) and levodopa (l-DOPA) to neutral and cationic homo- and heteronuclear dimers of Au, Ag, and Cu (Au2, Ag2, ...
Added: August 12, 2026
Корсунский В. А., Бяков К. Е., М.: Издательство МГТУ им. Н.Э. Баумана, 2025.
Описана методика выбора параметров энергетической установки и тяговых электродвигателей мобильного робота на этапе проектирования с использованием программного комплекса MatLab. Для студентов высших учебных заведений, обучающихся по специальностям 23.05.01 «Наземные транспортно-технологические средства», 23.05.02 «Транспортные средства специального назначения», и магистрантов 2 курса, обучающихся по направлению подготовки 23.05.04 «Наземные транспортно-технологические средства». ...
Added: August 7, 2026
Saitov S. R., Saidzhonov B. M., Vasiliev R. B. et al., Journal of Applied Physics 2026 Vol. 139 No. 18 Article 185702
This work presents a comprehensive investigation into the temperature-dependent thermally stimulated conductivity and photoconductivity of vacuum-annealed thin films based on core–shell CdSe/CdS nanoplatelets passivated with oleic acid ligands. Controlled thermal annealing under vacuum conditions leads to a substantial increase in both dark and photoinduced conductivity, which is primarily attributed to partial desorption of the ligands. ...
Added: May 18, 2026
Гущина В. А., / Series chemrxiv-2023-vpzhz-v2 "ChemRxiv". 2023.
All-inorganic perovskite CsPbBr3 and Cs4PbBr6 nanoparticles are being intensively studied due to their unique properties and wide range of applications; however, however, the nature of their optical properties is not yet fully understood due to the difficulty of synthesis of singlephase nanoparticles. In this article we describe the features of the synthesis of single-phase particles ...
Added: May 14, 2026
Pilé I., Deng Y., Shchur L., / Series arXiv "math". 2026. No. 2604.10254.
We investigate the spatial overlap of successive spin configurations in Markov chain Monte Carlo simulations using the local Metropolis algorithm and the Svendsen-Wang and Wolff cluster algorithms. We examine the dynamics of these algorithms for two models in different universality classes: the Ising model and the Potts model with three components. The overlap of two ...
Added: April 20, 2026
Kagan M., Silkin V. M., Efremov D. V., / Series arXiv "math". 2024. No. 2411.12836.
In this study, we analyze the dielectric function of high-Tc cuprates as a function of doping level, taking into account the full energy band dispersion within the CuO2 monolayer. In addition to the conventional two-dimensional (2D) gapless plasmon mode, our findings reveal the existence of three anomalous branches within the plasmon spectrum. Two of these branches ...
Added: November 27, 2024
Anikeeva V., Болдырев Н. Ю., Семенова О. И. et al., Оптика и спектроскопия 2024 Т. 132 № 8 С. 793–799
The paper presents the results of the temperature dependences study of the luminescence spectra (3.6 – 120 K) upon excitation by 405 nm light and of the non-contact measured photoconductivity spectra (3.6 – 300 K) of a CsPbBr3 single crystal. In the low-temperature photoluminescence (PL) spectrum, in addition to the self-trapped exciton line (2.318 eV at 10 K), a rich ...
Added: October 29, 2024
Influence of anisotropy on the study of critical behavior of spin models by machine learning methods
Sukhoverkhova D., Shchur L., / Series arXiv "math". 2024. No. 2410.14523.
In this paper, we applied a deep neural network to study the issue of knowledge transferability between statistical mechanics models. The following computer experiment was conducted. A convolutional neural network was trained to solve the problem of binary classification of snapshots of the Ising model's spin configuration on a two-dimensional lattice. During testing, snapshots of ...
Added: October 21, 2024
Tolstikov S., Mullahmetov I., Pozhidaev E. et al., Технологии электромагнитной совместимости 2024 № 1(88) С. 62–71
The study involves the computational modeling of electrostatic discharge initiation in polymer materials utilized in space environment under low-temperature conditions. To address this challenge, experimental data on the radiation-induced electrical conductivity of polyimide and polyethylene terephthalate at reduced temperatures, have been employed. The simulation encompasses the evaluation of electric field intensity within polyimide and polyethylene ...
Added: June 6, 2024
Mozolenko V., Fadeeva Marina, Shchur L., / Series arXiv "math". 2024. No. 2405.10865.
The development of new algorithms for simulations in physics is as important as the development of new analytical methods. In this paper we present a comparison of the recently developed microcanonical population annealing (MCPA) algorithm with the rather mature Wang-Landau algorithm. The comparison is performed on two cases of the Potts model exhibiting a first ...
Added: May 20, 2024
Kagan M., Аксёнов С. В., / Series Research Square "Research Suqare". 2024. No. 1.
We study different resonances (first of all of the Fano type) in the interference device formed by the Aharonov-Bohm ring with superconducting (SC) wire in the topologically nontrivial state playing a role of a bridge between top and bottom arms. We analyze Majorana modes on the ends of the SC wire and show that the collapse of the ...
Added: April 10, 2024
Saitov S., Amasev D., Aleksandrov A. et al., Organic Electronics: physics, materials, applications 2023 Vol. 112 Article 106693
The photoconductivity in thin films of a new composite based on CdSe nanoplatelets (NPLs) and PCDTBT polymer has been studied using photoconductivity temperature dependences, current-voltage and lux-ampere measurements at various temperatures and applied bias. The incorporation of 7 vol% of NPLs into the polymer blend led to an increase in photoconductivity by an order of magnitude compared to the pristine PCDTBT film in the temperature range ...
Added: February 1, 2024
Ребров Я. В., Glazkov V., Murtazoev A. F. et al., / Series cond-mat "arxiv.org". 2023.
Nabokoite family compounds ACu7(TeO4)(SO4)5Cl (A=Na, K, Cs, Rb) are one of the candidates for the evasive spin-liquid state predicted for highly-frustrated square kagome lattice (SKL). Their magnetic subsystem includes SKL layers decorated by additional copper ions. All members of this family are characterized by quite high Curie-Weiss temperatures (∼80−200 K), but magnetic ordering was reported ...
Added: January 29, 2024