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About the microscopic picture of the hole transport in dehdoped polycarbonate
P. 557-558.
Our approach to the problem of charge carrier transport in homogeneous polymers assumes carrier hopping on a densely packed manifold of transport (hopping) centers retaining the short-range order of the respective single crystal. The central idea, which distinguishes it from the Bassler’s disorder theory, is that the energy scatter concerns only a small fraction of hopping centers, which begin to act as traps. The majority of isoenergetic centers build up a transfer band with microscopic mobility µ0 equal to that in the respective single crystal. The origin of the energy scatter (and traps themselves) is ascribed to the elementary voids of the fluctuation free volume forming an association with the normal hopping centers.
In book
* 2. , M. : HSE, 2014
Sadovnichii D. N., A.P. Tyutnev, Milekhin Y. M., Russian Chemical Bulletin 2020 No. 9 P. 1607-1613
The modern state of experimental and theoretical studies of the radiation-induced conductivity and charging of polymeric dielectrics under the action of electron beams is considered. The eff ect of the molecular mobility on the transport of excess charge carriers is discussed. ...
Added: December 19, 2020
Chistyakov A., Zvaigzne M., Nikitenko V. et al., The Journal of Physical Chemistry Letters 2017 Vol. 8 No. 17 P. 4129-4139
Quantum dot (QD) solids represent a new type of condensed matter drawing high fundamental and applied interest. Quantum confinement in individual QDs, combined with macroscopic scale whole materials, leads to novel exciton and charge transfer features that are particularly relevant to optoelectronic applications. This Perspective discusses the structure of semiconductor QD solids, optical and spectral ...
Added: October 7, 2017
Fishchuk I. I., Kadasnchuk A., Novikov S. V. et al., Molecular Crystals and Liquid Crystals 2014 Vol. 589 P. 18-28
We report on the influence of the lateral electric field on the charge mobility in organic field-effect transistors (OFET) based on C 60 films with multigrain morphology. The experimental data were quantitatively described using a recent analytical model by accounting for the strong local electric fields in a multigrain transistor channel and for the energy ...
Added: March 4, 2015
A.P. Tyutnev, B.L. Linetskiy, A.V. Nikerov et al., Russian Journal of Physical Chemistry B 2015 Vol. 9 No. 4 P. 648-657
Abstract—A theoretical analysis of the nonlinear field dependence of the pulsed radiationinduced conductiv ity of polystyrene in strong electric fields is performed. An explanation of the previously uncomprehended phe nomenon of the sharp increase in the radiationinduced electrical conductivity in the presence of an electric field with a strength of above 5 × 107 V/m ...
Added: January 18, 2016
Novikov S. V., / Cornell University. Series cond-mat "arxiv.org". 2022. No. 2209.14955.
Charge transport in amorphous semiconductors having spatially correlated exponential density of states (DOS) has been considered for the arbitrary behavior of the correlation function of random energies. Average carrier velocity is exactly calculated for the quasi-equilibrium (nondispersive) transport regime. For the symmetric exponential DOS with exponential tails for low and high energies and non-positive correlation ...
Added: November 1, 2022
Омельченко О. Д., Грибкова О. Л., Тамеев А. Р. et al., Физикохимия поверхности и защита материалов 2014 Т. 50 № 5 С. 512-518
Two techniques of manufacturing a nanocomposite based on a complex of polyaniline with polymer acid and graphene are proposed. The electric conductivity of thin nanocomposite layers is higher than that of a polymer complex of polyaniline and strongly depends on the degree of oxidation of graphene. An explanation of the effect is suggested that takes ...
Added: February 28, 2015
Martynov Y., Nazmitdinov R., Moia-Pol A. et al., Physical Chemistry Chemical Physics 2017 Vol. 19 No. 30 P. 19916-19921
Organometal triiodide perovskites are promising, high-performance absorbers in solar cells. Considering the perovskite as a thin film absorber, we solve transport equations and analyse the efficiency of a simple heterojunction configuration as a function of electron–hole diffusion lengths. We found that for a thin film thickness of ~1 micron the maximum efficiency of ~31% could ...
Added: September 29, 2017
Afanasyeva M., В кн. : Innovative Information Technologies: Materials of the International scientific–practical conference. Part 2. * 2.: M. : HSE, 2014. С. 417-420.
...
Added: November 23, 2015
A.P. Tyutnev, V.S. Saenko, Aleshkevich A. et al., Polymer Science - Series A 2017 Vol. 59 No. 4 P. 575-578
Abstract—Transient current curves in a polar molecularly doped polymer for subsurface and bulk generations of charge carriers are compared. No transformation of the horizontal plateau on the former to the curve predicted by the diffusion and drift theory was found, contrary to expectations for quasi-equilibrium transport conditions. This behavior indicates a nonequilibrium character of the ...
Added: June 15, 2017
49601782, Ikhsanov R., 49601816 et al., Journal of Applied Physics 2020 Vol. 128 No. 225501 P. 1-8
Numerical calculations have been performed on the time of flight transients predicted by a newly developed model describing consistently the radiation-induced conductivity of common insulating polymers under both pulsed and continuous irradiation. The model differs substantially from the conventional multiple trapping formalism based on an exponential trap distribution by the presence of additional deep traps distributed in energy ...
Added: December 5, 2020
Afanasyeva M., В кн. : Научно-техническая конференция студентов, аспирантов и молодых специалистов НИУ ВШЭ. Материалы конференции. : М. : МИЭМ НИУ ВШЭ, 2014. С. 209-210.
...
Added: November 23, 2015
Dunlap D. H., Schein L. B., Tyutnev A. et al., Journal of Physical Chemistry 2010 Vol. 114 No. 19 P. 9076-9088
The mechanism of charge transport in molecularly doped polymers has been the subject of much discussion over the years. In this paper, data obtained from a new experimental variant of the time-of-flight (TOF) technique, called TOF1a, are compared to the predictions of a two-layer multiple trapping model (MTM) with an exponential distribution of traps. In ...
Added: April 12, 2012
49601782, Novikov S. V., Journal of Chemical Physics 2013 Vol. 138 No. 104120 P. 1-9
We present the results of Monte Carlo simulations of the charge carrier transport in a disordered molecular system containing spatial and energetic disorders using the dipolar glass model. Model parameters of the material were chosen to fit a typical polar organic photoconductor polycarbonate doped with 30% of aromatic hydrazone, whose transport properties are well documented ...
Added: April 3, 2013
Novikov S. V., Tyutnev A., Schein L. B., Chemical Physics 2012 No. 403 P. 68-73
Using Monte Carlo simulation we investigated time of flight current transients predicted by the dipolar glass model for a random spatial distribution of hopping centers. Behavior of the carrier drift mobility was studied at room temperature over a broad range of electric field and sample thickness. A flat plateau
followed by current decay is the most ...
Added: November 7, 2012
А.П. Тютнев, Б.Л. Линецкий, А.В. Никеров et al., Химическая физика 2015 Т. 34 № 7 С. 58-61
A theoretical analysis of the peculiarities of the nonlinear field dependence of radiation-pulse conductivity of polystyrene in strong electric fields. The explanation of previously misunderstood the rapid increase of the radiation conductivity in electric fields, the intensity of which exceeds 5E7 V/m. this behavior cannot be explained on the basis of the Onsager theory for ...
Added: May 25, 2015
A. P. Tyutnev, A. V. Nikerov, V. S. Saenko, et al., Polymer Science - Series A 2015 Vol. 57 No. 1 P. 94-100
Abstract—The multipletrapping model with a Gaussian trap distribution was used for the numerical analysis of the effects of nonequilibrium transport on the temperature dependence and field dependence of the mobility of carriers in a typical molecularly doped polymer. It was shown that, with allowance for the prescribed Poole–Frenkel Frenkel type field dependence of mobility under ...
Added: May 24, 2015
49601782, Ikhsanov R., Novikov S. V., Chemical Physics 2014 Vol. 440 P. 1-7
We have compared time-of-flight curves predicted by hopping and multiple trapping models with the Gaussian and exponential site/trap energy distributions, fitting Monte-Carlo predictions of the former with numerical calculations of the latter in a wide time domain using logarithmic coordinates lg j–lg t for the characterization of current shapes and an estimation of transit times. As a ...
Added: February 28, 2015
Afanasyeva M., В кн. : Инновации на основе информационных и коммуникационных технологий: Материалы международной научно-практической конференции, 2014. : М. : НИУ ВШЭ, 2014. С. 457-459.
...
Added: November 23, 2015
Afanasyeva M., В кн. : Научно-техническая конференция студентов, аспирантов и молодых специалистов НИУ ВШЭ им. Е.В. Арменского. Материалы конференции. : М. : МИЭМ НИУ ВШЭ, 2016.
В работе рассматриваются основные методы защиты технических средств от влияния электростатических разрядов. Также исследуются модели испытаний технических средств на определение их устойчивости к возникновению электростатических разрядов. ...
Added: June 6, 2016
Садовничий Д. Н., А.П. Тютнев, Мелехин Ю. М., Известия Академии наук. Серия химическая 2020 № 9 С. 1607-1613
В обзоре рассмотрено современное состояние вопросов экспериментального и теоретического изучения радиационно-индуцированной электропроводности и электризации полимерных диэлектриков при воздействии пучков электронов. Обсуждается влияние молекулярной подвижности на транспорт избыточных носителей заряда в полимерных материалах. ...
Added: December 15, 2020
Tyutnev A., Saenko V. S., Pozhidaev E., Chemical Physics 2011 Vol. 114 No. 389 P. 75-80
The dipolar disorder formalism (DDF) of Borsenberger and Bдssler has been further developed based on a unified approach treating the van der Waals and the dipolar disorder energies as being roportional to mean intersite distance in a certain power. Tested against real molecularly doped polymers with the concentration of the dopant changing in a wide ...
Added: April 12, 2012