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Selective laser spectroscopy of a highly dispersed Bi4Ge3O12 scintillator doped with Pr3+ ions

Optical Materials. 2022. Vol. 128. Article 112330.
Alimov O., Doroshenko M., Egorysheva A., Gajtko O., Pierpont K., Shodiev H., Veselova V.

The optical properties of a highly dispersed bismuth orthogermanate powder (HDP_BGO) were studied at 300 K. The fluorescence of undoped HDP_BGO under ultraviolet (UV) excitation (266nm) was shown to result from Frenkel excitons. The HDP_BGO fluorescence decay kinetics under UV excitation had a complex decay form similar to that of BGO single crystal and was a sum of four exponentialswith lifetimes τ 1, 2, 3, 4– 0.16/0.30/0.70/2.7 μs respectively. Two types of Pr ions optical centers with lifetimes of ~5.0 and 85 μs have been determined in a HDP_BGO: Pr3+. The resonance energy transfer of the electronic excitation from the HDP_BGO to Pr3‡ions was identified. The effect of Pr3+ ions on the HDP_BGO fluorescence lifetime reduction from 160 to 35 ns was established.

Research target: Chemistry Physics
Language: English
Full text
DOI
Keywords: energy transferluminescence kineticsfluorescenceLaser spectroscopy
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