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Nonlinear spectroscopy of excitonic states in transition metal dichalcogenides

Physical Review B: Condensed Matter and Materials Physics. 2022. Vol. 105. No. 11. Article 115436.
Zhumagulov Y., Vyacheslav D. Neverov, Alexander E. Lukyanov, Gulevich D., Andrey V. Krasavin, Vagov A., Perebeinos V.

Second-harmonic generation (SHG) is a well-known nonlinear spectroscopy method to probe electronic
structure, specifically, in transition metal dichalcogenide (TMDC) monolayers. This work investigates the
nonlinear dynamics of a strongly excited TMDC monolayer by solving the time evolution equations for the
density matrix. It is shown that the presence of excitons qualitatively changes the nonlinear dynamics leading,
in particular, to a huge enhancement of the nonlinear signal as a function of the dielectric environment. It is also
shown that the SHG polarization angular diagram and its dependence on the driving strength are very sensitive
to the type of exciton state. This sensitivity suggests that SHG spectroscopy is a convenient tool for analyzing
the fine structure of excitonic states.

Research target: Physics Nanotechnologies Materials Technologies
Language: English
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Keywords: nonlinear opticsнелинейная оптикаspectroscopyспектроскопияsecond harmonic generationгенерация второй гармоникиlow-dimensional materialsнизкоразмерные материалы
Publication based on the results of:
Investigations of quantum effects in low-dimensional materials  (2022)
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