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Regular version of the site

Article

Chemical Transformations of Biomass-Derived C6-Furanic Platform Chemicals for Sustainable Energy Research, Materials Science, and Synthetic Building Blocks

ACS Sustainable Chemistry & Engineering. 2018. Vol. 6. No. 7. P. 8064-8092.
Kucherov F. A., Romashov Leonid V., Ananikov V. P., Galkin K. I.

Recent advances in the area of biomass-derived C6-furanic platform chemicals for sustainable biomass
processing are analyzed focusing on chemical reactions important for development of practical applications and
materials science. Among the chemical processes currently being studied, tuning the amount of oxygen-containing
functional groups remains the most active research direction. Production of efficient fuels requires the removal of oxygen atoms (reduction reactions), whereas utilization of biomassderived furanic derivatives in material science points out the importance of oxidation in order to form dicarboxylic derivatives. Stimulated by this driving force, oxidation and reduction of 5-(hydroxymethyl)furfural (HMF) are nowadays massively studied. Moreover, these fundamental transformations are often used as model reactions to test new catalysts, and HMF transformations guide the development of new catalytic systems. From the viewpoint of organic synthesis, highly diverse chemical reactivity is explored and a number of bioderived synthetic building blocks with different functional groups are now accessible. This Perspective covers the most recent literature (since Jan 2017) to highlight the emerging research trends.