• A
  • A
  • A
  • АБВ
  • АБВ
  • АБВ
  • A
  • A
  • A
  • A
  • A
Обычная версия сайта
  • RU
  • EN
  • HSE University
  • Publications
  • Articles
  • Hydrogenation of Unsaturated Hydrocarbons on Platinum and Palladium Catalysts Encapsulated in Mesoporous Bakelites
  • RU
  • EN
Расширенный поиск
Высшая школа экономики
Национальный исследовательский университет
Priority areas
  • business informatics
  • economics
  • engineering science
  • humanitarian
  • IT and mathematics
  • law
  • management
  • mathematics
  • sociology
  • state and public administration
by year
  • 2028
  • 2027
  • 2026
  • 2025
  • 2024
  • 2023
  • 2022
  • 2021
  • 2020
  • 2019
  • 2018
  • 2017
  • 2016
  • 2015
  • 2014
  • 2013
  • 2012
  • 2011
  • 2010
  • 2009
  • 2008
  • 2007
  • 2006
  • 2005
  • 2004
  • 2003
  • 2002
  • 2001
  • 2000
  • 1999
  • 1998
  • 1997
  • 1996
  • 1995
  • 1994
  • 1993
  • 1992
  • 1991
  • 1990
  • 1989
  • 1988
  • 1987
  • 1986
  • 1985
  • 1984
  • 1983
  • 1982
  • 1981
  • 1980
  • 1979
  • 1978
  • 1977
  • 1976
  • 1975
  • 1974
  • 1973
  • 1972
  • 1971
  • 1970
  • 1969
  • 1968
  • 1967
  • 1966
  • 1965
  • 1964
  • 1963
  • 1958
  • More
Subject
News
September 9, 2026
‘Balkan Hospitality Opens Doors: Studying Dialects on the Verge of Extinction
You cannot study spoken dialects from books. Instead, you need to go to a village, seek out its elders, and earn the trust of local residents before you can record hours of spontaneous stories. This is how Natalia Muravleva, Associate Professor at the Faculty of Humanities, conducts her research. Her internship in Serbia continued her long-standing study of dialects spoken by Macedonian settlers. In this interview, she discusses how diaspora cultural centres help researchers reach informants, why native speakers need to be interviewed only in their own language (otherwise, as she puts it, they may 'break'), and how a single field season helped her finalise her monograph. She also shares warm memories of autumn in Belgrade and of colleagues with whom grammar can be discussed in three languages at once.
September 9, 2026
Scientists Train Neural Network to Generate Process Plans from 3D Models
Researchers at the HSE FCS AI and Digital Science Institute have developed CAD2TechSpec, a framework that converts 3D models of mechanical parts into machining process plans—step-by-step instructions for machine tools. The solution aims to reduce the time required for the design and preparation of technical process documentation in mechanical engineering, aircraft manufacturing, and other high-tech industries. The study findings have been published in PeerJ Computer Science.
September 7, 2026
Biologists Discover 'Molecular Fingerprint' of Preeclampsia
Researchers at HSE University employed a new method to model hypoxia in placental cells during pregnancies complicated by preeclampsia and identified molecular markers of tissue hypoxia. Since hypoxia is one of the key mechanisms underlying preeclampsia, these findings are important for a more accurate and timely diagnosis of the disease and for the development of effective treatment methods. The paper has been published in Placenta.

 

Have you spotted a typo?
Highlight it, click Ctrl+Enter and send us a message. Thank you for your help!

Publications
  • Books
  • Articles
  • Chapters of books
  • Working papers
  • Report a publication
  • Research at HSE

?

Hydrogenation of Unsaturated Hydrocarbons on Platinum and Palladium Catalysts Encapsulated in Mesoporous Bakelites

Chemistry and Technology of Fuels and Oils. 2017. Vol. 53. No. 3. P. 318–332.
Boronoev M. P., Kulikov A., Subbotina E. S., Kulikov L. A., Egazar’yants S. V., Kardasheva Y. S., Maksimov A. L., Karakhanov E. A.

Syntheses are reported for catalysts derived from platinum and palladium nanoparticles supported on a mesoporous phenol formaldehyde polymer modified by an ionic liquid. These catalysts are used for the hydrogenation of unsaturated compounds, specifically, acyclic and cyclic isoprenoids: isoprene, 2,5 – dimethyl–2,4–hexadiene, limonene, α –terpinene, γ –terpinene, as well as phenylacetylene, transstilbene, and 1,4–diphenyl–1,3–butadiene. High activity was found for these catalysts in hydrogenation reactions. The palladium catalysts were more active than their platinum analogs. The products of complete hydrogenation predominate in the hydrogenation of isoprenoids on the palladium catalysts, while monoene products predominate in the reactions on platinum catalysts.

Research target: Chemistry Chemical Technologies Effective Natural Resource Management
Language: English
Full text
DOI
Text on another site
Keywords: hydrogenationpalladiummesoporous materialsunsaturated compounds
Similar publications
2,2-Diaryl-1,3,2-dioxaborines based on curcumin: synthesis, photophysical properties and preliminary biological studies
Nazarov Alexey A., Dudarova N., Zhidkova O. et al., Journal of Photochemistry and Photobiology A: Chemistry 2026 Vol. 483 Article 117654
Сyclocondensation of phenyl, ortho-bromophenyl, para-phenylphenyl, para-methoxycarbonylphenyl, para-tolyl and para-methoxyphenyl boronic acid with curcumin in the presence of K3PO4 upon refluxing in 1,4-dioxane for 24 h leads to the formation of curcumin-based 2,2-diaryl-1,3,2-dioxaborines in good yields. The absorption-emission spectra of the synthesized fluorescent conjugates and 1,3,2-dioxaborine with para-biphenyl boronic substituent demonstrated the highest quantum yield. Among the compounds studied, conjugate curcumin with para-methoxycarbonylphenyl boronic substituent ...
Added: September 9, 2026
Degree-based topological co-indices for QSPR modelling of benzenoid hydrocarbons: a comparative computational study
Chemical Papers 2026
Benzenoid hydrocarbons are structurally regular aromatic compounds, which makes them well suited for quantitative structure–property relationship (QSPR) studies. This study presents a QSPR analysis of nineteen benzenoid hydrocarbon species using degree-based topological co-indices. We developed a Python program to compute eleven degree-based topological co-indices from molecular graphs and evaluated their ability to explain variations in ...
Added: September 8, 2026
Bridging experiment and molecular dynamics: Mefenamic acid confinement in nanocrystalline cellulose aerogels under scCO2 conditions
Gurina D., Fashchevsky K. A., Oparin R. D. et al., Surfaces and Interfaces 2026 Vol. 98 Article 110545
In this work, we combine experimental characterization and molecular dynamics (MD) simulations to elucidate the molecular mechanisms governing the impregnation of mefenamic acid (MFA) into nanocrystalline cellulose (NCC) aerogels. NCC aerogels were impregnated with MFA in scCO2, and low-temperature nitrogen adsorption revealed a concentration-dependent decrease in surface area, pore volume, and pore size, with an ...
Added: September 8, 2026
Stress tensor of inhomogeneous flexible polymer chain solutions beyond the ground-state dominance approximation
Budkov Y., Journal of Chemical Physics 2026 Vol. 165 No. 9 Article 094902
We derive the stress tensor of a flexible polymer solution within the Gaussian-chain self-consistent field theory (SCFT) without invoking the ground-state dominance (GSD) approximation. Starting from a covariant formulation of the single-chain partition function in a background metric, we obtain the symmetric stress tensor expressed through the full Edwards propagators. The result contains the local ...
Added: September 2, 2026
“-Ethylene” vs “-ethane”: How minor cation variations drive the self-assembly of structurally different supramolecular diiodine-halometalate hybrid complexes
Novikov A., Polyhedron 2026 Vol. 299 Article 118358
Two new supramolecular halometalate hybrid complexes, (H2bpen){[MCl5](I2)} (M = Sb(III) (1) and Bi(III) (2); bpen – 1,2-Bis(4-pyridyl)ethylene, have been prepared. Despite very close similarity of the nature of cations, they reveal significant structural difference from the (H2bpe){[MCl5](I2)} (bpe – 1,2-bis(4-pyridil)ethane) reported earlier. We discuss these features, along with thermal stability, optical properties as well as Raman spectra ...
Added: September 2, 2026
Monometallic Ln3+ and heterometallic Ln3+–Cd2+ complexes based on pentafluorophenylacetic acid: efficient control of dimension and luminescent properties
Belousov Y., Кискин М. А., Sidoruk A. et al., Australian Journal of Chemistry 2022 Vol. 75 No. 9 P. 572–580
Four new complexes [Ln(pfaa)3(H2O)2]n (Ln = Eu (1), Tb (2)) and [Ln2Cd2(pfaa)10 (phen)2(EtOH)2]·2MeCN (Ln = Eu (3), Tb (4), phen = 1,10-phenanthroline) based on pentaphorphenylacetic acid (Hpfaa) have been prepared and completely investigated. The structures of compounds 1 and 3 were studied by single crystal X-ray diffraction analysis: the isostructural complexes 1 and 2 represent ...
Added: August 26, 2026
Understanding the electric double layer at electrode–electrolyte interfaces, Part III: crystallographic-face dependence of silver capacitance in aqueous NaF solutions
Mazur D., Petr E. Brandyshev, Doronin S. et al., Electrochimica Acta 2026 Vol. 577 Article 149729
The electric double layer (EDL) at a single-crystal metal surface is controlled not only by the electrolyte composition and the electrode potential, but also by the atomic structure of the surface itself. This makes the Ag(hkl)/NaF interface a stringent test for continuum theories of the EDL. In the third part of our series, we examine ...
Added: August 20, 2026
Hall effect in electrolyte solutions: Self-consistent Debye–Hückel–Onsager theory
Budkov Y., Kalikin N., Journal of Chemical Physics 2026 Vol. 165 Article 064506
A self-consistent statistical-mechanical theory of the Hall effect in electrolyte solutions is developed by extending the self-consistent Debye–Hückel–Onsager (SCDHO) framework to crossed electric and magnetic fields. The theory incorporates non-local ionic charge distributions via Slater-type form factors, regularizing the Coulomb interaction at short range, and accounts for dielectric friction through ion-specific coefficients, employing experimental values ...
Added: August 12, 2026
Charge-controlled binding, alloy synergy, and the copper anomaly in Au–Ag–Cu dimers to clusters: DFT-derived design rules for targeted drug delivery
Obijiofor O., Alexander S. Novikov, New Journal of Chemistry 2026 Vol. 50 No. 33 P. 13931–13957
The rational design of coinage metal nanocarriers requires a mechanistic understanding of metal-drug binding and predictive descriptors that translate molecular interactions into design rules. Using DFT (B3LYP-D3BJ/def2-TZVP, SMD water), we systematically investigated the binding of 5-fluorouracil (5-FU) and levodopa (l-DOPA) to neutral and cationic homo- and heteronuclear dimers of Au, Ag, and Cu (Au2, Ag2, ...
Added: August 12, 2026
Assessing walkability and climate adaptive capacity in relation to urban morphology and historical development
Shartova N., Mironova E., Geo Journal 2026 Vol. 91 Article 78
The historical timeline of urban development profoundly shapes the contemporary form and functionality of cities. Traditionally, cities were planned with limited consideration for the promotion of a healthy urban environment. Using Nizhny Novgorod, Russia, a city that has evolved from a medieval market town to an industrial centre and later into a multifunctional city with ...
Added: August 9, 2026
Картографирование усыхания хвойных лесов по данным дистанционного зондирования Земли на примере лесов хребта Хамар-Дабан
Tsydypova M., Современные проблемы дистанционного зондирования Земли из космоса 2026 Т. 23 № 3 С. 263–275
The article presents a methodology for mapping coniferous forest decline, based on the integration of automated remote sensing data interpretation techniques, vegetation indices, remote sensing data on above-ground biomass (Biomass CCI (Climate Change Initiative)), and materials from ground-based forest pathology surveys using forests of the Khamar-Daban ridge (Republic of Buryatia) as a case study. The ...
Added: August 9, 2026
Encyclopedia of Ecology, 3rd Edition. Volume 3
Sandlerskiy R., Elsevier, 2026.
Encyclopedia of Ecology, Third Edition, Four Volume Set - with over 300 chapters - once again provides a comprehensive reference work covering the current ideas and practices in ecology. Ecology is the ideal field for studying complex, adaptive, and self-organizing systems and by observing and understanding ecosystems, it provides valuable insights into creating sustainable systems. This knowledge is ...
Added: August 9, 2026
Surface-sulfonated Al₂O₃, CeO₂, and TiO₂ as functional fillers for Nafion-type gel polymer electrolytes for lithium metal batteries
Voropaeva D., S. Novikova, I. Stenina et al., Solid State Ionics 2026 Vol. 445 Article 117288
Composite gel polymer electrolytes based on a perfluorinated sulfonic acid cation-exchange MF-4SC membrane containing surface-sulfonated nanoparticles of aluminum oxide, cerium (IV) oxide, and titanium oxide (sAl2O3, sCeO2, and sTiO2, respectively) were prepared by casting from a dispersion in N,N-dimethylformamide and plasticized with a 1,3-dioxolane/1,2-dimethoxyethane mixture. The influence of the filler nature on ionic conductivity, solvent uptake, activation energy, lithium ...
Added: July 30, 2026
Catalytic Hydrogenation of Carbon Dioxide as a Method to Produce Valuable Chemicals
Makaryan I. A., Sedov I., Savchenko V. I., Catalysis in Industry 2024 Vol. 16 No. 1 P. 14–38
The aim of this review is to summarize and comparatively analyze recent reports on studying carbon dioxide conversion to methanol, dimethyl ether, and C2+ hydrocarbons, in particular, olefins, by catalytic hydrogenation. It is shown that the main approaches to providing high activity and selectivity of these processes are the targeted design of catalysts and the selection of conditions ...
Added: February 24, 2025
Phosphorescent Cyclometalated Palladium(II) and Platinum(II) Complexes Derived from Diaminocarbene Precursors
Kashina M., Luzyanin K., Dar'in D. et al., Inorganic Chemistry 2024 Vol. 63 No. 12 P. 5315–5319
Metal-mediated self-assembly of isocyanides and methyl 4-aminopyrimidine-5-carboxylate leads to luminescent PdII and PtII complexes featuring C,N-cyclometalated acyclic diaminocarbene (ADC) ligands. The solid-state luminescent properties of these diaminocarbene derivatives are attributed to their triplet-state metal/metal-to-ligand charge-transfer (3MMLCT) nature, which is driven by attractive intermolecular M···M interactions further reinforced by the intramolecular π–π interactions even in the ...
Added: September 16, 2024
Hydrogenation-controlled band engineering of dumbbell graphene
Song Y., Chen M., Xie X. et al., Nano Energy 2024 Vol. 127 Article 109763
The stability of the dumbbell structure has been confirmed by previous theory and experiment. Based on first-principles calculations, we proposed hexagonal dumbbell graphene (HDB C10) and rectangular dumbbell graphene (RDB C10) monolayers containing periodically raised C (CR) atoms. They turn out to have high mobility semiconductor properties. By adsorbing H atoms on these CR atoms, ...
Added: May 24, 2024
Base-Ionizable Anionic NHC Ligands in Pd-catalyzed Reactions of Aryl Chlorides
Chernenko A., Baydikova V., Kutyrev V. et al., ChemCatChem 2024 Article e202301471
Aryl chlorides, due to their affordability and accessibility, are preferred reagents in Pd-catalyzed arylation reactions. However, the reactivity of aryl chlorides is often lower than that of aryl bromides and iodides due to the significantly higher barriers of the oxidative addition stage. This research introduces a novel design for NHC ligands, which notably enhances the ...
Added: February 14, 2024
Noble Metal versus Abundant Metal Catalysts in Fine Organic Synthesis: Cost Comparison of C–H Activation Methods
Komarova A., Dmitry S. Perekalin, Organometallics 2023 Vol. 42 No. 13 P. 1433–1438
There is a common assumption that replacement of the classical catalyst based on rare and expensive noble metals by the catalysts based on earth-abundant metals will dramatically reduce the costs of organic synthesis. Herein we demonstrate that it may not be true, mainly because sophisticated organic substrates and modern reagents are often as expensive as ...
Added: August 11, 2023
Palladium Nanoparticles Entrapped In a Hydrogen Bonded Crystalline Organic Salt Matrix as a Selective Heterogeneous Reduction Catalyst
Kuznetsova S., Yunusov S., Gak A. et al., ChemistrySelect 2022 Vol. 7 No. 41 Article e202203011
Hydrogen bonded crystalline organic salt matrix encapsulates Pd nanoparticles and makes them selective non-pyrophoric catalysts towards reduction of carbon – carbon triple bonds, inhibiting simultaneous C=O reduction. The comparison of the catalytic performance with Pd/C was carried out to show similar catalytic activity of both catalysts towards C=C bonds. ...
Added: January 31, 2023
Mechanistic Studies for Pd(II)(O2) Reduction Generating Pd(0) and H2O: Formation of Pd(OH)2 as a Key Intermediate
Cha J., Lee E., Dmitry V. Yandulov, Inorganic Chemistry 2022 Vol. 61 No. 37 P. 14544–14552
Molecular oxygen (O2) remains to be an ideal yet underutilized feedstock for the oxidative transformation of organic substrates and renewable energy systems such as fuel cells. Palladium (Pd) has shown particular promise in enabling these applications. The present study describes a Pd-mediated O2 reduction to water via C–H activation of 9,10-dihydroanthracene (DHA) by a Pd(II) ...
Added: October 24, 2022
On the Mechanism of the Oxidative Cleavage of N-Heterocyclic-Carbene–Palladium Bonds with Iodine
Lee E., Lee J., Yandulov D. V., European Journal of Inorganic Chemistry 2017 Vol. 2017 P. 2058–2067
Added: October 24, 2022
A Highly Substitutable Palladium(II) Complex Stabilized by the Smallest Steric N-Heterocyclic Carbene, IMe (IMe = 1,3-Dimethylimidazole-2-ylidene)
Lee E., Bae D. Y., Yandulov D. V., Bulletin of the Korean Chemical Society 2016 Vol. 37 P. 1745–1746
Added: October 24, 2022
A Palladium(II) Peroxido Complex Supported by the Smallest Steric N-Heterocyclic Carbene, IMe = 1,3-Dimethylimidazole-2-ylidene, and Its Reactivity by Oxygen-Atom Transfer
Lee E., Bae D. Y., Park S. et al., European Journal of Inorganic Chemistry 2016 Vol. 2016 P. 4561–4564
Added: October 24, 2022
Удивительный пример сохранения необычной куполообразной структуры 3,5-ди-(трет-бутил)-2-оксиазобензола PDII в кристалле и газовой фазе
Tkachev V., Bozhenko K., Utenyshev A. et al., Известия РАН. Серия химическая 2021 Т. 70 № 5 С. 847–856
The structure of the newly synthesized palladium(ii) 3,5-di(tert-butyl)-2-oxyazobenzene, PdL2, was determined by X-ray diffraction. The metal chelate was found to adopt an unusual domed conformation, with the trans-planar coordination unit at the top. This is the first complex of this class, the domed structure of which was confirmed by X-ray diffraction and in which the ...
Added: September 14, 2021
  • About
  • About
  • Key Figures & Facts
  • Sustainability at HSE University
  • Faculties & Departments
  • International Partnerships
  • Faculty & Staff
  • HSE Buildings
  • HSE University for Persons with Disabilities
  • Public Enquiries
  • Studies
  • Admissions
  • Programme Catalogue
  • Undergraduate
  • Graduate
  • Exchange Programmes
  • Summer University
  • Summer Schools
  • Semester in Moscow
  • Business Internship
  • Research
  • International Laboratories
  • Research Centres
  • Research Projects
  • Monitoring Studies
  • Conferences & Seminars
  • Academic Jobs
  • Yasin (April) International Academic Conference on Economic and Social Development
  • Media & Resources
  • Publications by staff
  • HSE Journals
  • Publishing House
  • iq.hse.ru: commentary by HSE experts
  • Library
  • Economic & Social Data Archive
  • Video
  • HSE Repository of Socio-Economic Information
  • HSE1993–2026
  • Contacts
  • Copyright
  • Privacy Policy
  • Site Map
Edit