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Organometallic derivatives of Rh- and Ir-substituted polyoxotungstates with Keggin structure: reactivity screening by electrospray ionization mass-spectrometry
Dalton Transactions. 2012. Vol. 41. No. 33. P. 9889–9892.
Mainichev D. A., Sokolov M. N., Adonin S. A., Sinkevich P. L., Vicent C., Fedin V. P.
ESI-MS based methodology for the rapid reactivity screening of [PW11O39RhCl]5− and [PW11O39Ir(H2O)]4− toward various metalation-intended substrates (reagents with an activated C–H bond, boronic acids and organotin compounds) is presented. Formation of a series of new organometallic POM derivatives with Rh–R (R = malonate, phenylacetate, CH3, Ph, ferrocenyl) and Ir–R (R = CH3) bonds is reported.
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Added: October 2, 2026
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Added: October 1, 2026
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Added: October 1, 2026
Pakhlov P., Pakhlova G., Bodrov D. et al., Journal of High Energy Physics 2026 Article 278
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Added: October 1, 2026
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Teregulov T., Loubenets E. R., / Series Quantum Physics "arXiv". 2026. No. 2609.31472.
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Levashev V., / Series arXiv "math". 2026. No. 2609.06010.
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