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Ising-like Magnetism in Quasi-Two-Dimensional Co(NO3)2·2H2O
Materials. 2022. Vol. 15. No. 20. P. 7066–0.
Vorobyova A., Danilovich I. L., Morozov I., Vasiliev A., Volkova O., Iqbal A., Rahaman B., Saha-Dasgupta T.
Keywords: magnetic properties
Ekaterina N. Zorina-Tikhonova, Matiukhina A., Korlyukov A. et al., CrystEngComm 2025 Vol. 27 No. 20 P. 3352–3361
In this work, new NiII coordination compounds with cyclopropane-1,1-dicarboxylic acid (H2cpdc) dianions were synthesized: {[Na2Ni(cpdc)2(H2O)6]·4H2O}n (1), {[K6Ni3(cpdc)6(H2O)10]·8H2O}n (2),
{[Rb6Ni3(cpdc)6(H2O)12]·5.5H2O}n (3), and [Cs2Ni(cpdc)2(H2O)8]n (4). All complexes contained mononuclear bischelate fragments {NiII(cpdc)2(H2O)2}2− bound by alkali atoms in a 1D coordination polymer for 1, 2D for 2 and 4, and 3Dfor 3. In the topological representation of coordination bonds ...
Added: June 3, 2025
Matiukhina A., Ekaterina N. Zorina-Tikhonova, Daniil O. Blinou et al., Journal of Magnetism and Magnetic Materials 2025 No. 614 Article 172650
The interaction of Co(NO3)2⋅6H2O and MI2CO3 (MI = Rb or Cs) with dimethylmalonic acid (H2Me2mal) leads to
the formation of 3D polymeric compounds: {[Co4Rb8(Me2mal)8(H2O)8]⋅5H2O}n (1) and {[CoCs2(Me2mal)2
(H2O)4]⋅H2O}n (2), respectively. The structures of 1 and 2 were characterized using X-ray diffraction analysis
and IR spectroscopy. Each complex contains CoII atoms arranged in four vertex polyhedra. Both compounds
exhibit field-induced ...
Added: February 20, 2025
Harin E. V., Sheftel E. N., Tedzhetov V. A. et al., Thin solid films 2024 Vol. 807 Article 140544
Investigation and quantifying of the parameters of the phase and structure state, static magnetic properties, magnetic microstructure formed over the entire volume of the film and in the near-surface layer, the surface roughness of Fe72.4Ti5.4B19.2O3.0 film were carried out using the combination of the methods such as x-ray diffraction, magnetic force microscopy, atomic force microscopy, ...
Added: December 9, 2024
Zorina-Tikhonova E., Chistyakov A., Novikova V. et al., CrystEngComm 2023 Vol. 25 No. 19 P. 2859–2870
Added: September 17, 2024
Rinat F. Salikov, Belyy A., Matvey K. Ilyushchenko et al., Chemistry - A European Journal 2024 Vol. 30 No. 41 Article e202401041
Investigations of the nature and degree of antiaromaticity of cycloheptatrienyl anion derivatives using both experimental and computational tools are presented. The ground state of cycloheptatrienyl anion in the gas phase is triplet, planar and Baird-aromatic. In DMSO, it assumes a singlet distorted allylic form with a paratropic ring current. The other derivatives in both phases ...
Added: July 12, 2024
Vorobyova A., Danilovich I. L., Morozov I. et al., Journal of Alloys and Compounds 2022 Vol. 929 P. 167197–0
Two novel transition metal nitrates (NO)M(NO3)3 (M = Co, Ni) have been characterized in thermodynamic measurements. The structure of these compounds provides a unique opportunity for accommodation of Jahn – Teller cation with odd number of electrons Co2+ (3d7), and non – Jahn - Teller one with even number of electrons Ni2+ (3d8), in similar ...
Added: June 4, 2024
Vorobyova A., Komleva E. V., Geidorf M. Y. et al., Journal of Alloys and Compounds 2023 Vol. 968 P. 172072–0
Tetragonal crystal structure of molybdenum oxytribromide, MoOBr3, consists of non-planar Mo2Br6 units joined by non-equidistant Mo-O-Mo bonds into infinite ladders, which are connected to each other by the van der Waals forces. Within unit cell, the apical Mo atoms in any given ladder are shifted along the c axis either above (+z) or below (−z) ...
Added: June 4, 2024
Хайретдинова Д. Р., Долуденко И. М., Панина Л. В. et al., Физика твердого тела 2022 Т. 64 № 9 С. 1144–1152
Изучено несколько типов нанопроволок (НП) из сплавов различного состава, полученных методом
матричного синтеза на основе трековых мембран. Подобраны электролиты для получения НП нужного
состава. Контроль электроосаждения по хроноамперограммам позволил систематически изменять геометрические параметры и морфологию. Топографии полученных массивов НП и их элементный состав были
изучены с помощью электронной микроскопии с рентгеноспектральным анализатором. Магнитные свойства
образцов были исследованы на вибрационном ...
Added: December 6, 2023