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  • Особенности хемосорбции крезола на пористом железосодержащем сорбенте, полученном из углеродного остатка переработки лигнина, Сообщение I. Пористая структура и адсорбционная способность сорбента
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News
September 18, 2026
When Pictures Hinder Understanding: Illustrations May Impede Learning of Abstract Ideas
Illustrations can help remember specific actions but do not always make abstract ideas easier to learn. Researchers from HSE University and Humboldt University compared how people learn from texts with different levels of abstractness. They found that participants remembered illustrations better and performed better on related tasks after reading a multimedia text about yoga asanas than after reading an abstract text about the Nash equilibrium. The findings could help improve the selection of illustrations for educational and informational materials. The study has been published in Learning and Instruction.
September 17, 2026
'I Wish That People Would Place Greater Trust in Science'
When Tatiana Eremicheva chose Fundamental and Computational Linguistics as her field of study, she thought it would be about learning languages. Instead, she discovered it was about helping people. In this interview for the HSE Young Scientists project, she discusses science as a way of understanding the world, billiards as a team-building activity, and why learning to read is not always as easy as it seems.
September 15, 2026
Immunity to Chaos: How Personal Resources Help Us Cope with the Challenges of a Turbulent World
International conflicts, crises and digital overload—the modern world puts our minds to the test every day. Traditional psychology often focuses on the consequences: anxiety, depression, and psychosomatic disorders. But what if we looked at the problem differently—through the lens of the resources that prevent us from breaking down? Psychological immunity is precisely this set of resources. Alena Zolotareva and her group, Psychological Immunity as a Resource for Positive Functioning, are developing an integrative model of this phenomenon, adapting diagnostic tools and preparing for large-scale empirical research. Why do psychologists need to collaborate with medical professionals, and how could their research transform preventive care in clinics and corporations?

 

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Особенности хемосорбции крезола на пористом железосодержащем сорбенте, полученном из углеродного остатка переработки лигнина, Сообщение I. Пористая структура и адсорбционная способность сорбента

Нефтехимия. 2021. Т. 61. № 1. С. 92–98.
Бондаренко Г. Н., Колбешин А. С., Либерман Е. Ю., Chistyakov A., Пасевин В. И., Цодиков М. В.

The results of studying the porous structure and characteristics of chemisorption of m-cresol on the surface of a new adsorbent obtained from carbon-containing residues of carbon dioxide catalytic reforming of lignin of wood origin are presented. The main stage of the formation of a porous structure is the treatment of the carbon iron-containing residue with carbon dioxide in a plasma-catalytic mode stimulated by microwave radiation. Iron-containing clusters were formed on the surface of the original lignin and used as a catalyst at the first stage of its processing. The sorbent has a developed porous structure. The total pore volume is 0.65 cm3/g, while the micropore volume is 0.18 cm3/g, and the mesopore volume is 0.42 cm3/g. The adsorbent is characterized by a monomodal distribution of adsorption pores over effective sizes with a diameter of 3.8 nm. The in situ dynamics of m-cresol adsorption was studied using IR spectroscopy. It has been shown that during the adsorption process, a chemical transformation of cresol occurs with the formation of Ph-O-C bonds between the phenyl ring of cresol and the terminal (carbon or oxygen) atoms of the adsorbent.

Research target: Chemistry
Language: Russian
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Keywords: гидролизный лигнинlignin ADSORBENTMICROWAVE IRRADIATION PLASMA CATALYTIC MODEадсорбентмикроволновое облучениеплазменно-каталитический режим
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Added: September 15, 2026
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Added: September 14, 2026
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Doubly reduced phthalocyanine complexes remain largely unexplored despite their potential relevance for molecular spin-based applications. Herein, we report the synthesis of a series of crystalline complexes, {cryptand(Cs + )} 2 [M(Pc) 4– ] 2–. ...
Added: September 14, 2026
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series of anionic bi- and trinuclear complexes of Co II , Fe II , and Mn II with hexaazatrinaphthylene (HATNA) and hexaazatriphenylenehexacarbonitrile (HAT(CN) 6 ), incorporating paramagnetic Cp* 2 Fe + cations ( S = 1/2), were obtained and investigated. ...
Added: September 14, 2026
1D and 2D coordination polymers based on ring-reduced freebase and copper-containing meso-tetra(4-pyridyl)porphyrins and M(III) (TMHD) 3 units (M = Dy, Tb and Gd; TMHD: 2,2,6,6-tetramethyl-3,5-heptanedionate)
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Added: September 14, 2026
Singlet–Triplet Transitions in the Dianionic Complex of Fullerene C 60 with Iron Carbonyl: (TBA + ) 2 {[Fe 2 (CO) 6 ]-η 2 ,η 2 -C 60 } 2–
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Added: September 14, 2026
Crystalline Trinuclear Exo- and Endocyclic Complexes of a Tetrapyrazinoporphyrazine Ligand with 3 d - and 4 f -Metals
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A redox-active tetrapyrazinoporphyrazine ligand was used as a platform for the design of multimetallic coordination complexes. The first paramagnetic homo- and heterotrimetallic complexes have been obtained as crystals through the reaction of iron­(II) octaethyltetrapyrazinoporphyrazine, FeII(Et8TPyzPz), with 3d- (FeII, CoII) and 4f-metal (DyIII) iodides. In these conditions, tetrapyrazinoporphyrazine can coordinate to metals to form exo- and ...
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Added: September 14, 2026
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Added: September 14, 2026
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Added: September 14, 2026
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Added: September 14, 2026
Effect of nuclearity and reduction state of the central ligand on magnetic properties of hexaazatrinaphthylene-based cobalt(ii) and iron(ii) complexes: from extremely weak to record-breaking antiferromagnetic exchange interaction
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Added: September 14, 2026
Single-Ion Magnetism of the [DyIII(hfac)4]− Anions in the Crystalline Semiconductor {TSeT1.5}●+[DyIII(hfac)4]− Containing Weakly Dimerized Stacks of Tetraselenatetracene
Flakina A. M., Nazarov D., Faraonov M. et al., International Journal of Molecular Sciences 2024 Vol. 25 No. 15 Article 8068
The oxidation of tetraselenatetracene (TSeT) by tetracyanoquinodimethane in the presence of dysprosium(III) tris(hexafluoroacetylacetonate), DyIII(hfac)3, produces black crystals of {TSeT1.5}●+[DyIII(hfac)4]− (1) salt, which combines conducting and magnetic sublattices. It contains one-dimensional stacks composed of partially oxidized TSeT molecules (formal averaged charge is +2/3). Dimers and monomers can be outlined within these stacks with charge and spin ...
Added: September 14, 2026
Mixing of real and quantum gases
Борщевский А. Я., Physical Chemistry Chemical Physics 2025 Vol. 27 No. 9 P. 4793–4803
Through the consistent application of quantum statistical thermodynamics, functions of isothermal mixing of real rarefied gases and quantum gases in states of varying degrees of degeneracy are obtained. The reasons for the emergence and resolution of the “Gibbs paradox” and other “paradoxes” are analyzed. Numerical calculations of entropy and pressure jumps were performed using the ...
Added: September 14, 2026
Coordination vs. oxidative rearrangement of photochromic spiropyrans upon reacting with FeIIICl3 and FeIIIBr3
Osipov N., Faraonov M., Kuzmin A. V. et al., New Journal of Chemistry 2024 Vol. 48 No. 30 P. 13526–13537
Photochromic 1,3,3-trimethylindolino-β-naphthopyrylospiran (TMI–NPS) and 1,3,3-trimethylindolinonaphthospirooxazine (TMI–NSO) spiropyrans transform into the open merocyanine (MC) form, which exhibits a red-violet color upon reacting with one equivalent of anhydrous FeIIICl3 or FeIIIBr3 in o-dichlorobenzene. Slow mixing with n-hexane precipitates black crystals of the coordination complexes: (TMI–NPS)·FeIIICl3 (1), (TMI–NPS)·FeIIIBr3·2C6H4Cl2 (2) and (TMI–NSO)·FeX3·0.5C6H4Cl2 (where X = Cl for 3 and ...
Added: September 14, 2026
Expanded Porphyrin exhibiting offcentered out-of-plane coordination to Dysprosium
Nazarov D., Labella J., Kuzmin A. V. et al., CCS CHEMISTRY 2024 Vol. 6 No. 7 P. 1731–1738
The complexation of high-spin lanthanides to porphyrinoids is a powerful strategy for the development of advanced molecular magnets. In this context, the use of expanded porphyrinoids remains elusive since their coordination chemistry is challenging to control. Herein, taking inspiration from on-surface chemistry, we explored the coordination of Dy3+ to a six-membered porphyrinoid, namely, the hemihexaphyrazine ...
Added: September 14, 2026
Fuel Oil Conversion in the Plasma Catalytic Mode, Stimulated by Microwave Radiation in the Presence of Nanosized Iron-Containing Systems
Tsodikov M. V., Konstantinov G. I., A. V. Chistyakov et al., Нефтехимия 2022 Т. 62 С. 761–767
Conversion of mixtures of fuel oil with iron-containing substrates (carbon adsorbent and lignin, both modified with 0.5 wt % Fe) to hydrocarbon products and hydrogen was studied. The use of microwave radiation in the presence of the above-indicated iron-containing substrates capable of its absorption with the generation of breakdown phenomena and plasma is a promising approach to rapid ...
Added: November 14, 2023
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