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Ultra-bright and narrow-band emission from Ag atomic sized nanoclusters in a self-assembled plasmonic resonator

Nanoscale. 2022. Vol. 14. No. 27. P. 9910–9917.
Anton S. Gritchenko, Alexey S. Kalmykov, Kulnitskiy B., Yuri G. Vainer, Wang S., Melentiev P. N., Balykin V. I.

We have proposed, implemented and investigated a novel, efficient quantum emitter based on an atomic-sized Ag nanocluster in a plasmonic resonator. The quantum emitter enables the realization of: (1) ultra-bright fluorescence, (2) narrow-band emission down to 4 nm, (3) ultra-short fluorescence lifetime. The fluorescence cross-section of a quantum emitter is on the order of σ ∼ 10−14 cm2, which is comparable to the largest fluorescence cross-sections of dye molecules and quantum dots, and enables a light source with a record high intensity known only for plasmon nanolasers. The results presented suggest a unique method for fabricating nanoprobes with high brightness and wavelength-tunable spectrally narrow fluorescence, which is needed for multiplex diagnostics and detection of substances at extremely low concentrations.

Research target: Physics Nanotechnologies
Language: English
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Keywords: nanoclustersnanoplasmonicsFluorescence spectroscopy
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