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The Photovoltaic Effect and Charge Carrier Mobility in Layered Compositions of Bithiophene or Related Rotaxane Copolymer with C70 Fullerene Derivative
Technical Physics Letters. 2017. Vol. 43. No. 2. P. 173–176.
Organic photovoltaic cells with a bulk heterojunction have been manufactured in which the photoactive layer consists of a mixture of bithiophene copolymer or related rotaxane with a fullerene derivative (PC70BM). The mobility of charge carriers in photoactive layers has been determined, the current–voltage characteristics of photovoltaic cells have been measured, and the energy level diagram of cell components has been constructed. It is established that the polyrotaxane component (macrocycle) insulates a part of thiophene fragments of the macromolecule, thus hindering the transport of carriers and leading to large energy losses for exciton dissociation, which results in a decreasing photovoltaic effect.
Teregulov T., Loubenets E. R., / Series Quantum Physics "arXiv". 2026. No. 2609.31472.
We develop a new three-party quantum secret-sharing (QSS) protocol based on a three-qubit W state. This protocol encodes the secret-sequence bits using X gates and employs randomly selected Hadamard operations and measurement bases to generate information and security-test rounds. We evaluate the efficiency of the proposed protocol and analyze its security against an internal adversary ...
Added: September 28, 2026
Vergeles S. S., Vointsev I., Physics of Fluids 2026 Vol. 38 P. 024117-1–024117-8
We analytically consider the problem of the Langmuir instability. The instability describes emergence of transverse modulation of horizontal current with vertical shear, when it is superimposed on surface wave co-directional with the flow. Compared to the Craik–Leibovich scheme, we account for the scattering of surface wave on the modulated current, which is significant if the ...
Added: September 26, 2026
Frolov N. Y., Klokov A. Y., Sharkov A. I. et al., Applied Physics Letters 2026 Vol. 128 P. 092201-1–092201-5
Understanding the properties of two-dimensional material interfaces with the substrate is necessary for device applications. Surface acoustic wave propagation through a layered material flake on a substrate could provide unique information on the transverse rigidity of the flake-to-substrate interaction. Ultrasonic waves were generated by a focused femtosecond laser pulse at the surface of a model ...
Added: September 26, 2026
Войтович В. И., Makhov I., Мельниченко И. А. et al., Optics Letters 2026 Vol. 51 No. 17 P. 4872–4875
The influence of cavity surface passivation with SiO2 coating deposited by the plasma-enhanced chemical vapor deposition technique is investigated for injection microdisk lasers with an InGaAsN/GaAs quantum well active region. The electroluminescence spectra of the microdisk lasers with cavity diameters ranging from 12 to 32 μm with and without sidewall surface passivation were studied for a ...
Added: September 25, 2026
Бабичев А. В., Makhov I., Kryzhanovskaya N. et al., Оптика и спектроскопия 2026 Т. 134 № 3 С. 272–277
Представлены результаты по реализации генерации при повышенных температурах в лазерах с длиной волны генерации 980 nm на основе вертикального микрорезонатора с использованием непоглощающих на длине волны оптической накачки зеркал. Минимальная пороговая мощность накачки составила ~0.8 mW и соответствовала температуре 150 K. Добротность микрорезонатора, определенная на пороге генерации, превысила 13000. Максимальная рабочая температура микролазера составила 195 ...
Added: September 25, 2026
Бабичев А. В., Makhov I., Kryzhanovskaya N. et al., Письма в Журнал технической физики 2026 Т. 52 № 12 С. 40–43
Реализована одночастотная генерация при 300 K в лазерах на основе вертикального микрорезонатора. Для лазеров с полупроводниковым выводным зеркалом пороговая плотность мощности накачки составила 6.5 kW/cm2. Добротность микрорезонатора и длина волны излучения, определенные на пороге генерации, равнялись 8800 и ~ 959.8 nm. Применение конструкции микрорезонатора с гибридным выводным зеркалом позволило повысить добротность микрорезонатора (до 12 360) ...
Added: September 25, 2026
Бабичев А. В., Makhov I., Kryzhanovskaya N. et al., Письма в Журнал технической физики 2026 Т. 52 № 18 С. 30–34
Представлены результаты реализации генерации при комнатной температуре в планарных вертикальных микрорезонаторах на основе зеркал Al0.2Ga0.8As/Al0.9Ga0.1As. При 300 K пороговая плотность мощности и добротность на пороге генерации составили 11.4± 0.7 kW/cm2 и 5070± 160 соответственно. Двукратное превышение порога генерации привело к увеличению добротности микрорезонатора до 19 000. Эффективный латеральный теплоотвод подтвержден малым сдвигом энергии кванта, который составил ...
Added: September 25, 2026
Budkov Y., Kiselev M. G., Journal of Chemical Physics 2026 Vol. 165 No. 12 Article 124508
We develop a three-mode statistical-mechanical theory for a two-conformer
solute in a near-critical solvent. A compressible lattice model with
vacancies yields the Gaussian free-energy functional for a critical conserved
density, an orthogonal noncritical conserved mode, and the local conformer
fraction. Their couplings follow from packing and cohesive interactions,
rather than being introduced phenomenologically. Kawasaki transport of the
two conserved fields and ...
Added: September 24, 2026
Kryzhanovskaya N., Makhov I., Dragunova A., St. Petersburg Polytechnical University Journal: Physics and Mathematics 2026 Vol. 19 No. 1.1 P. 98–104
The planar microcavity structure was grown using molecular-beam epitaxy.
Single-mode lasing was observed at a wavelength of 960 nm for pillars with a diameter of
15 μm. At 300 K, the lasing threshold was approximately 30 mW. Increasing the pump
power to 2.7 times the threshold power resulted in a mode energy shift of approximately
1 meV. This shift ...
Added: September 23, 2026
Andreeva S., Gavrilov A. A., Dzhikirba K. R. et al., Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 114 Article 134515
We examine plasma excitations with linear dispersion in a system of superconducting electrons in thin
NbN disks. Using frequency-domain terahertz spectroscopy, we study the evolution of plasmons up to critical
temperature Tc. The observed excitations tend to shift to the lower frequencies while temperature is increasing
and the spectral features vanish at T > Tc. We study the ...
Added: September 23, 2026
Образцова А. А., Ivanov K., Moiseev E. et al., Journal of Physics D: Applied Physics 2026 Vol. 59 No. 30 P. 305103
We demonstrate a thermo-optically tunable microlaser based on an InGaAs/GaAs quantum-dot (QD) active region employing a deformed limaçon-shaped cavity. The asymmetric geometry effectively lifts the degeneracy of high-Q whispering-gallery modes, enabling single-mode lasing. A side-mode suppression ratio exceeds 25 dB over a wide current range. Under continuous-wave electrical pumping, the device achieves a peak output power ...
Added: September 23, 2026
Budkov Y., Journal of Chemical Physics 2026 Vol. 165 No. 12 Article 124105
Exact theories of electrolyte structure must satisfy the nonlocal constraints imposed by electrostatic screening, yet these constraints are most commonly formulated only for homogeneous bulk systems and at the level of two-point correlations. Here, we develop a unified field-theoretic framework that extends them to general inhomogeneous ionic fluids and nonlinear charge correlations. Using a standard ...
Added: September 22, 2026
Боровицкая И. В., Пименов В. Н., Коршунов С. Н. et al., Перспективные материалы 2026 № 10 С. 37–54
Проведено сравнение, обобщение и систематизация механизмов эрозии и разрушения
поверхности малоактивируемых материалов, перспективных для использования в
качестве материалов вакуумной камеры термоядерных реакторов: ванадия, его сплава
V – 10 Ti – 6 Cr – 0,05 Zr – 0,1 Si и вольфрама при последовательном воздействии на
них ионных и тепловых потоков. Тепловые потоки имитировали с помощью мощного
импульсного лазерного излучения (ЛИ), создаваемого ...
Added: September 22, 2026
Iontsev M.A., Mukhin S. I., Fistul M. V., Physical Review B: Condensed Matter and Materials Physics 2016 Vol. 94 No. 17 P. 174–510
We report a theoretical study of the ac response of superconducting quantum metamaterials (SQMs), i.e., an array of qubits (two-level systems) embedded in a low-dissipative resonator. By making use of a particular example of a SQM, namely the array of charge qubits capacitively coupled to the resonator, we obtain a second-order phase transition between an ...
Added: September 22, 2026
sobov P., Yakushev I., Shestakov A. et al., Organometallics 2025 Vol. 44 No. 24 P. 2873–2881
Interaction of {Cryptand(K+)}(C60•–) with CpCo(CO)2 yields the air-sensitive crystalline salt {Cryptand(K+)}{CpCo(CO)-η2-C60•–} (1), in which C60•– replaces carbonyl group in CpCo(CO)2. Two Co–C bonds of 2.028(9) and 2.057(8)Å are formed. The magnetic moment of 1 is 1.72 μB, indicating a doublet S = 1/2 spin state of {CpCo(CO)-η2-C60•–} at 300 K. The compound shows a broad ...
Added: September 20, 2026
Cherkashina N. I., Pavlenko V. I., Bondarenko G.G. et al., Inorganic Materials: Applied Research 2026 Vol. 17 No. 5 P. 1247–1257
The description is given to the synthesis of a flexible polymer composite for radiation protection
based on a rubber matrix and rare-earth metal oxides (Dy2O3 and Gd2O3). The physico-mechanical parameters
are established for the compositions with dysprosium oxide as follows: the density ranging from 1.31 to
2.44 g/cm3, tensile strength is staying between 6.06 and 1.72 MPa. In ...
Added: September 15, 2026
Sobov P. A., Yakushev I. A., Shestakov A. et al., Inorganic Chemistry 2026 Vol. 65 No. 16 P. 9107–9115
Interaction of fullerene C60 with Cs2Fe(CO)4 in the presence of two equivalents of tetrabutylammonium iodide (TBAI) yields the first dianionic coordination complex of fullerene: (TBA+)2{[Fe2(CO)6]-η2,η2-C60}2– (1). According to magnetic data and DFT calculations, complex 1 has a diamagnetic ground (S = 0) and a triplet excited state (S = 1) populated above 80 K. As ...
Added: September 14, 2026
Sobov P. A., Khasanov S., Kuzmin A. V. et al., Inorganic Chemistry Communications 2026 Vol. 185 Article 116055
New complex {(dppf)CpFe(CO)}(C60)⋅C6H4Cl2 (1) was obtained when stoichiometric mixture of C60 and CoII(dppf)Cl2 is reduced by two equivalents of (Cs+){CpFe(CO)2−} (dppf: 1,1`-bis(diphenylphosphino)ferrocene). CpFe(CO)2− anion reduces CoII(dppf)Cl2 and CpFe(CO)2 abstracts the dppf ligand from Co(dppf) forming (dppf)CpFeI(CO). Electron transfer from (dppf)CpFeI(CO) to C60 is observed. As a result, the state of {(dppf)CpFe(CO)}δ+(C60)δ−⋅C6H4Cl2 (δ = 0.54–0.86) is intermediate between ...
Added: September 14, 2026
Sobov P. A., Kuzmin A. V., Shevchun A. F. et al., Synthetic Metals 2025 Vol. 313 Article 117904
Modification of the neutral triptycene TPC-X molecule by increasing the size of the X substituent at the 9th position from X = H to Br and I affects the magnetic and conducting properties of the (MDABCO+)(C60•−)(TPC-X) salts (1–3, respectively), where MDABCO+ is N-methyldiazabicyclooctanium. These salts feature hexagonal fullerene layers composed of C60•−, which remain undimerized owing to ...
Added: September 14, 2026
Sobov P. A., Faraonov M., Khasanov S. et al., New Journal of Chemistry 2024 Vol. 48 No. 22 P. 10002–10009
Radical anion salts of fullerenes have been obtained through the reaction of Cs·C60 and Cs·C70 with cationic dye (astrophloxine+)(I−) yielding crystalline salts (astrophloxine+)2(C60˙−)2·C6H4Cl2·C6H14 (1) and (astrophloxine+)2(C70−)2 (2). Salt 1 contains C60˙− radical anions arranged in 3D packing among which pairs of types I and II can be outlined. Strong antiferromagnetic coupling of spins is observed ...
Added: September 14, 2026
Гущина В. А., / Series chemrxiv-2023-vpzhz-v2 "ChemRxiv". 2023.
All-inorganic perovskite CsPbBr3 and Cs4PbBr6 nanoparticles are being intensively studied due to their unique properties and wide range of applications; however, however, the nature of their optical properties is not yet fully understood due to the difficulty of synthesis of singlephase nanoparticles. In this article we describe the features of the synthesis of single-phase particles ...
Added: May 14, 2026
Pilé I., Deng Y., Shchur L., / Series arXiv "math". 2026. No. 2604.10254.
We investigate the spatial overlap of successive spin configurations in Markov chain Monte Carlo simulations using the local Metropolis algorithm and the Svendsen-Wang and Wolff cluster algorithms. We examine the dynamics of these algorithms for two models in different universality classes: the Ising model and the Potts model with three components. The overlap of two ...
Added: April 20, 2026
Черкашина Н. И., Павленко В. И., Bondarenko G. et al., Перспективные материалы 2026 № 4 С. 14–26
В данной работе представлен синтез гибкого полимерного композита для защиты от радиации на основе каучуковой матрицы и оксидов редкоземельных металлов, таких как Dy2O3 и Gd2O3, предназначенного для создания радиационно-защитных экранов и средств индивидуальной защиты. Исследованы его физико-механические характеристики: составы с добавлением оксида диспрозия имеют плотность от 1,31 до 2,44 г/см3, предел прочности при растяжении от ...
Added: April 2, 2026
Margarita Chetyrkina, Umriukhin P., Ershova E. et al., Biomaterials Translational 2025 Vol. 6 No. 3 P. 359–370
Fullerenes are one of the most popular nanomaterials, and C70 fullerene is the second most common fullerene after C60 buckminsterfullerene. Minor modification of fullerenes derivatives can change their biological effects and antioxidant properties. A plethora of water-soluble derivatives can be synthesised based on buckminsterfullerenes. In the present study, we synthesised three water-soluble C70 fullerene derivatives ...
Added: February 12, 2026