Laser-induced demagnetization in van der Waals 𝑋⁢𝑌- and Ising-like antiferromagnets NiPS3 and FePS3

PHYSICAL REVIEW MATERIALS. 2024. Vol. 8. No. 1. Article 014408.

Kuntu D. V., Arkhipova E. A., Shelukhin L. A., Mertens F., M. A. Prosnikov, Eliseyev I. A., Smirnov A. N., Davydov V. Y., Mañas-Valero S., Coronado E., Cinchetti M., Kalashnikova A. M.

The critical behavior of laser-induced changes in magnetic ordering is studied experimentally in two-dimensional zigzag antiferromagnets XY-like NiPS3 and Ising-like FePS3. To examine laser-induced dynamics in flakes of these compounds, we employ time-resolved exchange linear dichroism effect sensitive to zigzag magnetic ordering and independent of the orientation of the antiferromagnetic vector. In both compounds laser excitation in the vicinity of the absorption edge induces partial quenching of the antiferromagnetic ordering manifested by exchange linear dichroism reduction. The amplitude of the effect varies with temperature as the derivative of the antiferromagnetic vector and exhibits a critical behavior with the exponents corresponding to XY and Ising models for NiPS3 and FePS3, respectively. Critical slowing down of the demagnetization in the vicinity of Néel temperature is found, however, only in FePS3. In contrast, the increase of the demagnetization time near the ordering temperature in NiPS3 is minor. We show that the difference in the demagnetization times correlates well with the spin specific heat in both compounds. Beyond the range of slowing down, the demagnetization times in NiPS3 and FePS3 are comparable, about 5–10 ps, and are longer than those reported earlier for CoPS3 and considerably shorter than for MnPS3. This points to the importance of the unquenched angular momentum of transition-metal ions in laser-induced demagnetization process.

Keywords: critical phenomena