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Osmolyte-modulated differential capacitance and disjoining pressure for nanoconfined electrolytes: A modified Poisson–Boltzmann theory
Journal of Chemical Physics. 2025. Vol. 163. No. 3. Article 034709.
This study employs modified Poisson–Boltzmann theory to systematically investigate the influence of zwitterionic osmolyte additives to an electrolyte solution on disjoining pressure and electric differential capacitance within charged, slit-like nanopores with conductive walls. We demonstrate that increasing concentrations of zwitterionic osmolytes synergistically enhance both disjoining pressure and differential capacitance, highlighting their dual role in the potential improvement of supercapacitor performance. The insights gained underscore the unique capabilities of zwitterionic osmolytes as multifunctional additives for fine-tuning the properties of electric double layers, thereby bridging the gap between capacitive efficiency and microporous electrode longevity.
Ratnikov F., Bocharnikov V., Journal of High Energy Physics 2026 Vol. 2026 P. 1–21
The BM@N experiment (Baryonic Matter at the Nuclotron) is the first fixed-target experiment at the JINR NICA accelerator complex. In this work, data on the interactions of a carbon-ion beam with kinetic energies of 4.0A GeV and 4.5A GeV with C, Al, Cu, and Pb targets are used to measure transverse momentum spectra and rapidity ...
Added: August 12, 2026
Budkov Y., Kalikin N., Journal of Chemical Physics 2026 Vol. 165 Article 064506
A self-consistent statistical-mechanical theory of the Hall effect in electrolyte solutions is developed by extending the self-consistent Debye–Hückel–Onsager (SCDHO) framework to crossed electric and magnetic fields. The theory incorporates non-local ionic charge distributions via Slater-type form factors, regularizing the Coulomb interaction at short range, and accounts for dielectric friction through ion-specific coefficients, employing experimental values ...
Added: August 12, 2026
Ali S., Bocharnikov V., Ratnikov F. et al., Sensors 2026 Vol. 26 No. 16 Article 5024
Large distributed sensor arrays require repeated recalibration as radiation damage, material aging, gain variation, and readout drift alter channel responses. We studied a high-granularity calorimeter as a large sensor array and addressed unsupervised recalibration from two unpaired datasets: a nominal reference response and an aged response with attenuated cell-wise signals. Aging was modeled by a ...
Added: August 11, 2026
Ponomarev A., Aleksandrov N., Journal of Physics D: Applied Physics 2026 Vol. 59 Article 315205
Electron attachment and detachment in H2O:O2 and H2O:air mixtures are theoretically studied at moderate (40–100 Td) reduced electric fields. It is shown that there are two synergistic mechanisms of ultra-rapid electron detachment from negative ions in these mixtures, whereas these detachment channels are absent in pure gases. Effective attachment coefficient calculated with consideration for fast ion–molecule ...
Added: August 6, 2026
Khrapai V., Tikhonov E., Nature Physics 2026 P. 1–2
Feng et al.1 presented transport measurements of three-terminal normal–superconductor–normal devices based on topological insulator nanowires. They measured the full differential conductance matrix, defined as Gij = ∂Ii /∂Vj , beyond the linear response regime as a function of various control parameters. Here i, j∈ [1, 2] denote normal terminals biased by the voltages V1 and ...
Added: August 5, 2026
G. G. Bondarenko, Kristya V. I., Savichkin D. O. et al., Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques 2026 Vol. 20 No. 2 P. 417–423
A model of a glow gas discharge in a mixture of argon and mercury vapor is formulated in the presence
of a thin insulating film on the cathode surface. Dependences of the discharge characteristics on the
mixture temperature are calculated in the range of its variation, in which a noticeable contribution to ionization
of the working gas is ...
Added: August 1, 2026
Касимов Р. Х., Аржанов А. И., Седых К. О. et al., Оптический журнал 2026 Т. 93 № 1 С. 80–86
Предмет исследования. Использование метода капельного нанесения для изготовления источника одиночных фотонов. Цель работы. Разработка технологического процесса изготовления источника одиночных фотонов на коллоидных квантовых точках для использования их в фотон- ных интегральных схемах. Метод. На первом этапе в программе ANSYS Lumerical рассчитыва- ются период и фактор заполнения фокусирующих элементов связи на длинах волн 545 и 600 ...
Added: July 31, 2026
Nevzorov A., Golikov A., Gneushev D. et al., JETP Letters 2026 Vol. 147–151 No. 3 P. 147–151
This paper demonstrates a special stochastic operation mode of a photonic element with a thin GeTe film deposited at a silicon nitride waveguide. As opposed to traditional deterministic switching between stable states, it has been shown that identical pump laser pulses cause a stochastic change in the transmission coefficient. The discovered effect opens up new ...
Added: July 31, 2026
Dual-mode infrared detection via photovoltaic and barrier pyroelectric effects in PbTe p–n junctions
Jarashneli A., Кобцев Д. М., Upcher A. et al., Journal of Applied Physics 2026 Vol. 140 No. 2 Article 024501
In the work, two effects appeared in PbTe p–n junctions under mid-wavelength infrared (2 − 5 μm) and long-wavelength infrared irradiation (≈10.6 μm). The first effect was created by the optical absorption of lR-photons in PbTe and caused by its photovoltage effect. The second novel effect is related to the heating process and the formation ...
Added: July 31, 2026
Nikolaev G. A., Orlov O. V., Andreeva S. et al., Physical Review Applied 2026 Vol. 26 Article 014099
We report the electrical detection of the spin resonance with temporal resolution in a two-dimensional electron system. Spin resonance was excited by pulses of subterahertz radiation characterized by relatively short rise and fall times on the order of 10 ns and was observed as a resonant peak in the high-frequency conductivity of the two-dimensional channel. The ...
Added: July 31, 2026
S. A. Andreeva, Orlov O. V., A. V. Shchepetilnikov et al., Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 114 No. 6 Article 065420
We investigate the temperature dependence of the pseudospin phase transition at filling factor 𝜈=2 in the quantum Hall regime. Experiments were performed on a high-quality, wide AlAs quantum well, where the pseudospin degree of freedom arises naturally from the near degeneracy and equivalence of the two conduction-band valleys. The anisotropic 𝑔-factor inherent to AlAs enabled independent measurement of ...
Added: July 31, 2026
Voropaeva D., S. Novikova, I. Stenina et al., Solid State Ionics 2026 Vol. 445 Article 117288
Composite gel polymer electrolytes based on a perfluorinated sulfonic acid cation-exchange MF-4SC membrane
containing surface-sulfonated nanoparticles of aluminum oxide, cerium (IV) oxide, and titanium oxide (sAl2O3,
sCeO2, and sTiO2, respectively) were prepared by casting from a dispersion in N,N-dimethylformamide and
plasticized with a 1,3-dioxolane/1,2-dimethoxyethane mixture. The influence of the filler nature on ionic conductivity,
solvent uptake, activation energy, lithium ...
Added: July 30, 2026
Metlov K., Andrei B. Bogatyrëv, Annalen der Physik 2026 Vol. 538 No. 6 Article e70234
Thanks to the recent progress in bulk full three-dimensional nanoscale magnetization distribution imaging, there is a growing
interest to three-dimensional (3D) magnetization textures, promising new high information density spintronic applications.
Compared to 1D domain walls or 2D magnetic vortices/skyrmions, they are a much harder challenge to represent, analyze and
reason about. Here we build analytical representation for such ...
Added: July 28, 2026
Dmitry Vasilyev, Gorev V., Ikhsanov R. et al., Journal of Materials Science 2026 No. 61 P. 25452–25470
The orthorhombic phase of 𝛼-Mo2 C is a key component in electrocatalytic applications, as Mo2C-based catalysts can exhibit catalytic performance comparable to or exceeding that of noble metals. Despite its technological relevance, theoretical understanding of the anisotropy in the thermal expansion and related thermoelastic properties of 𝛼-Mo2 C remains limited. In this work, first-principles calculations ...
Added: July 23, 2026
Borovitskaya I. V., Pimenov V. N., Korshunov S. N. et al., Physics of Atomic Nuclei 2026 Vol. 89 No. 1 P. S48–S55
The effect of high-power pulsed laser radiation (LR) generated in the GOS 1001 setup in the
Q-modulated mode (with a flux power density q equal to 1 × 1014 W/m2, pulse duration t = 50 ns, and the
number of pulses N from 1 to 8 in vacuum) on the structure and microhardness of the surface of ...
Added: July 22, 2026
Korogod D., Shapeev A., Ivan S. Novikov, Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 114 No. 2 Article 024104
We present two models with explicit long-range electrostatics in the form of Coulomb interactions. Both models include point charges depending on their local atomic environments, and the second model also conserves a total charge of an atomic system. We combine the proposed long-range models with the local moment tensor potential (MTP) and demonstrate that they ...
Added: July 22, 2026
Sozykin K., Rybin N., Chertkov A. et al., Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 113 No. 22 Article 224111
The global optimization of atomic clusters represents a fundamental challenge in computational chemistry and materials science due to the exponential growth of local minima with system size (i.e., the curse of dimensionality). We introduce a framework that overcomes this limitation by exploiting the low-rank structure of potential energy surfaces through tensor train (TT) decomposition. Our ...
Added: July 22, 2026
Loubenets E. R., / Series arxiv.org "quant-ph". 2026. No. 2607.18050.
In many quantum applications it is important to know whether or not a Bell nonlocal two-qudit state exhibits its nonlocality under correlation scenarios with some given numbers S1,S2≥1 of generalized quantum measurements at two sites. In the present article, we find analytically a new general locality condition sufficient for a nonseparable Werner state with a ...
Added: July 21, 2026
Doronin S., Yury A. Budkov, Current Opinion in Electrochemistry 2026 Vol. 57 Article 101853
The electric double layer (EDL) governs charge distribution at electrode–electrolyte interfaces, controlling reaction kinetics and energy storage performance. This mini review surveys the evolution of EDL theory—from the classical Gouy-Chapman-Stern framework to modern coupled quantum-continuum schemes that integrate electronic structure with statistical mechanics. We show how modified Poisson–Boltzmann (mPB) formu-lations incorporating finite ion size, dielectric ...
Added: April 19, 2026
Yury A. Budkov, Nikolai N. Kalikin, Physical Chemistry Chemical Physics 2026 Vol. 28 No. 11 P. 6756–6768
This study presents a novel approach to addressing the limitations in understanding the behavior of charged particles in solutions. The approach is based on the development of the Self-Consistent Debye–Hückel–Onsager (SCDHO) theory, which integrates the effects of non-local charge distributions using a Slater-type charge form factor model. This results in a modified Coulomb potential at ...
Added: February 27, 2026
Daria A. Mazur, Petr E. Brandyshev, Doronin S. et al., Electrochimica Acta 2026 Vol. 545 Article 147660
Recent advances in theoretical modelling of the electric double layer (EDL) have significantly improved the
accuracy of key parameters such as differential capacitance and ion profiles, paving the way for molecularlevel
descriptions of electrochemical interfaces. Despite these developments, existing models often lack a
unified physical framework, limiting their ability to capture complex interfacial phenomena such as ion
adsorption and ...
Added: November 11, 2025
Nesterova I., Kondratyuk N., Budkov Y. et al., Advances in Colloid and Interface Science 2025 Vol. 346 Article 103623
Room temperature ionic liquids show great promise as electrolytes in various technological applications, such as energy storage or electrotunable lubrication. These applications are particularly intriguing due to the specific behavior of ionic liquids in nanoconfinement. While previous research has been focused on optimizing the required characteristics through the selection of electrolyte properties, the contribution of ...
Added: September 2, 2025
Yury A. Budkov, Petr E. Brandyshev, Physical Review E - Statistical, Nonlinear, and Soft Matter Physics 2025 Vol. 111 No. 4 Article 044130
In this paper, we use the formalism of finite-temperature quantum field theory to investigate the Casimir force between flat, ideally conductive surfaces containing confined, but mobile ions. We demonstrate that, in the Gaussian approximation, the ionic fluctuations contribute separately from the electromagnetic fluctuations that are responsible for the standard Casimir effect. This is in line ...
Added: April 21, 2025
Yury A. Budkov, Nikolai N. Kalikin, Petr E. Brandyshev, Journal of Statistical Mechanics: Theory and Experiment 2024 Vol. 2024 No. 12 Article 123201
This extended article presents a thermomechanical approach for calculating the stress tensor from the thermodynamic potential of inhomogeneous fluids and some applications to ionic fluids. The technique, based on the invariance of the fluid's thermodynamic potential with respect to spatial transformations of translation and rotation, offers an alternative to the general covariant approach developed by ...
Added: December 15, 2024