### Book

## Nanoscale Materials and Devices for Electronics, Photonics and Solar Energy

This book presents research dedicated to solving scientific and technological problems in many areas of electronics, photonics and renewable energy. Progress in information and renewable energy technologies requires miniaturization of devices and reduction of costs, energy and material consumption. The latest generation of electronic devices is now approaching nanometer scale dimensions; new materials are being introduced into electronics manufacturing at an unprecedented rate; and alternative technologies to mainstream CMOS are evolving. The low cost of natural energy sources have created economic barriers to the development of alternative and more efficient solar energy systems, fuel cells and batteries.

Nanotechnology is widely accepted as a source of potential solutions in securing future progress for information and energy technologies. *Nanoscale Materials and Devices for Electronics, Photonics and Solar Energy* features chapters that cover the following areas: atomic scale materials design, bio- and molecular electronics, high frequency electronics, fabrication of nanodevices, magnetic materials and spintronics, materials and processes for integrated and subwave optoelectronics, nanoCMOS, new materials for FETs and other devices, nanoelectronics system architecture, nano optics and lasers, non-silicon materials and devices, chemical and biosensors,quantum effects in devices, nano science and technology applications in the development of novel solar energy devices, and fuel cells and batteries.

The optical properties of graphene-based structures are discissed. The universal optical absorption in graphene is reviewed. The photonic band structure and transmission of graphene-based photonic crystals are considered. The spectra of plasmon and magnetoplasmon excitations in graphene layers and grapehene nanoribbons (GNR) are analyzed. The localization of the electromagnetic waves in the photonic crystals with defects, which play a role of waveguide, is studied. Properties of plasmons and magnetoplasmons in graphene layers and GNR are reviewed. The surface plasmon amplification by stimulated emission of radiation with the net amplification of surface plasmons in the doped GNR is described. The minimal population inversion per unit area needed for the net amplification of plasmons in a doped GNR is reported. The various applications of graphene for photonics and optoelectronics are reviewed. The tunability of photonic and plasmonic properties of various graphene structures by doping achieved by applying the gate voltage is discussed.

The article is devoted to development of optimal design mathematical models for power systems using renewable energy sources (RES) on the stage of pre-investment feasibility study. Economic and social practicability of the carbon-free energy sector development in Russia is confirmed by calculated data of renewable energy sources potentials such as fuel, heat and power, resource saving and environmental (in tons of CO and CO2-equivalents) potentials. In order to increase the attractiveness of investing in renewable energy sector the optimal investment designing problem is defined and MILP economic and mathematical model is developed for ecological and economic optimization of decentralized wind-solar hybrid power supply investment projects. The macro structure of the model is considered. The basic mathematical relationships that form the region of feasibility are presented. Designed models can be used to justify the investment in distributed power systems.

The optical properties of graphene-based structures are discissed. The universal optical absorption in graphene is reviewed. The photonic band structure and transmission of graphene-based photonic crystals are considered. The spectra of plasmon and magnetoplasmon excitations in graphene layers and grapehene nanoribbons (GNR) are analyzed. The localization of the electromagnetic waves in the photonic crystals with defects, which play a role of waveguide, is studied. Properties of plasmons and magnetoplasmons in graphene layers and GNR are reviewed. The surface plasmon amplification by stimulated emission of radiation with the net amplification of surface plasmons in the doped GNR is described. The minimal population inversion per unit area needed for the net amplification of plasmons in a doped GNR is reported. The various applications of graphene for photonics and optoelectronics are reviewed. The tunability of photonic and plasmonic properties of various graphene structures by doping achieved by applying the gate voltage is discussed.

The development of power supplies for ionizing radiation detectors is a complex and difficult problem, especially if this concerns with autonomous mobile measuring systems. In this article, we describe the experience of the implementation of the autonomous solar energy supply for semiconductor ionizing radiation detectors.

Technology mining (TM) helps to acquire intelligence about the evolution of research and development (R&D), technologies, products, and markets for various STI areas and what is likely to emerge in the future by identifying trends. The present chapter introduces a methodology for the identification of trends through a combination of “thematic clustering” based on the co-occurrence of terms, and “dynamic term clustering” based on the correlation of their dynamics across time. In this way, it is possible to identify and distinguish four patterns in the evolution of terms, which eventually lead to (i) weak signals of future trends, as well as (ii) emerging, (iii) maturing, and (iv) declining trends. Key trends identified are then further analyzed by looking at the semantic connections between terms identified through TM. This helps to understand the context and further features of the trend. The proposed approach is demonstrated in the field photonics as an emerging technology with a number of potential application areas.

We demonstrate evidence of coherent magnetic flux tunneling through superconducting nanowires patterned in a thin highly disordered NbN film. The phenomenon is revealed as a superposition of flux states in a fully metallic superconducting loop with the nanowire acting as an effective tunnel barrier for the magnetic flux, and reproducibly observed in different wires. The flux superposition achieved in the fully metallic NbN rings proves the universality of the phenomenon previously reported for InOx .We perform microwave spectroscopy and study the tunneling amplitude as a function of the wire width, compare the experimental results with theories, and estimate the parameters for existing theoretical models.

The possibilities of computer experiments performed with the MDSLAGMELT v. 10.0 information-research system (IRS) with remote access are described. The main classes of mathematical models and methods and the sets of properties obtained in computer experiments are considered. An information model is developed for an oxide melt to study multidimensional composition–temperature–property–structure relations. A nanostructural model based on generalized graph network descriptors is considered in detail. The results of simulating the structure-sensitive properties of the SiO2–Na2O system using IRS are presented.

**DOI: **10.1134/S0036029513080156

The dynamics of a two-component Davydov-Scott (DS) soliton with a small mismatch of the initial location or velocity of the high-frequency (HF) component was investigated within the framework of the Zakharov-type system of two coupled equations for the HF and low-frequency (LF) fields. In this system, the HF field is described by the linear Schrödinger equation with the potential generated by the LF component varying in time and space. The LF component in this system is described by the Korteweg-de Vries equation with a term of quadratic influence of the HF field on the LF field. The frequency of the DS soliton`s component oscillation was found analytically using the balance equation. The perturbed DS soliton was shown to be stable. The analytical results were confirmed by numerical simulations.

By using superconducting quantum interference device (SQUID) magnetometry, we investigated anisotropic high-field (H less than or similar to 7T) low-temperature (10 K) magnetization response of inhomogeneous nanoisland FeNi films grown by rf sputtering deposition on Sitall (TiO2) glass substrates. In the grown FeNi films, the FeNi layer nominal thickness varied from 0.6 to 2.5 nm, across the percolation transition at the d(c) similar or equal to 1.8 nm. We discovered that, beyond conventional spin-magnetism of Fe21Ni79 permalloy, the extracted out-of-plane magnetization response of the nanoisland FeNi films is not saturated in the range of investigated magnetic fields and exhibits paramagnetic-like behavior. We found that the anomalous out-of-plane magnetization response exhibits an escalating slope with increase in the nominal film thickness from 0.6 to 1.1 nm, however, it decreases with further increase in the film thickness, and then practically vanishes on approaching the FeNi film percolation threshold. At the same time, the in-plane response demonstrates saturation behavior above 1.5-2T, competing with anomalously large diamagnetic-like response, which becomes pronounced at high magnetic fields. It is possible that the supported-metal interaction leads to the creation of a thin charge-transfer (CT) layer and a Schottky barrier at the FeNi film/Sitall (TiO2) interface. Then, in the system with nanoscale circular domains, the observed anomalous paramagnetic-like magnetization response can be associated with a large orbital moment of the localized electrons. In addition, the inhomogeneous nanoisland FeNi films can possess spontaneous ordering of toroidal moments, which can be either of orbital or spin origin. The system with toroidal inhomogeneity can lead to anomalously strong diamagnetic-like response. The observed magnetization response is determined by the interplay between the paramagnetic-and diamagnetic-like contributions.

Radiation conditions are described for various space regions, radiation-induced effects in spacecraft materials and equipment components are considered and information on theoretical, computational, and experimental methods for studying radiation effects are presented. The peculiarities of radiation effects on nanostructures and some problems related to modeling and radiation testing of such structures are considered.

Let k be a field of characteristic zero, let G be a connected reductive algebraic group over k and let g be its Lie algebra. Let k(G), respectively, k(g), be the field of k- rational functions on G, respectively, g. The conjugation action of G on itself induces the adjoint action of G on g. We investigate the question whether or not the field extensions k(G)/k(G)^G and k(g)/k(g)^G are purely transcendental. We show that the answer is the same for k(G)/k(G)^G and k(g)/k(g)^G, and reduce the problem to the case where G is simple. For simple groups we show that the answer is positive if G is split of type A_n or C_n, and negative for groups of other types, except possibly G_2. A key ingredient in the proof of the negative result is a recent formula for the unramified Brauer group of a homogeneous space with connected stabilizers. As a byproduct of our investigation we give an affirmative answer to a question of Grothendieck about the existence of a rational section of the categorical quotient morphism for the conjugating action of G on itself.

This proceedings publication is a compilation of selected contributions from the “Third International Conference on the Dynamics of Information Systems” which took place at the University of Florida, Gainesville, February 16–18, 2011. The purpose of this conference was to bring together scientists and engineers from industry, government, and academia in order to exchange new discoveries and results in a broad range of topics relevant to the theory and practice of dynamics of information systems. Dynamics of Information Systems: Mathematical Foundation presents state-of-the art research and is intended for graduate students and researchers interested in some of the most recent discoveries in information theory and dynamical systems. Scientists in other disciplines may also benefit from the applications of new developments to their own area of study.

Let G be a connected semisimple algebraic group over an algebraically closed field k. In 1965 Steinberg proved that if G is simply connected, then in G there exists a closed irreducible cross-section of the set of closures of regular conjugacy classes. We prove that in arbitrary G such a cross-section exists if and only if the universal covering isogeny Ĝ → G is bijective; this answers Grothendieck's question cited in the epigraph. In particular, for char k = 0, the converse to Steinberg's theorem holds. The existence of a cross-section in G implies, at least for char k = 0, that the algebra k[G]G of class functions on G is generated by rk G elements. We describe, for arbitrary G, a minimal generating set of k[G]G and that of the representation ring of G and answer two Grothendieck's questions on constructing generating sets of k[G]G. We prove the existence of a rational (i.e., local) section of the quotient morphism for arbitrary G and the existence of a rational cross-section in G (for char k = 0, this has been proved earlier); this answers the other question cited in the epigraph. We also prove that the existence of a rational section is equivalent to the existence of a rational W-equivariant map T- - - >G/T where T is a maximal torus of G and W the Weyl group.