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Regular version of the site
Of all publications in the section: 24
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Article
Li I. P., Bondarenko G. Inorganic Materials: Applied Research. 2012. Vol. 3. No. 5. P. 381-384.

A method to improve emission homogeneity of pressed palladium–barium cathodes applied in magnetrons with self-heating initiation is proposed. The initial palladium powder is annealed at 950°C for 60 min and then calcined in vacuum under pressure of residual gases P ≤ 1 × 10–4 Pa. It is demonstrated that cathodes produced by pressing and subsequent sintering of a powdered mixture of palladium and intermetallic compound Pd5Ba in vacuum are characterized by a high distribution homogeneity of components. Within testing of magnetrons produced with such cathodes, the yield of good items is increased by a factor of 1.5.

Added: Nov 30, 2012
Article
Yastrebinskii R. N., Bondarenko G.G., Pavlenko V. I. Inorganic Materials: Applied Research. 2017. Vol. 8. No. 2. P. 275-278.

In this paper the calculations for coefficients of weakening of both photon and neutron beams when the ones pass through the iron-magnet-serpentinit cement concrete (IMSCC) have been presented. IMSCC is using for biological protection of nuclear reactors. At the energies of photons in the range from 0.2 to 11 MeV the main contribution to weakening of beam gives Compton's effect. But at the photon energies more than 11 MeV the main contribution to weakening of beam gives effect of electron-positron couples formation. At an assessment of influence of fast neutrons, it has been shown that, despite the low density of hydrogen in the studied composite, a contribution of hydrogen to coefficient of weakening of a neutron stream was very important. It is connected with both a high concentration of hydrogen and the fact that at neutron irradiation the higher kinetic energy is transferred to light atomic nuclei than heavy ones. 

Added: Mar 29, 2017
Article
Andreev D. V., Bondarenko G., Stolyarov A. A. Inorganic Materials: Applied Research. 2016. Vol. 7. No. 2. P. 187-191.
The processes of changing the charge state of metal–oxide–semiconductor (MOS) structures that contain a multilayer gate dielectric on the basis of a thermal SiO2 film doped with phosphorus under the influence of highfield electron injection are investigated. It is determined that a negative charge accumulating in a thin phosphosilicate glass (PSG) film of MOS structures containing a SiO2–PSG twolayer gate dielectric under highfield tunneling injection of electrons can be used for the correction of the threshold voltage, for the enhancement of the charge stability, and for an increase in the breakdown voltage of devices with MOS structure. It is shown that the density of electron traps increases with an increase in the thickness of the PSG film containing them, while their capture cross section remains unchanged. The method for the modification of the electrophysical characteristics of MOS structures by the highfield tunneling injection of electrons into a dielectric under a controlled current load is proposed. The method allows one to control changes in the parameters of MOS structures directly in the process of their modification. It is established that a MOS structure with a high thermal field stability can be obtained by its annealing at 200°C after the modification of its charge state by the electron injection.
Added: May 28, 2016
Article
Maslyaev S. A., Morozov E. V., Romakhin P.A. et al. Inorganic Materials: Applied Research. 2016. Vol. 7. No. 3. P. 330-339.

Alumina ceramics with corundum structure (α-Аl2О3) manufactured by powder technology method was irradiated by pulsed ion beams and high-temperature plasma in Plasma Focus device and by free running mode laser radiation. Irradiation in the PF-5M device was carried out with nitrogen and air working gases with power flux density for the plasma flow q ≈ 107 W/cm2 and pulse duration τp ≈ 100 ns, and for ion flow q ≈ 108 W/cm2, τi ≈ 20 ns. Exposure with pulsed laser radiation was carried out in air with q (3 – 5)105 W/cm2 and τ ≈ 0.7 ms. The features of erosion (weight loss) and the damage of the surface layer of ceramics for these modes of exposure were investigated. It has been shown that the joint use of Plasma Focus and pulsed laser exposure is promising for simulation of extreme processes of damage and erosion of materials in thermonuclear fusion reactor (such as ELMs effects in the reactor Iter or at the first wall of the chambers with inertial plasma confinement) in order to study and predict their behavior under these conditions.

Added: May 17, 2016
Article
Kiselyova N., Dudarev V.A., Korzhuev M. Inorganic Materials: Applied Research. 2016. Vol. 7. No. 1. P. 34-39.

A database (DB) on the bandgap of inorganic substances available via the Internet (http://bg.imetdb.ru) was developed for the information service of specialists in the sphere of inorganic chemistry and materials science. The DB is integrated with other information systems on the properties of inorganic substances and materials, which provides the search of a wide range of parameters of a specific sub stance. The possibility of the use of the information from the developed DB for the search of relations between the bandgap width and other parameters of thermoelectric materials and for predicting the bandgap of chal copyrites is considered.

Added: Feb 23, 2016
Article
Pavlenko V. I., Novikov L. S., Bondarenko G.G. et al. Inorganic Materials: Applied Research. 2013. Vol. 4. No. 2. P. 169-173.

The paper presents experimental data on the effects of the flow of atomic oxygen (AO) for highly filled composites of high impact polystyrene (HIPS) and superfine silicon-organic filler. The coefficients of erosion after exposure to AО, by scanning electron microscopy of the composites was studied relief after irradiation. Also in the paper, the physical and mathematical modeling of erosion processes on the basis of the data.

Added: Sep 28, 2012
Article
Novikov L., Voronina E., Chirskaya N. Inorganic Materials: Applied Research. 2014. Vol. 4. No. 2. P. 107-115.

Features of formation and migration of radiation-induced defects in carbon nanotubes (CNT) and nanostructured materials are examined. The main methods and software tools used for the simulating nanomaterial structure and space factors are described. The results of mathematical simulation are presented.

Added: Mar 2, 2015
Article
Morozov E. V., Demin A. S., Pimenov V. N. et al. Inorganic Materials: Applied Research. 2018. Vol. 9. No. 3. P. 361-369.

The degradation of a bilateral pressed tungsten surface layer by pulsed laser irradiation in the freerunning mode (power density q = 105–5 × 106 W/cm2, pulse duration τ = 0.7 ms) and the Q-switched mode (q = 109–1010 W/cm2, τ = 80 ns) as well as under plasma beam irradiation in a plasma focus (PF) device (q = 108–1012 W/cm2, τ = 10–100 ns) has been investigated. The features of the degradation, erosion, and structural changes in the tungsten surface layer under different irradiation conditions have been determined. It has been shown that the use of PF devices in combination with laser equipment is promising for the simulation of the extreme radiation–thermal effects in materials that are typical of thermonuclear fusion devices with magnetic and inertial plasma confinement.

Added: May 18, 2018
Article
Pavlenko V. I., Bondarenko G.G., Tarasov D. G. et al. Inorganic Materials: Applied Research. 2013. Vol. 4. No. 5. P. 389-393.

The work presents the technological regime of manufacturing of the high-filled composites on the base of a fluoroplastic matrix, and results about the modification of polymer composites obtained under γ-irradiation action. Paramagnetic centers on atoms of silicon Х• and peroxide CFO2 • macroradicals form by the action of γ- irradiation in the structure of polymer composite. The relations radicals X•/SFO2• are defined by the EPR method. The optimal degree of filling of fluoroplastic matrix modified bismuth oxide is chosen. At accumulated dose of 5 MGy the strength of  composite did not change.

 

 

Added: Nov 6, 2013
Article
Andreev V. V., Bondarenko G., Mihal'kov A. M. et al. Inorganic Materials: Applied Research. 2011. Vol. 2. No. 5. P. 425-427.
Added: Jan 30, 2014
Article
Pimenov V. N., Bondarenko G.G., Dyomina E. V. et al. Inorganic Materials: Applied Research. 2019. Vol. 10. No. 3. P. 503-511.

The damage and structural state of the surface layer of Al–Li–Mg samples composed of Al–5% Mg–2% Li (wt %) under pulsed action of power streams of high-temperature deuterium plasma and highenergy deuterium ions in the Plasma Focus (PF) device have been investigated. The radiation power density was q ~ 106 W/cm2; the pulse duration was 50–100 ns. Pulsed thermal heating and rapid cooling is established to lead to the melting and solidification of a thin surface layer of the alloy for several tens of nanoseconds. At the same time, in the superheated surface layer of the alloy, microcavities of a spherical shape are formed which is associated with intense evaporation of lithium into micropores within the heated layer. Thermal stresses caused by abrupt heating, melting, and cooling of a thin surface layer of metal result in formation of microcracks in the near-surface zone of the samples. The evaporation by the power electron beam of the elements of the anode material of the PF device (copper and tungsten) and their subsequent deposition onto the irradiated surface of the investigated samples in the form of droplets of submicron size are noted. It is shown that the thermal and radiationstimulated processes generated in the alloy under the action of pulsed energy fluxes in the implemented irradiation regime lead to the redistribution of elements in the surface layer of the aluminum solution, contributing to an increase in magnesium content and the formation of magnesium oxide on the surface.

Added: Jun 2, 2019
Article
Andreev V. V., Bondarenko G., Stolyarov A. A. et al. Inorganic Materials: Applied Research. 2014. Vol. 5. No. 2. P. 129-132.

The charge state change of MOS structures with multilayer dielectric films SiO2–PSG under highfield injection modification at different temperatures is studied in this article. The effect of temperature on the thermal stability of the negative charge component used to adjust the threshold voltage of MOS transistors is investigated. It is found that the performance of the highfield injection modification of MOS structures in the mode of constant current at elevated temperatures increases not only the density of the trapped negative charge but also its thermally stable component.

Added: Aug 4, 2014
Article
A.P.Tyutnev, G.A. Belik, A.E. Abrameshin et al. Inorganic Materials: Applied Research. 2013. Vol. 4. No. 2. P. 98-102.

Abstract—Charging of polymeric samples with grounded metal layer is studied by two main schemes of experiment. In the first scheme, a polymer film is irradiated with the low-energy electrons with energy of 20–40 keV under conditions of absence of grounded metal objects nearby. It is demonstrated that development of breakdown in the double electrical layer on the open surface of the polymer is impossible. In the second scheme, when a grounded metallic mask is placed on the surface of the polymer film in the irradiation zone, discharges are easily initiated and represent spark creeping discharges. A possible mechanism of their initiation is proposed.

Added: Apr 18, 2013
Article
Andreev V. V., Bondarenko G., Stolyarov A. A. et al. Inorganic Materials: Applied Research. 2015. Vol. 6. No. 2. P. 128-132.

Dielectric films and siliconinsulator interfaces in metalinsulatorsemiconductor (MIS) structures are modified using injectionthermal treatment, which involves highfield injection of a specified charge into the gate dielectric and subsequent annealing of the structure. The effect of the injectionthermal treatment modes on the MIS structure modification is investigated. The injectionthermal treatment is shown to reduce imperfection of the dielectric films and, thus, enhance reliability of the MIS devices. It is established that the MIS structure modification processes occurring at the injectionthermal treatment are largely identical to those occurring at the radiation thermal treatment; therefore, for certain MIS devices, the radiation thermal treatment can be replaced by the injectionthermal one.

Added: Apr 9, 2015
Article
Pavlenko V. I., Bondarenko G.G., Cherkashina N. I. Inorganic Materials: Applied Research. 2020. Vol. 11. No. 2. P. 304-311.

The article presents the possibility of obtaining polymer composite materials based on thermoplastic polyimide and tungsten oxide (WO3) modified with a hydrophobic silicone fluid. Data on surface microscopy, Vickers microhardness, density, and thermal stability of composites with different tungsten oxide contents are presented. As a result of modifying tungsten oxide, its surface becomes hydrophobic, and the contact angle increases from 31° to 101°. The microstructure of the surface of composites has a fine-grained structure without microcracks and chips. The lowest density material has no filler. With increasing filler content, the density increases. When the content of the filler is 80 wt %, the density is 4.35 g/cm3. The optimum content of tungsten oxide filler is 60 wt % as measured by the surface microhardness. The work shows that the introduction of the proposed filler significantly increases the heat resistance of polyimide. Pure polyimide is stable up to 425°С, and at a temperature of 680°С, its full thermal decomposition takes place. With increasing content of modified tungsten oxide in the composite, the rate of mass loss decreases. In the composite containing 60 wt % filler at 680°C, the mass loss is 38%.

Added: Apr 2, 2020
Article
Yastrebinskii R. N., Bondarenko G., Pavlenko V. I. Inorganic Materials: Applied Research. 2017. Vol. 8. No. 5. P. 691-695.

It is shown that a constructional radiation-shielding composite material with high resistance to radiation-thermal loads can be obtained. The material was produced using a Portland cement mix, boroncontaining chrysotile, magnetite filler, plasticizing additives, and metal fraction by the vibro-packing method. The content of chemically bound water was at least 1.5 wt %. Exposure to high doses of gamma radiation led to formation of monocalcium ferrite CaFe2O4 with high physical and X-ray density in the cement– magnetite–serpentinite composite. Its formation resulted in radiation hardening and increased the mechanical strength of the composite up to the dose of 10 MGy. When a protective composite was exposed to γ radiation with the absorbed dose of 20 MGy, the mechanical strength of the composite was reduced by only 4– 5% compared to that of the unirradiated sample.

Added: Sep 19, 2017
Article
Yastrebinskii R. N., Bondarenko G., Pavlenko V. I. Inorganic Materials: Applied Research. 2016. Vol. 7. No. 5. P. 718-723.

The effect of fast electrons with energy of 0.5–6.2 MeV at a fluence of 1018 electrons/cm2 and γ sources of 60Со (Е = 1.25 МeV) at the absorbed dose of 0.1–25 MGy on the radiation-protective composites based on a magnetite matrix used for biological protection of nuclear reactors is calculated and studied experimentally. The depth of penetration of the electron beam and the nature of distribution of the absorbed dose of fast electrons on thickness of the protective composite are studied. The processes promoting change in the oxidation and coordination states of iron atoms and structural-phase and magnetic states in the composite under the influence of fast electrons and γ radiation are determined.

Added: Sep 21, 2016
Article
Kalaev M., Semkin N., Novikov L. Inorganic Materials: Applied Research. 2013. Vol. 4. No. 3. P. 205-210.

We study experimentally how optical, electrical, and physical properties of spacecraft surface elements (optical glasses, "metal-insulator-metal" structures, and solar arrays) change upon bombardment by high-speed particles of submicron and micron size. For particle acceleration, we use an electrodynamic accelerator. В© Pleiades Publishing, Ltd., 2013.

Added: Mar 2, 2015
Article
Bondarenko G., Kokin M., Pyatykh D. S. et al. Inorganic Materials: Applied Research. 2012. Vol. 3. No. 2. P. 179-182.

A method based on the spectral analysis of thermowave oscillations formed under the effect of radiation of lasers operated in a periodic pulsed mode is developed for investigating the state of the interface of multilayered systems. The method is based on high sensitivity of the shape of the oscillating component of the pyrometric signal to adhesion characteristics of the phase interface. The shape of the signal is quantitatively estimated using the correlation coefficient (for a film–interface system) and the transfer function (for multilayered specimens).

Added: Nov 30, 2012
Article
Yastrebinskii R. N., Bondarenko G.G., Pavlenko A. V. Inorganic Materials: Applied Research. 2018. Vol. 9. No. 5. P. 825-831.

In work researches of structural features of mineral crystal phases and deficiency of crystals of an organosilikonate of bismuth are conducted at various temperature of its processing (from 100 to 5000C). According to x-ray diffraction ranges in СuКα - radiation the periods of a crystal lattice of a crystal are estimated, the analysis of broadening of the most intensive diffraction line for this crystal taking into account crystallographic indexes h, k, l by an approximation method for determination of the size of areas of coherent dispersion and microdistortions of a crystal lattice Δа/а is made. On the basis of the conducted researches it is revealed that at heat treatment of the Na2O-Vi2O3-SiO2 system (NBS material) in a temperature interval 300-5000C there was a decrease in amorphy, microdistortions and density of dislocations of defects in a crystal lattice of a sillenit of structure of Bi12SiO20. Formation of more dense structure of a crystal of a sillenit with the increased x-ray density (9,210 g/cm3) and increase in parameters of a cubic lattice of a crystal is recorded (and =10,1335 Å). The developed material of structure Bi12SiO20 can be used as a gamma and protective filler of radiation protective polymers, and also for creation of electro-and magneto-optical modulators of laser radiation.

Added: Oct 3, 2018
Article
Yastrebinskii R. N., Bondarenko G.G., Pavlenko A. V. Inorganic Materials: Applied Research. 2018. Vol. 9. No. 2. P. 221-226.

A combined method for synthesizing a highly dispersed (0.8–2.5 μm) hydrophobic Na2O– Bi2O3–SiO2 powder (NBS powder) based on solutions of sodium methyl siliconate and bismuth nitrate is studied. The powder is synthesized at a reduced temperature (100°C). The microstructure and the phase composition of the resulting compounds in the Na2O–Bi2O3–SiO2 system at different processing temperatures are investigated. The structural phase transformations in the mineral phases of NBS powder are revealed in the temperature range of 100–500°C. The metastable bismuth silicate Bi2SiO5 at 400°C is transformed into stable sillenite with composition Bi12SiO20 having a cubic crystal structure (a = 10.1050 Å). The synthesized NBS powder can be used as a filler to fabricate highly effective constructional radiation-shielding polymer composites with tailored properties.

Added: Mar 28, 2018
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