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Point Defect Model for the kinetics of oxide film growth on the surface of T91 steel in contact with lead–bismuth eutectic
Corrosion Science. 2023. Vol. 211. Article 110829.
Point Defect Model (PDM) has been successfully employed for aqueous solutions to describe the rate of surface corrosion of structural materials. In this work, the adaptation of PDM for the case of lead–bismuth coolant is developed. The necessary modifications in the set of electrochemical reactions and in the model of electrostatic potential distribution in the oxide film are made. Parameters of the proposed model, PDM_PB, are optimized using the experimental data for T91 grade steel. The obtained adaptation of PDM shows applicability to the case of lead and lead–bismuth coolants which is of critical importance for the next-generation fast-neutron reactors.
Publication based on the results of:
Бондаренко Г.Г., Кристя В. И., Савичкин Д. О. et al., Поверхность. Рентгеновские, синхротронные и нейтронные исследования 2026 № 4 С. 29–36
Сформулирована модель тлеющего газового разряда в смеси аргона и паров ртути при наличии
на поверхности катода тонкой диэлектрической пленки. Рассчитаны зависимости характеристик
разряда от температуры в интервале ее изменения, в котором заметный вклад в ионизацию
рабочей газовой смеси дает ионизация атомов ртути метастабильными возбужденными атомами
аргона (реакция Пеннинга). Показано, что в случае катода без диэлектрической пленки при
повышении температуры до ...
Added: June 20, 2026
Zirnik G., Ostovari Moghaddam A., Zhukov S. et al., Journal of Materials Science: Materials in Electronics 2026 Vol. 37 Article 738
In regards to the advances in InGaZnO for flexible transistors applications, herein for the first time we measure the broadband radio-frequency range (10 Hz to 1 MHz) dielectric permittivity ε′ and electrical conductivity σ of InGaZnO4 nanoparticle layers at different temperatures ranging from 10 to 300 K. The InGaZnO4 nanoparticles prepared by metal–nitrate–glycol gel decomposition method exhibited ...
Added: June 6, 2026
Das A., Saikia J., Maji N. et al., ChemNanoMat 2026 Vol. 12 No. 5 Article e202500733
Developing efficient photoactive materials from bio-derived resources is vital yet challenging for achieving effective water splitting performance. In this work, nano carbon dots (CDs) of zero-dimensional (0D) were synthesized from papaya peel through a simple and eco-friendly process and subsequently anchored onto the two-dimensional (2D) layered structure of graphitic carbon nitride (g-C3N4, GCN) at various ...
Added: June 2, 2026
Wary R. R., Mahato B., Sharma N. et al., The Journal of Physical Chemistry Letters 2026 Vol. 17 No. 17 P. 5099–5107
Development of heterojunction materials is an efficient approach for enhancing photocatalytic and photoelectrochemical processes. We develop a ZnO/CuO heterojunction via Cu doping into a ZnO matrix. Structural characterization confirmed that Cu was effectively incorporated into ZnO without any structural changes. The improved optical properties and reduced charge carrier recombination of the doped samples were confirmed ...
Added: June 2, 2026
Duran E. ., Pulgar A., Izquierdo R. et al., Physica Status Solidi (A) Applications and Materials 2026 Vol. 223 No. 7 Article e202500942
Ceramic superconductors exhibit remarkable properties, including zero electrical resistance and potent magnetic behavior, operating at temperatures as high as the boiling points of liquid nitrogen (77 K) and liquid hydrogen (20 K). These characteristics position them as key enablers for sustainable technologies spanning electric propulsion, lossless energy transmission, advanced medical imaging, and quantum computation. This review presents ...
Added: June 1, 2026
Андреев Д. В., Корнев С. А., Bondarenko G. et al., Перспективные материалы 2026 № 6 С. 5–11
Выполнено сравнительное исследование процессов сильнополевой зарядовой
деградации подзатворного диэлектрика структур металл-диэлектрик-полупроводник (МДП)
с алюминиевым и поликремниевым затвором. Зарядовые явления в МДП-структурах
изучали методом сильнополевой инжекции электронов в диэлектрик в режиме возрастания
плотности стрессового инжекционного тока с кратковременными переключениями
в измерительный режим при постоянной низкой плотности инжекционного тока.
Использование данного метода позволило получить новые данные о процессах зарядовой
деградации подзатворного диэлектрика МДП-структур с ...
Added: May 21, 2026
Rathish S., Andrey S. Vasenko, Thazhathenair A. et al., The Journal of Physical Chemistry Letters 2026 Vol. 17 No. 18 P. 5386–5394
We demonstrate and rationalize the effect of Au nanoparticles (NPs) on the hierarchical g-C3N4/CeO2 heterojunction. g-C3N4/CeO2 decorated with monodispersed plasmonic Au NPs was synthesized. Detailed analyses showed that CeO2 nanocubes and monodispersed Au NPs were evenly distributed over the 2D g-C3N4 surface, forming a robust interface enriched with abundant active sites. The structure enabled efficient separation of photogenerated charge ...
Added: May 16, 2026
Paul R., Das A., Sharma N. et al., Colloids and Surfaces A: Physicochemical and Engineering Aspects 2026 Vol. 728 Article 138830
Niobium-doped TiO2 (Nb-TiO2), demonstrates dual functionality as an efficient photocatalyst for dye degradation and a promising photoelectrocatalyst for water oxidation. Nb incorporation via a facile hydrothermal method was confirmed by XRD (Rietveld refinement), XPS, TEM, FT-IR, Raman, and BET analyses, indicating successful lattice doping and structural modification. Photocatalytic dye degradation experiments were conducted using a model ...
Added: May 16, 2026
Гущина В. А., / Series chemrxiv-2023-vpzhz-v2 "ChemRxiv". 2023.
All-inorganic perovskite CsPbBr3 and Cs4PbBr6 nanoparticles are being intensively studied due to their unique properties and wide range of applications; however, however, the nature of their optical properties is not yet fully understood due to the difficulty of synthesis of singlephase nanoparticles. In this article we describe the features of the synthesis of single-phase particles ...
Added: May 14, 2026
Гущина В. А., Mendeleev Communications 2025 Vol. 35 No. 2 P. 193–195
All-inorganic perovskite CsPbBr3 and Cs4PbBr6 nanoparticles are intensively studied for their unique optical properties, though synthesizing single-phase nanoparticles has posed challenges. Detailed synthesis method of CsPbBr3 and Cs4PbBr6 single-phase nanoparticles and their chemical and phase analysis are described. Distinctive optical characteristics, such as photoluminescence, optical band gap and the Urbach tail region, are revealed and explained within the current ...
Added: May 14, 2026
Гущина В. А., Physics of Complex System 2026 Vol. 7 No. 1 P. 3–15
Heterostructures based on ZnO nanorods and CsPbBr3 nanocrystals were investigated for their potential as semiconductor SERS substrates. We found that ZnO morphology governs the efficiency of interfacial energy transfer, leading to enhanced photoluminescence under 390 nm excitation and a noticeable reduction of the bandgap in the composites. Raman analysis revealed a pronounced intensity enhancement and ...
Added: May 14, 2026
Гущина В. А., Russian Journal of Inorganic Chemistry 2024 Vol. 69 No. 6 P. 940–948
Currently, ABX3 nanoparticles (NPs) based on lead halides attract the attention due to their unique optical properties and a wide range of applications. The preparation of NPs with lead as a partial or complete replacement is particularly interesting because of the toxicity of this chemical element and most of its compounds. In this study, we propose a ...
Added: May 6, 2026
Yasnitsky L., Голдобин М. А., Мезенцев А. С., Прикладная математика и вопросы управления 2025 № 2 С. 99–116
Представлен обзор современных методов и основанных на них программных
инструментах, применяемых для математического моделирования серийных производственных процессов с целью снижения брака и повышения качества производимых изделий. Перечисляются группы работ, нацеленных на обнаружение и классификацию дефектов, работ, в которых решаются задачи прогнозирования образования дефектов и определения значимости параметров, работ направленных на поиск
оптимального сочетания технологических параметров изготовления изделий, ...
Added: May 5, 2026
Morozov E. V., Demin A. S., Borovitskaya I. V. et al., Inorganic Materials: Applied Research 2026 Vol. 17 No. 3 P. 619–626
This article presents the results of experiments on the impact of powerful pulsed ion-plasma and
electron flows generated in the working chamber of the Plasma Focus PF-5M installation during each highvoltage
discharge on a model aluminum alloy B95. It is shown that the general characteristics of the alloy’s
damage upon exposure to pulsed flows of helium ions (HI) ...
Added: May 4, 2026
Pavlenko V. I., Bondarenko G.G., Cherkashina N. I. et al., Inorganic Materials: Applied Research 2026 Vol. 17 No. 2 P. 276–282
A composite material based on polyethylene, boron carbide (B4C), and bismuth oxide (Bi2O3) is
synthesized by the method of joint cryogenic milling of all components in liquid nitrogen environment followed
by pressing. The effect of cryogenic milling on the distribution of fillers in a composite is studied and
the prospects of using this method are assessed in comparison ...
Added: April 9, 2026
Черкашина Н. И., Павленко В. И., Bondarenko G. et al., Перспективные материалы 2026 № 4 С. 14–26
В данной работе представлен синтез гибкого полимерного композита для защиты от радиации на основе каучуковой матрицы и оксидов редкоземельных металлов, таких как Dy2O3 и Gd2O3, предназначенного для создания радиационно-защитных экранов и средств индивидуальной защиты. Исследованы его физико-механические характеристики: составы с добавлением оксида диспрозия имеют плотность от 1,31 до 2,44 г/см3, предел прочности при растяжении от ...
Added: April 2, 2026
Chowde Gowda C., Alexey Kartsev, Tiwari N. et al., Journal of Materials Chemistry C 2024 Vol. 12 No. 46 P. 18691–18703
Two-dimensional (2D) chromium telluride Cr2Te3 exhibits strong ferromagnetic ordering with high coercivity at low temperatures and paramagnetic behavior when approaching room temperature. The spin states of monolayer Cr2Te3 show ferromagnetic ordering in the ground state. In situ Raman analysis reveals a reversible structure transformation and hence proves ferromagnetic to paramagnetic transition during low-temperature heating cycles (0–25 °C). The magnetic ...
Added: March 16, 2026
Zhukov V. P., Chulkov E., Physica B: Condensed Matter 2024 Vol. 695 Article 416529
Ab initio calculations of the electronic structure and thermoelectric characteristics of low- and high-temperature phases of tin selenide, SnSe, with electronic and hole conductivity have been performed. It is shown that the calculations of thermoelectric properties on the basis of the Boltzmann-Onzager theory with consideration of carrier scattering on optical phonons lead to results in good agreement with experimental data. At temperatures below ...
Added: September 24, 2025
Yasnitsky L., Shteinle D. K., , in: 2024 6th International Conference on Control Systems, Mathematical Modeling, Automation and Energy Efficiency (SUMMA).: NY: IEEE, 2024. P. 780–783.
The aim of the work is to obtain recommendations for the selection of the chemical composition of the raw material mass, ensuring a reduction in the defects of high-strength steel smelted in an open-hearth furnace, as well as the creation of an intelligent supervisor of an automated steelmaking process control system. Machine learning models are ...
Added: July 11, 2025
Грузман В. М., Yasnitsky L., Литейное производство 2024 № 6 С. 25–27
Brief information on the mathematical processing of accumulated production data in metallurgy is given. Attention is drawn to the large volume of these data (3000 and 5000 heats) when determining the relationship between the chemical composition and mechanical properties of carbon steel. ...
Added: August 7, 2024
Егорышева А. В., Голодухина С. В., Плукчи К. Р. et al., Журнал неорганической химии 2023 Т. 68 № 12 С. 1702–1714
Разработаны методики синтеза LaNi1/3Sb5/3O6 со структурой розиаита цитратным методом и соосаждением с последующим отжигом. Показано влияние условий синтеза на морфологию образцов.
Проведен сравнительный анализ каталитических свойств LaNi1/3Sb5/3O6, синтезированного различными методами, в реакции окисления СО. Наибольшую эффективность и стабильность продемонстрировал катализатор, синтезированный цитратным методом (температура 90%-ной конверсии СО составила T90 = 336°С). Методами ИК-спектроскопии диффузного отражения in ...
Added: November 11, 2023
Ilyushchenko M., Salikov R., Litvinenko V. et al., Journal of Organic Chemistry 2023 Vol. 88 No. 9 P. 5661–5670
An approach to the synthesis of seven-membered systems via the chain elongation of nucleophilic propenes and subsequent 8π-electrocyclization is proposed. The cascade reaction yields either cycloheptadienes or bicycloheptenes, and the latter are formed via a 6π-electrocyclization of intermediate cycloheptadienyl anion which was proved to be reversible in a basic medium. The electrocyclic nature of the ...
Added: October 18, 2023
Cha J., Lee E., Dmitry V. Yandulov, Inorganic Chemistry 2022 Vol. 61 No. 37 P. 14544–14552
Molecular oxygen (O2) remains to be an ideal yet underutilized feedstock for the oxidative transformation of organic substrates and renewable energy systems such as fuel cells. Palladium (Pd) has shown particular promise in enabling these applications. The present study describes a Pd-mediated O2 reduction to water via C–H activation of 9,10-dihydroanthracene (DHA) by a Pd(II) ...
Added: October 24, 2022
Abramov V., Abramova A., Bayazitov V. et al., Processes 2022 Vol. 10 No. 10 Article 2063
Although water contamination with drug residues is a threat to public health, there are currently barely any effective methods of purifying water from pharmaceutical substances. In this study, continuous-flow sonoplasma treatment was used for the complete degradation of tetracycline and ciprofloxacin in polluted municipal water. The addition of CeO2 nanoparticles as catalysts significantly increased the degradation ...
Added: October 23, 2022