?
Реологические и адгезионные свойства клеев-расплавов на основе нефтеполимерных смол и полиэтиленвинилацетата
Высокомолекулярные соединения. Серия А. 2021. Т. 63. № 3. С. 184–197.
Костюк А. В., Смирнова Н. М., Antonov S. V., Ильин С. О.
Polymer hot-melt adhesives are obtained on the basis of poly(ethylene-vinyl acetate), polyethylene wax, and aromatic (C9) hydrocarbon resins differing in the degree of hydrogenation of aromatic groups (from 0 to 37%). The content of poly(ethylene-vinyl acetate) is varied from 30 to 80%, and the concentration of other components of the adhesive is within 10–35%. The rheology of adhesive components and blend compositions is studied in detail, and the adhesion characteristics of the adhesives are determined. It is found that the use of a nonhydrogenated resin leads to high adhesion properties of the adhesive but imparts viscoplasticity to it. The use of a hydrogenated resin provides better rheological properties of the adhesive, but a higher content of poly(ethylene-vinyl acetate) is required to achieve good adhesion characteristics.
Nazarov Alexey A., Dudarova N., Zhidkova O. et al., Journal of Photochemistry and Photobiology A: Chemistry 2026 Vol. 483 Article 117654
Сyclocondensation of phenyl, ortho-bromophenyl, para-phenylphenyl, para-methoxycarbonylphenyl, para-tolyl and para-methoxyphenyl boronic acid with curcumin in the presence of K3PO4 upon refluxing in 1,4-dioxane for 24 h leads to the formation of curcumin-based 2,2-diaryl-1,3,2-dioxaborines in good yields. The absorption-emission spectra of the synthesized fluorescent conjugates and 1,3,2-dioxaborine with para-biphenyl boronic substituent demonstrated the highest quantum yield. Among the compounds studied, conjugate curcumin with para-methoxycarbonylphenyl boronic substituent ...
Added: September 9, 2026
Chemical Papers 2026
Benzenoid hydrocarbons are structurally regular aromatic compounds, which makes them well suited for quantitative structure–property relationship (QSPR) studies. This study presents a QSPR analysis of nineteen benzenoid hydrocarbon species using degree-based topological co-indices. We developed a Python program to compute eleven degree-based topological co-indices from molecular graphs and evaluated their ability to explain variations in ...
Added: September 8, 2026
Gurina D., Fashchevsky K. A., Oparin R. D. et al., Surfaces and Interfaces 2026 Vol. 98 Article 110545
In this work, we combine experimental characterization and molecular dynamics (MD) simulations to elucidate the molecular mechanisms governing the impregnation of mefenamic acid (MFA) into nanocrystalline cellulose (NCC) aerogels. NCC aerogels were impregnated with MFA in scCO2, and low-temperature nitrogen adsorption revealed a concentration-dependent decrease in surface area, pore volume, and pore size, with an ...
Added: September 8, 2026
Marychev P., Shanenko A., Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 114 No. 7 Article 074509
We investigate the effect of weak interband impurity scattering on the intertype (IT) domain between type-I and type-II superconductivity in diffusive two-band superconductors. Our results show that the significant broadening of the IT domain with increasing band diffusivity ratio, previously established in the absence of interband scattering, persists under weak interband scattering. However, depending on ...
Added: September 7, 2026
Томаева М. А., Неверов В. Д., Shanenko A. et al., Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 114 P. 1–6
We report a thermally driven structural crossover of vortex matter in a two-dimensional superconducting Penrose quasicrystal. At low temperatures, vortices are pinned by the quasiperiodic lattice, forming an aperiodic pattern. With increasing temperature, vortex-vortex interactions dominate, leading to a conventional triangular Abrikosov lattice. Our findings reveal a tunable interplay between intrinsic pinning and vortex interactions, ...
Added: September 5, 2026
Неверов В. Д., Красавин А. В., Vagov A. et al., Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 113 P. 1–6
We develop a neural network approach to solve the self-consistent Bogoliubov-de Gennes equations in strongly disordered s-wave superconductors. The method accurately reproduces inhomogeneous gap distributions and generalizes to system sizes far larger than those used in training. It reduces computational scaling from O(N6 ) to O(N2), enabling quantitative analysis of percolation phenomena and the superconductor-insulator ...
Added: September 5, 2026
Бондаренко Г.Г., Фишер М. Р., Кристя В. И., Известия РАН. Серия физическая 2026 Т. 90 № 4 С. 867–874
Сформулирована модель катодного слоя тлеющего газового разряда при наличии на
части рабочей поверхности катода тонкой диэлектрической пленки. Показано, что переход тлеющего разряда в дуговой разряд, сопровождающийся значительным увеличением плотности разрядного тока и уменьшением катодного падения напряжения, происходит наиболее быстро, если
пленка занимает примерно половину поверхности катода. ...
Added: September 4, 2026
Budkov Y., Journal of Chemical Physics 2026 Vol. 165 No. 9 Article 094902
We derive the stress tensor of a flexible polymer solution within the Gaussian-chain self-consistent field theory (SCFT) without invoking the ground-state dominance (GSD) approximation. Starting from a covariant formulation of the single-chain partition function in a background metric, we obtain the symmetric stress tensor expressed through the full Edwards propagators. The result contains the local ...
Added: September 2, 2026
Novikov A., Polyhedron 2026 Vol. 299 Article 118358
Two new supramolecular halometalate hybrid complexes, (H2bpen){[MCl5](I2)} (M = Sb(III) (1) and Bi(III) (2); bpen – 1,2-Bis(4-pyridyl)ethylene, have been prepared. Despite very close similarity of the nature of cations, they reveal significant structural difference from the (H2bpe){[MCl5](I2)} (bpe – 1,2-bis(4-pyridil)ethane) reported earlier. We discuss these features, along with thermal stability, optical properties as well as Raman spectra ...
Added: September 2, 2026
Danil Kobtsev, Jarashneli A., Maman N. et al., Applied Sciences (Switzerland) 2026 Vol. 16 No. 17 Article 8577
AIVBVI semiconductors, particularly lead chalcogenides, remain key materials for mid-wave infrared (MWIR) photodetection due to their narrow bandgap and exceptional carrier transport properties. However, the realization of high-quality p-type PbTe thin films, suitable for p–n junction devices, remains a technological challenge. In this work, we report the fabrication of high-mobility p-type PbTe thin films grown on ...
Added: August 30, 2026
Meng K., Vasenko A., Chulkov E. et al., The Journal of Physical Chemistry Letters 2026 Vol. 17 No. 36 P. 10546–10554
Data-driven discovery of sodium-ion cathodes is often limited by small data sets and the poor interpretability of graph neural networks (GNNs). Here, we developed Symbol_ETR, an interpretable framework combining symbolic regression with ensemble learning. By constructing explicit nonlinear descriptors, symbolic regression extra trees regression (Symbol_ETR) achieves a test R2 of 0.90 for average voltage prediction ...
Added: August 29, 2026
Belousov Y., Кискин М. А., Sidoruk A. et al., Australian Journal of Chemistry 2022 Vol. 75 No. 9 P. 572–580
Four new complexes [Ln(pfaa)3(H2O)2]n (Ln = Eu (1), Tb (2)) and [Ln2Cd2(pfaa)10 (phen)2(EtOH)2]·2MeCN (Ln = Eu (3), Tb (4), phen = 1,10-phenanthroline) based on pentaphorphenylacetic acid (Hpfaa) have been prepared and completely investigated. The structures of compounds 1 and 3 were studied by single crystal X-ray diffraction analysis: the isostructural complexes 1 and 2 represent ...
Added: August 26, 2026
Mazur D., Petr E. Brandyshev, Doronin S. et al., Electrochimica Acta 2026 Vol. 577 Article 149729
The electric double layer (EDL) at a single-crystal metal surface is controlled not only by the electrolyte composition and the electrode potential, but also by the atomic structure of the surface itself. This makes the Ag(hkl)/NaF interface a stringent test for continuum theories of the EDL. In the third part of our series, we examine ...
Added: August 20, 2026
Budkov Y., Kalikin N., Journal of Chemical Physics 2026 Vol. 165 Article 064506
A self-consistent statistical-mechanical theory of the Hall effect in electrolyte solutions is developed by extending the self-consistent Debye–Hückel–Onsager (SCDHO) framework to crossed electric and magnetic fields. The theory incorporates non-local ionic charge distributions via Slater-type form factors, regularizing the Coulomb interaction at short range, and accounts for dielectric friction through ion-specific coefficients, employing experimental values ...
Added: August 12, 2026
Obijiofor O., Alexander S. Novikov, New Journal of Chemistry 2026 Vol. 50 No. 33 P. 13931–13957
The rational design of coinage metal nanocarriers requires a mechanistic understanding of metal-drug binding and predictive descriptors that translate molecular interactions into design rules. Using DFT (B3LYP-D3BJ/def2-TZVP, SMD water), we systematically investigated the binding of 5-fluorouracil (5-FU) and levodopa (l-DOPA) to neutral and cationic homo- and heteronuclear dimers of Au, Ag, and Cu (Au2, Ag2, ...
Added: August 12, 2026
G. G. Bondarenko, Kristya V. I., Savichkin D. O. et al., Journal of Surface Investigation: X-Ray, Synchrotron and Neutron Techniques 2026 Vol. 20 No. 2 P. 417–423
A model of a glow gas discharge in a mixture of argon and mercury vapor is formulated in the presence
of a thin insulating film on the cathode surface. Dependences of the discharge characteristics on the
mixture temperature are calculated in the range of its variation, in which a noticeable contribution to ionization
of the working gas is ...
Added: August 1, 2026
Voropaeva D., S. Novikova, I. Stenina et al., Solid State Ionics 2026 Vol. 445 Article 117288
Composite gel polymer electrolytes based on a perfluorinated sulfonic acid cation-exchange MF-4SC membrane
containing surface-sulfonated nanoparticles of aluminum oxide, cerium (IV) oxide, and titanium oxide (sAl2O3,
sCeO2, and sTiO2, respectively) were prepared by casting from a dispersion in N,N-dimethylformamide and
plasticized with a 1,3-dioxolane/1,2-dimethoxyethane mixture. The influence of the filler nature on ionic conductivity,
solvent uptake, activation energy, lithium ...
Added: July 30, 2026
Садртдинова Г. И., Vinogradov A., Nifantiev I. et al., Polymer 2025 Vol. 339 Article 129133
Isotactic copolymerization of but-1-ene with bio-based undec-10-en-1-ol (M1), dec-9-en-1-ol (M2) and their silyl esters (M3–M5), catalyzed by C1-symmetric ansa-heterocene [Me2Si(η5-2,4,7-trimethelinden-1-yl)(η5-2,5-dimethyl-7H-cyclopenta[1,2-b:4,3-b']dithiophen-7-yl)]ZrCl2 (Zr1), activated by iBu3Al and MMAO-12, was explored for the first time. At [AlMMAO]/[Zr1] = 40 and [Monomer]/[Zr1] = 5,000, iBu2Al-protected ω-alken-1-ols have demonstrated highest activities and up to 16.7 mol% degrees of the comonomer incorporation with a formation of ...
Added: May 12, 2026
Садртдинова Г. И., Ovchinnikova V., Ilyin S. et al., Petroleum Chemistry 2024 Vol. 64 P. 1253–1265
The paper proposes a series of promising Zr(IV) complexes and experimentally confirms that, when activated with minimal amounts of modified metylaluminoxane MMAO-12 ([Al]/[Zr] ~20–40), these complexes are able to initiate copolymerization of hex-1-ene with polar vinyl monomers FG-(CH2)8CH=CH2 [where FG is a functional group selected from C(O)NMe2, CH2OSiMe3, C(O)OiPr, and CH2OH]. The prepared copolymers were ...
Added: May 12, 2026
Nesterova I., Kondratyuk N., Budkov Y. et al., Advances in Colloid and Interface Science 2025 Vol. 346 Article 103623
Room temperature ionic liquids show great promise as electrolytes in various technological applications, such as energy storage or electrotunable lubrication. These applications are particularly intriguing due to the specific behavior of ionic liquids in nanoconfinement. While previous research has been focused on optimizing the required characteristics through the selection of electrolyte properties, the contribution of ...
Added: September 2, 2025
Лесин А. В., Исаев А. В., Тонконогов Б. П. et al., Тонкие химические технологии 2023 Т. 19 № 6 С. 485–496
Objectives. A quick cold start of emergency and auxiliary power units based on diesel engines should be possible at any time without
problems and in the shortest possible time. The condition of the engine oil is one of the most important factors influencing the smooth
start-up of power plants. During diesel engine operation, engine oil accumulates soot ...
Added: February 26, 2025
Ilyin S., Kostyuk A., Anokhina T. et al., International Journal of Molecular Sciences 2023 Vol. 24 No. 9 Article 8057
The weak point of ionic liquids is their high viscosity, limiting the maximum polymer concentration in the forming solutions. A low-viscous co-solvent can reduce viscosity, but cellulose has none. This study demonstrates that dimethyl sulfoxide (DMSO), being non-solvent for cellulose, can act as a nominal co-solvent to improve its processing into a nanofiltration membrane by ...
Added: January 30, 2024
Dmitrii Roshchin, Kravchenko I., Fu T. et al., Chemical Engineering Sciences 2023 Vol. 281 Article 119169
The aim of this work was to study the relationship between hydrodynamic resistance and flow instability of shear-thinning fluids in channels with sudden contraction and expansion. To this end, the critical conditions of bifurcation transitions from symmetric to asymmetric vortex flow depending on the channel geometry and rheological properties of Carreau model fluid were investigated. ...
Added: January 8, 2024
Makarova V. V., Gorbacheva S. N., Kostyuk A. V. et al., Journal of Energy Storage 2022 Vol. 47 Article 103595
The work is devoted to evaluation of the thermal conductivity of composites based on asphaltenes and paraffin as a phase change material. Asphaltenes with different structural characteristics, obtained by chemical modification and fractionation were used to improve the heat conductivity of paraffin. Modification of asphaltenes with sulfuric acid and oleum made it possible to obtain ...
Added: January 29, 2023