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Nanoarchitecture: Toward Quantum-Size Tuning of Superconductivity.
Quantum confinement is known to affect a nanosized superconductor
through quantum-size variations of the electronic density of states. Here, it is
demonstrate that there is another quantum-confinement mechanism over-
looked in previous studies. In particular, it is found that the electron–electron
attraction can be enhanced due to quantum-confinement modifications of
electronic wave functions. The superconducting correlations are strengthened
by such quantum mechanical effect, which creates a subtle interplay with
surface–substrate phonon modifications. The combined effect depends on
nanofilm thickness and can be controlled by nanoarchitechture. The
calculations are in a reasonable agreement with experiments performed on
high-quality aluminum films. These findings shed light on the long-standing
problem of the size dependence of the critical temperature in low-
dimensional superconductors.