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Regular version of the site

Article

Methyl Viologen Iodobismuthates

Polyhedron. 2018. Vol. 154. P. 430-435.
Buikin P. A., Ilyukhin A. B., Simonenko N. P., Laurinavichyute V. K., Vitalii Yu. Kotov.

The interaction of iodobismuthate anions and methyl viologen [MV]2+ cations in aqueous solutions led to the formation of three compounds, two of which were identified as [MV][BiI5] and [MV]3[Bi2I11]I. Hybrid iodobismuthates [MV]3[Bi2I11]I and [MV]3[Bi2I9]2(DMF)3(H2O) were isolated from dimethylformamide (DMF). The heating of the latter material (up to 200 o C) resulted in a mixture of products, one of which was identified as [MV][BiI5]. A simple antisolvent precipitation method was proposed to create the [MV] [BiI5]/SiO2 composite material.