Тонкие слои нанокомпозитов на основе комплекса полианилина и графена
Two techniques of manufacturing a nanocomposite based on a complex of polyaniline with polymer acid and graphene are proposed. The electric conductivity of thin nanocomposite layers is higher than that of a polymer complex of polyaniline and strongly depends on the degree of oxidation of graphene. An explanation of the effect is suggested that takes into account electron interactions between the graphene planes and polyaniline backbone, as well as the possibility of formation of hydrogen bonds between functional groups of semioxidized graphene and polyacid. The results of surface topography analysis for thin layers of polyaniline and nanocomposite agree well with the regularities of the structure of each layer that are due to the above interactions between graphene and the polymer complex.
The contribution of electron–phonon scattering to conductivity of a quantum cylinder in a lon-gitudinal magnetic field has been studied. It has been shown that the conductivity of the nanotube undergoes Aharonov–Bohm oscillations with variations in the magnetic flux through the nanotube cross section. The formulas describing the temperature dependence of the resistance of the nanostructure both in the case of an isotropic phonon spectrum and with allowance for the effects of phonon confinement have been obtained in the analytical form.
The photoemission of excess charge carriers into high-ohmic gallium arsenide was investigated. It was revealed, that the illumination even small local sample areas located far from contacts, influences both on contacts transition resistance and on volume conductivity of the crystal. On Suite-voltage dependencies there is a linear plot, angular coefficient which is directly proportional to the diameter of the illuminated surface. The model qualitatively explain the experimental results.
We present the results of Monte Carlo simulations of the charge carrier transport in a disordered molecular system containing spatial and energetic disorders using the dipolar glass model. Model parameters of the material were chosen to fit a typical polar organic photoconductor polycarbonate doped with 30% of aromatic hydrazone, whose transport properties are well documented in literature. Simulated carrier mobility demonstrates a usual Poole-Frenkel field dependence and its slope is very close to the experimental value without using any adjustable parameter. At room temperature transients are universal with respect to the electric field and transport layer hickness. At the same time, carrier mobility does not depend on the layer thickness and transients develop a well-defined plateau where the current does not depend on time, thus demonstrating a non-dispersive transport regime. Tails of the transients decay as power law with the exponent close to −2. This particular feature indicates that transients are close to the boundary between dispersive and non-dispersive transport regimes. Shapes of the simulated transients are in very good agreement with the experimental ones. In summary, we provide a first verification of a self-consistency of the dipolar glass transport model, where major transport parameters, extracted from the experimental transport data, are then used in the transport simulation, and the resulting mobility field dependence and transients are in very good agreement with the initial experimental data. © 2013 American Institute of Physics. [http://dx.doi.org/10.1063/1.4794791]
Our approach to the problem of charge carrier transport in homogeneous polymers assumes carrier hopping on a densely packed manifold of transport (hopping) centers retaining the short-range order of the respective single crystal. The central idea, which distinguishes it from the Bassler’s disorder theory, is that the energy scatter concerns only a small fraction of hopping centers, which begin to act as traps. The majority of isoenergetic centers build up a transfer band with microscopic mobility µ0 equal to that in the respective single crystal. The origin of the energy scatter (and traps themselves) is ascribed to the elementary voids of the fluctuation free volume forming an association with the normal hopping centers.
A contribution of the electron-phonon scattering to the conductivity of a quantum cylinder in a magnetic field is calculated. It is demonstrated that the nanotube conductivity undergoes the Aharonov–Bohm oscillations with changes of the magnetic flux through the nanotube cross section.
This edition presents abstracts of the reports of the participants of the VI International conference "Advanced materials and technologies - 2014"
The dynamics of a two-component Davydov-Scott (DS) soliton with a small mismatch of the initial location or velocity of the high-frequency (HF) component was investigated within the framework of the Zakharov-type system of two coupled equations for the HF and low-frequency (LF) fields. In this system, the HF field is described by the linear Schrödinger equation with the potential generated by the LF component varying in time and space. The LF component in this system is described by the Korteweg-de Vries equation with a term of quadratic influence of the HF field on the LF field. The frequency of the DS soliton`s component oscillation was found analytically using the balance equation. The perturbed DS soliton was shown to be stable. The analytical results were confirmed by numerical simulations.
Radiation conditions are described for various space regions, radiation-induced effects in spacecraft materials and equipment components are considered and information on theoretical, computational, and experimental methods for studying radiation effects are presented. The peculiarities of radiation effects on nanostructures and some problems related to modeling and radiation testing of such structures are considered.
This volume presents new results in the study and optimization of information transmission models in telecommunication networks using different approaches, mainly based on theiries of queueing systems and queueing networks .
The paper provides a number of proposed draft operational guidelines for technology measurement and includes a number of tentative technology definitions to be used for statistical purposes, principles for identification and classification of potentially growing technology areas, suggestions on the survey strategies and indicators. These are the key components of an internationally harmonized framework for collecting and interpreting technology data that would need to be further developed through a broader consultation process. A summary of definitions of technology already available in OECD manuals and the stocktaking results are provided in the Annex section.