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Optical features of nanoplatelets modified with chiral ligands
Optical Materials: X. 2026. Vol. 30. Article 100441.
A.M. Smirnov, Kurtina D. A., Saitov S. R., Fedyanin A. A., Mantsevich V. N., Musorin A. I., Kotova L. V., Zedomi T., Vasiliev R. B.
Chiral semiconductor nanostructures and nanoparticles are promising materials for applications in biological sensing, enantioselective separation, photonics, and spin-polarized devices. Here we performed a detailed analysis of optical properties of chiral CdSe nanoplatelets with thickness of 2 and 3 monolayers (ML) with Nacetyl-L-cysteine ligands. We studied the absorption spectra peculiarities, analyzed time-resolved photoluminescence and investigated circular and linear polarization of light passed the samples with different chirality. It was found that non-chiral nanoplatelets reveal the transformation of linear polarization into circular one due to the precence of birefringence. It was demonstrated that only one of the exciton resonances dominates in the polarization properties of chiral nanoplatelets. For chiral 2-ML-thick CdSe nanoplatelets the most pronounced chiral optical response corresponds to the heavy hole excitons and for 3-ML-thick CdSe nanoplatelets light hole excitons play the most important role. We performed complex analysis of the optical features of nanoplatelets modified by chiral ligands and combined for the first time to the best of our knowledge the polarization analysis with time resolved measurements. Moreover, we demonstrated an important role of birefringence in the semiconductor in addition to the presence of chiral ligands, which was not carefully separated before.
Никонов В. Д., Никитин С. С., Патракеев М. В., Ionics 2025 Vol. 31 No. 1 P. 675–687
Modification of perovskite-type oxides is an effective way to develop functional materials with advanced properties. The effects of cerium introduction into the A sublattice of La0.5Sr0.5FeO3−δ and variation of La:Sr ratio on the defect structure and charge transfer characteristics were studied in this work. The LaxSr0.85−xCe0.15FeO3−δ oxides were found to be single-phase with cubic (x = 0.1) and orthorhombic ...
Added: June 26, 2026
Polkin A., Skvortsov M., Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 113 Article 174516
We develop a full microscopic theory for the optical conductivity 𝜎(𝜔) of a dirty current-carrying superconductor. Within the Keldysh sigma model formalism, we obtain the general analytical expression for 𝜎(𝜔), applicable for arbitrary frequency 𝜔, temperature 𝑇, and dc supercurrent 𝐼. In addition to altering the usual Mattis-Bardeen conductivity 𝜎1(𝜔), a finite supercurrent introduces two new contributions: 𝜎qp2(𝜔) from quasiparticle redistribution and 𝜎SH2(𝜔) from the amplitude ...
Added: June 25, 2026
Skvortsov M., Artem Polkin, Physical Review B: Condensed Matter and Materials Physics 2026 Vol. 113 No. 10 Article 100502
A dissipationless supercurrent state in superconductors can be destroyed by thermal fluctuations. Thermally activated phase slips provide a finite resistance of the sample and are responsible for dark counts in superconducting single-photon detectors. The activation barrier for a phase slip is determined by a space-dependent saddle-point (instanton) configuration of the order parameter. In the one-dimensional ...
Added: June 25, 2026
Деменев А. А., Терешко С. Н., Гиппиус Н А et al., Известия РАН. Серия физическая Россия 2025 Т. 89 № 2 С. 265–273
The authors study the temporal evolution of polarized spectra of emissions from spinor exciton‒
polariton condensates in double tunnel-coupled potential traps inside a high-Q GaAs/AlAs microcavity
at 2 K upon resonance laser pumping with picosecond pulses at times of up to 1.5 ns. The period of the condensates’
spin relaxation in a double trap is estimated as τs ...
Added: June 23, 2026
Абрамов-Максимов В. Е., И.А. Бакунина, Геомагнетизм и аэрономия 2026 Т. 66 № 3 С. 515–529
Проанализировано 8 вспышечных событий по данным многочастотных наблюдений сети радиотелескопов Radio Solar Telescope Network. Целью анализа было выявление предвестников солнечных вспышек. В семи рассмотренных случаях выявлены предвспышечные квазипериодические флуктуации радиоизлучения. Сделанная по вейвлет-спектрам оценка квазипериодов дает в большинстве случаев значения 40–50 сек. В одном событии с большой вспышкой класса M8.0 квазипериодические флуктуации не проявились. В ...
Added: June 22, 2026
И.А. Бакунина, В.Ф. М., А.В. Ш. et al., Геомагнетизм и аэрономия 2025 Т. 65 № 9 С. 1363–1373
Рассмотрена связь особенностей положения и ориентации магнитных жгутов в активной области (АО) с источниками микроволнового (17 ГГц) излучения и излучения в крайнем ультрафиолетовом диапазоне (EUV) при возникновении эруптивных вспышек, сопровождающихся корональными выбросами массы, и вспышек с "запертой" эрупцией. Приведены примеры эруптивных событий, демонстрирующие пространственное совпадение микроволновых источников с расположением магнитных жгутов в АО, восстановленных при ...
Added: June 22, 2026
Г. Г. Бондаренко, Кристя В. И., Савичкин Д. О. et al., Поверхность. Рентгеновские, синхротронные и нейтронные исследования 2026 № 4 С. 29–36
Сформулирована модель тлеющего газового разряда в смеси аргона и паров ртути при наличии
на поверхности катода тонкой диэлектрической пленки. Рассчитаны зависимости характеристик
разряда от температуры в интервале ее изменения, в котором заметный вклад в ионизацию
рабочей газовой смеси дает ионизация атомов ртути метастабильными возбужденными атомами
аргона (реакция Пеннинга). Показано, что в случае катода без диэлектрической пленки при
повышении температуры до ...
Added: June 20, 2026
Chertenkov V. I., Shchur L., Lobachevskii Journal of Mathematics 2026 Vol. 47 No. 2 P. 720–727
Supervised machine learning is successfully applied to the study of critical phenomena and allows us to obtain a numerical estimate of the phase transition temperature and the correlation length exponent. We discuss the influence of possible systematic errors, as well as statistical errors, on the accuracy of such numerical estimates. Errors in the training and ...
Added: June 16, 2026
Батурин А. С., Гаврилов В. Р., Иванов А. В. et al., Измерительная техника 2026 Т. 75 № 2 С. 14–28
28 декабря 2025 года Всероссийскому научно-исследовательскому институту оптико-физических измерений (ВНИИОФИ) исполнилось 60 лет. За прошедшие десятилетия институт выполнил значительное количество научных исследований, разработал и поставил потребителям тысячи высокоточных средств оптико-физических измерений (включая эталонное оборудование). В статье представлены наиболее значимые для метрологического обеспечения оптико-физических измерений результаты научно-исследовательских работ, выполненных ВНИИОФИ за период 2016–2025 гг. ...
Added: June 15, 2026
Вишняков Г. Н., Левина Э. Ю., Minaev V., Измерительная техника 2025 Т. 74 № 2 С. 20–27
Качество формируемого оптической системой изображения определяется её частотно-контрастной характеристикой или коэффициентами передачи модуляции на различных пространственных частотах. Для обеспечения единства измерений коэффициентов передачи модуляции и создания эталонной базы по воспроизведению, хранению и передаче единицы коэффициента передачи модуляции усовершенствован Государственный первичный эталон единиц оптической силы очковой оптики ГЭТ 205-2013 в части воспроизведения единицы коэффициентов передачи модуляции ...
Added: June 15, 2026
Filippova A. V., Yurchenko N. Y., Smirnov S. A. et al., Journal of Alloys and Compounds 2026 No. 1074 Article 189162
This study investigates the effects of post-processing heat treatment at 300–500 °C on the microstructure, hardness, and tensile properties of laser powder bed fusion (PBF-LB) processed Al-bronze processed with energy densities (ED) in the range of 125–938 J/mm3. In the as-printed state, sharp needle-like α + β′ laths form at lower ED whereas with increasing ED, the β′ ...
Added: June 12, 2026
Спонтанное образование скин-слоя в воде с деформацией ОН-полосы КР вкладом компоненты льда 3200 см-1
Першин С. М., Степанов Е. В., Артемова Д. Г. et al., Письма в Журнал экспериментальной и теоретической физики 2026 Т. 123 № 6 С. 383–390
Открыто спонтанное образование в течение 4 ч скин-слоя дистиллированной воды толщиной до 3 мм при комнатной температуре с новыми свойствами. Обнаружены деформация ОН-полосы комбинационного рассеяния вкладом компоненты льда ( 3200 см-1), снижение коэффициента упругого рассеяния и его флуктуаций, а также увеличение на 20 капиллярах. Восстановление слоя после обогащения воздухом в результате перемешивания указывает на стабильность ...
Added: June 8, 2026
Springer, 2026.
The book presents the proceedings of the 13th International Conference on Frontiers of Intelligent Computing: Theory and Applications (FICTA 2024), held at Intelligent Systems Research Group (ISRG), London Metropolitan University, London, United Kingdom, during June 6–7, 2025. Researchers, scientists, engineers and practitioners exchange new ideas and experiences in the domain of intelligent computing theories with ...
Added: June 8, 2026
N.S. Artekha, D.R. Shklyar, Physics of Plasmas 2026 Vol. 33 No. 6 Article 062105
The peculiarities of resonant interaction between slow extraordinary (SE) waves and relativistic electrons have been studied. General equations of motion of relativistic electrons in the field of SE wave and a uniform ambient magnetic field are derived. Conditions of applicability of the isolated resonance approximation are elucidated. In this approximation, the equations of motion are reduced to one-dimensional set of ...
Added: June 6, 2026
Zirnik G., Ostovari Moghaddam A., Zhukov S. et al., Journal of Materials Science: Materials in Electronics 2026 Vol. 37 Article 738
In regards to the advances in InGaZnO for flexible transistors applications, herein for the first time we measure the broadband radio-frequency range (10 Hz to 1 MHz) dielectric permittivity ε′ and electrical conductivity σ of InGaZnO4 nanoparticle layers at different temperatures ranging from 10 to 300 K. The InGaZnO4 nanoparticles prepared by metal–nitrate–glycol gel decomposition method exhibited ...
Added: June 6, 2026
Flamarion M. V., Pelinovsky E., Nonlinear Dynamics 2026 Vol. 114 Article 784
In this article, we investigate wave packet and solitary wave dynamics in the Whitham–Ostrovsky (WO) equation. By means of a multiple-scales expansion, we formally derive a nonlinear Schrödinger (NLS) equation governing the envelope evolution.The corresponding modulational stability diagram is then obtained using the Lighthill criterion. We show that sufficiently large values of the low-frequency dispersive term render ...
Added: June 5, 2026
Hazarika A. P., Das A., Das S. K. et al., Physica B: Condensed Matter 2026 Vol. 738 Article 418803
Lemon grass (Cymbopogon citratus, LG-SiO2), horsetail (Equisetum debile, SG-SiO2), and cassava leaves (Manihot esculenta, CL-SiO2) were used to green-synthesize silica (SiO2) nanoparticles (NPs). While LG-SiO2 and SG-SiO2 had strong (101) peaks and a large 22° amorphous peak, XRD of CL-SiO2 verified crystallinity. LG-SiO2 (agglomerated porous), SG-SiO2 (rectangular-cube agglomerates), and CL-SiO2 (flake agglomerates) had different morphologies. The TEM image of LG-SiO2 revealed agglomerated ...
Added: June 4, 2026
Kornbleuth M., Opher M., Drake J. F. et al., Astrophysical Journal 2026 Vol. 1004 No. 1 Article 1
The shape of the heliosphere, regarded as comet-like since the 1960s, has recently been the subject of intense debate in the last decade. There is disagreement as to whether the heliospheric tail extends to ∼10,000 au in a comet-like shape or if it is short (∼400 au) with a split. Energetic neutral atom (ENA) maps from ...
Added: June 3, 2026
Bezzubov S., Vatsouro I., Alekseev I. et al., Organic Chemistry Frontiers 2026 Vol. 13 No. 3 P. 851–865
An efficient strategy is presented for the synthesis of rare-type inherently chiral calix[4]arenes having an asymmetric arrangement of functional groups at the wide rim of the cone macrocycle and possessing virtually unlimited functionalization capabilities. Selective protection of two proximal amino groups in the Cs-symmetrical wide-rim calixarene triamine by tert-butoxycarbonyl groups is suggested as the key synthesis step, ...
Added: February 17, 2026
Shornikova E., Yakovlev D., Tolmachev D. et al., ACS Applied Nano Materials 2025 Vol. 8 No. 2 P. 974–984
Diluted magnetic semiconductor (DMS) colloidal nanocrystals demonstrate remarkable magneto-optical properties. The ability to control their magnetization and, consequently, the circular polarization of exciton emission holds significant potential for spintronic applications. However, the interplay between bright and dark exciton recombination and its impact on the polarization of emission are not yet fully understood. We measure the ...
Added: January 26, 2026
Nguyen H. L., Do T. N., Durmusoglu E. G. et al., ACS Nano 2023 Vol. 17 No. 3 P. 2411–2420
We measure the ultrafast spectral diffusion, vibronic dynamics, and energy relaxation of a CdSe colloidal quantum wells (CQWs) system at room temperature using two-dimensional electronic spectroscopy (2DES). The energy relaxation of light-hole (LH) excitons and hot carriers to heavy-hole (HH) excitons is resolved with a time scale of ∼210 fs. We observe the equilibration dynamics ...
Added: November 19, 2025
Ankudinov N., Komarova A., Evgeniya S. Podyacheva et al., Chemical Communications 2024 Vol. 60 No. 65 P. 8601–8604
Molecules with chiral boron atoms have been scarcely studied due to limited synthetic access. Herein, we report a new method for their synthesis via asymmetric insertion of arydiazoacetates into the B–H bonds of prochiral carbene–boranes NHC–BH2R. The reaction is catalyzed by the rhodium(I) complex with the chiral diene ligand
tBu2-TFB, which can be conveniently prepared by ...
Added: February 23, 2025
Mikhail A. Boym, Pototskiy R., Evgeniya S. Podyacheva et al., Chemical Communications 2024 Vol. 60 No. 33 P. 4491–4494
Heating tert-butyl-tetraline with [(p-cymene)RuCl2]2 produces the racemic complex [(arene)RuCl2]2, which can be separated into enantiomers by chromatography of its diastereomeric adducts with chiral phosphine ligand. The resolved chiral complex catalyzes C–H activation of N-methoxy-benzamides and their annulation with N-vinyl-pivaloyl amide giving dihydroisoquinolones in 50–80% yields and with 40–80% enantiomeric excess. ...
Added: January 23, 2025
Klimenko G. A., A. Hasan, Yakimov B. P. et al., Journal of Luminescence 2024 Vol. 275 Article 120732
Peculiarities of photoluminescence (PL) and absorption spectra of gradient nanocrystals CdSe1-xSx colloidal solution were studied by pump and probe technique under stationary excitation of excitons by nanosecond laser pulses. The PL peaks and differential transmission peaks positions changing were revealed with the CdSe1-xSx nanocrystals composition variation. Bleaching of excitons transitions was observed for high pump ...
Added: June 20, 2024