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Найдено 6 публикаций
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Статья
Vitalii Yu. Kotov, Ilyukhin A. B., Birin K. P. et al. New Journal of Chemistry. 2016. Vol. 40. No. 12. P. 10041-10047.
Добавлено: 17 октября 2018
Статья
Roitershtein D., Savchenko M. S., Lyssenko K. A. et al. New Journal of Chemistry. 2017. Vol. 41. P. 13663-13672.
Добавлено: 19 октября 2018
Статья
Vitalii Yu. Kotov, Ilyukhin A. B., Korlyukov A. A. et al. New Journal of Chemistry. 2018. Vol. 42. No. 8. P. 6354-6363.
Добавлено: 17 октября 2018
Статья
Zaitseva E. R., Smirnov A. Y., Myasnyanko I. N. et al. New Journal of Chemistry. 2021. Vol. 45. No. 4. P. 1805-1808.
Добавлено: 2 февраля 2021
Статья
Vasilyeva I., Kuz’micheva G., Pochtar A. et al. New Journal of Chemistry. 2015. No. 40. P. 151-161.

Conditions for a sulfate method for the synthesis of a metastable modification, which has been previously described as ‘‘Z-TiO2’’ (Dadachov, 2006), were found and the stability region of this phase in the hydrolysis temperature–hydrolysis duration coordinates was determined. Investigation by a number of methods (X-ray powder diffraction, a differential dissolution method, thermogravimetry, IR spectroscopy, Raman spectroscopy) showed that the Z-phase is not a polymorph of TiO2 but is a pseudo-polymorph of titanium dioxide hydrate. It was demonstrated that nanoparticles of the lowtemperature Z-phase consist of the [TiO2xmH2O] core, the structure of which can be described as a superstructure in relation to anatase, and an amorphous shell containing TiO2x (trace amount), OH, HSO4 and water. The average crystallite size depends on the ratio of the constituents.

Добавлено: 14 января 2016
Статья
Kotov V., Buikin P., Ilyukhin A. B. et al. New Journal of Chemistry. 2021.
Добавлено: 22 сентября 2021