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Article

Hybrid halobismuthates: a coordinated BrIBr–anion

Mendeleev Communications. 2017. Vol. 27. No. 5. P. 454-455.
Vitalii Yu. Kotov, Simonenko N. P., Ilyukhin A. B.

A new organic-inorganic hybrid material containing bromo-bismuthate anions and bis(1-pyridino)hexane cations was synthesized and characterized. The reaction between (C-16/H22N2)(2)Bi2Br10 and HBr in the presence of HI vapor afforded (C16H22N2)(3)(BiBr6)2 as the main product and (C16H22N2)(3)(BiBr6)(BiBr7I) as a by-product containing the BrIBr- anion coordinated