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Article

Synthesis, crystal structure and optical properties of 1, 1'-(1, n-alkanediyl) bis (3-methylimidazolium) halobismuthates

Journal of Molecular Structure. 2018. Vol. 1151. P. 186-190.
Kotov Vitalii Yu., Ilyukhin A. B., Baranchikov A. E., Ishmetova R. I., Rusinov G. L., Kozyukhin S. A.

Four hybrid 3,3'-(alkane-1,n-di-yl)-bis(1-methyl-1H-imidazole-3-ium) halobismuthates were prepared by a facile solution route and characterized by diffuse reflectance spectra and photoluminescence measurements. Crystal structure of 3,3'-(buthane-1,4-di-yl)-bis(1-methyl-1H-imidazole-3-ium) bromo-bismuthate (1) contains zero-dimensional Bi2Br10 anions. Crystal structure of 3,3'-(pentane-1,5-di-yl)bis-(1-methyl-IH-imidazole-3-ium) iodobismuthate (4) contains zero-dimensional Bi2I9 anions.